Performance of a Non-Aqueous Vanadium Acetylacetonate Prototype Redox Flow Battery: Examination of Separators and Capacity Decay

2014 ◽  
Vol 162 (3) ◽  
pp. A363-A372 ◽  
Author(s):  
Ismailia L. Escalante-García ◽  
Jesse S. Wainright ◽  
Levi T. Thompson ◽  
Robert F. Savinell
Keyword(s):  
Redox Flow Battery ◽  
Flow Battery ◽  
Vanadium Acetylacetonate ◽  
Capacity Decay

scholarly journals Model-Based Condition Monitoring of a Vanadium Redox Flow Battery

Energies ◽  
2019 ◽  
Vol 12 (15) ◽  
pp. 3005 ◽  
Author(s):  
Meng ◽  
Xiong ◽  
Lim
Keyword(s):  
Parameter Identification ◽  
Real Time ◽  
Vanadium Redox Flow Battery ◽  
Redox Flow Battery ◽  
Flow Battery ◽  
Model Parameter ◽  
Model Based ◽  
Model Parameter Identification ◽  
Vanadium Redox ◽  
Capacity Decay

The safe, efficient and durable utilization of a vanadium redox flow battery (VRB) requires accurate monitoring of its state of charge (SOC) and capacity decay. This paper focuses on the unbiased model parameter identification and model-based monitoring of both the SOC and capacity decay of a VRB. Specifically, a first-order resistor-capacitance (RC) model was used to simulate the dynamics of the VRB. A recursive total least squares (RTLS) method was exploited to attenuate the impact of external disturbances and accurately track the change of model parameters in realtime. The RTLS-based identification method was further integrated with an H-infinity filter (HIF)-based state estimator to monitor the SOC and capacity decay of the VRB in real-time. Experiments were carried out to validate the proposed method. The results suggested that the proposed method can achieve unbiased model parameter identification when unexpected noises corrupt the current and voltage measurements. SOC and capacity decay can also be estimated accurately in real-time without requiring additional open-circuit cells.

Degradation mechanisms in the non-aqueous vanadium acetylacetonate redox flow battery

2012 ◽  
Vol 206 ◽  
pp. 490-496 ◽  
Author(s):  
Aaron A. Shinkle ◽  
Alice E.S. Sleightholme ◽  
Lucas D. Griffith ◽  
Levi T. Thompson ◽  
Charles W. Monroe
Keyword(s):  
Redox Flow Battery ◽  
Degradation Mechanisms ◽  
Flow Battery ◽  
Vanadium Acetylacetonate

A cobalt sulfide cluster-based catholyte for aqueous flow battery applications

2018 ◽  
Vol 6 (44) ◽  
pp. 21927-21932 ◽  
Author(s):  
Matthew B. Freeman ◽  
Le Wang ◽  
Daniel S. Jones ◽  
Christopher M. Bejger
Keyword(s):  
Active Material ◽  
Water Soluble ◽  
Molecular Cluster ◽  
Cobalt Sulfide ◽  
Redox Flow Battery ◽  
Flow Battery ◽  
Aqueous Flow ◽  
Sulfide Cluster

A water-soluble Co6S8 molecular cluster was prepared and electrochemically analyzed as a potential active material for redox flow battery applications.

Zirconium boride as a novel negative catalyst for vanadium redox flow battery

2021 ◽  
Author(s):  
Tongxue Zhang ◽  
Yingqiao Jiang ◽  
Zixuan Zhang ◽  
Jing Xue ◽  
Yuehua Li ◽  
...  
Keyword(s):  
Vanadium Redox Flow Battery ◽  
Zirconium Boride ◽  
Redox Flow Battery ◽  
Flow Battery ◽  
Vanadium Redox

scholarly journals Graphene-Based Electrodes in a Vanadium Redox Flow Battery Produced by Rapid Low-Pressure Combined Gas Plasma Treatments

2021 ◽  
Author(s):  
Sebastiano Bellani ◽  
Leyla Najafi ◽  
Mirko Prato ◽  
Reinier Oropesa-Nuñez ◽  
Beatriz Martín-García ◽  
...  
Keyword(s):  
Low Pressure ◽  
Vanadium Redox Flow Battery ◽  
Redox Flow Battery ◽  
Flow Battery ◽  
Plasma Treatments ◽  
Gas Plasma ◽  
Vanadium Redox
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