Model for Hydrogen Evolution Reaction in Aqueous Solutions Containing Dissolved CO2 in High Pressures

2019 ◽  
Vol 166 (14) ◽  
pp. C479-C484 ◽  
Author(s):  
Flávio V. V. de Sousa ◽  
Nathália A. Leite ◽  
Bernard Tribollet ◽  
Oswaldo E. Barcia ◽  
Oscar R. Mattos
Keyword(s):  
Aqueous Solutions ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
High Pressures

Hydrogen Evolution Reaction Evaluation in Aqueous Solutions Containing CO2at Different Pressures

2017 ◽  
Vol 164 (6) ◽  
pp. C294-C299 ◽  
Author(s):  
Flávio V. V. de Sousa ◽  
Pedro R. P. Viana ◽  
Bernard Tribollet ◽  
Oswaldo E. Barcia ◽  
Oscar R. Mattos
Keyword(s):  
Aqueous Solutions ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction

Photocatalytic Properties of Layered K3H3Nb10.8O30 in the Hydrogen Evolution Reaction from Aqueous Solutions of Alcohols

2017 ◽  
Vol 53 (2) ◽  
pp. 100-105 ◽  
Author(s):  
V. V. Shvalagin ◽  
G. Ya. Grodzyuk ◽  
G. V. Korzhak ◽  
N. S. Andriushyna ◽  
S. Ya. Kuchmy ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Photocatalytic Properties

Colloidally-synthesized cobalt molybdenum nanoparticles as active and stable electrocatalysts for the hydrogen evolution reaction under alkaline conditions

2016 ◽  
Vol 4 (8) ◽  
pp. 3077-3081 ◽  
Author(s):  
Joshua M. McEnaney ◽  
Taylor L. Soucy ◽  
James M. Hodges ◽  
Juan F. Callejas ◽  
Jared S. Mondschein ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Molybdenum Alloy ◽  
Colloidal Nanoparticles ◽  
Alkaline Conditions ◽  
Molybdenum Nanoparticles

Colloidal nanoparticles of a cobalt–molybdenum alloy were synthesized and found to be active electrocatalysts for the hydrogen evolution reaction in alkaline aqueous solutions.

Improved catalytic activity of Mo1−xWxSe2 alloy nanoflowers promotes efficient hydrogen evolution reaction in both acidic and alkaline aqueous solutions

Nanoscale ◽  
2017 ◽  
Vol 9 (37) ◽  
pp. 13998-14005 ◽  
Author(s):  
Oren E. Meiron ◽  
Vasu Kuraganti ◽  
Idan Hod ◽  
Ronen Bar-Ziv ◽  
Maya Bar-Sadan
Keyword(s):  
Catalytic Activity ◽  
Synergistic Effect ◽  
Aqueous Solutions ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Electrocatalytic Activity ◽  
Electrocatalytic Properties ◽  
Se Deficiency

The electrocatalytic properties of 2D MoWSe2 nanoflower alloys showed a synergistic effect towards hydrogen evolution. Se deficiency was also found to significantly change the electrocatalytic activity of the materials.

scholarly journals Highly branched cobalt phosphide nanostructures for hydrogen-evolution electrocatalysis

2015 ◽  
Vol 3 (10) ◽  
pp. 5420-5425 ◽  
Author(s):  
Eric J. Popczun ◽  
Christopher W. Roske ◽  
Carlos G. Read ◽  
J. Chance Crompton ◽  
Joshua M. McEnaney ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Cobalt Phosphide

Highly branched cobalt phosphide (CoP) nanostructures that expose predominantly (111) crystal facets are active electrocatalysts for the hydrogen evolution reaction in acidic aqueous solutions.

A crystalline–amorphous Ni–Ni(OH)2 core–shell catalyst for the alkaline hydrogen evolution reaction

2020 ◽  
Vol 8 (44) ◽  
pp. 23323-23329
Author(s):  
Jing Hu ◽  
Siwei Li ◽  
Yuzhi Li ◽  
Jing Wang ◽  
Yunchen Du ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Electrocatalytic Activity ◽  
Core Shell ◽  
Alkaline Conditions

Crystalline–amorphous Ni–Ni(OH)2 core–shell assembled nanosheets exhibit outstanding electrocatalytic activity and stability for hydrogen evolution under alkaline conditions.

Cobaloxime-Based Double Complex Salts as Efficient and Versatile Catalysts for the Light-Driven Hydrogen Evolution Reaction

2020 ◽  
Author(s):  
Elisabeth Hofmeister ◽  
Jisoo Woo ◽  
Tobias Ullrich ◽  
Lydia Petermann ◽  
Kevin Hanus ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Systematic Study ◽  
Cobalt Complexes ◽  
Spectroscopic Studies ◽  
Double Complex ◽  
Double Complex Salts ◽  
Noble Metal Catalysts ◽  
Reduction Potentials ◽  
Complex Salts

Cobaloximes and their BF<sub>2</sub>-bridged analogues have emerged as promising non-noble metal catalysts for the photocatalytic hydrogen evolution reaction (HER). Herein we report the serendipitous discovery that double complex salts such as [Co(dmgh)<sub>2</sub>py<sub>2</sub>]<sup>+</sup>[Co(dmgBPh<sub>2</sub>)<sub>2</sub>Cl<sub>2</sub>]<sup>-</sup> can be obtained in good yields by treatment of commercially available [Co(dmgh)<sub>2</sub>pyCl] with triarylboranes. A systematic study on the use of such double complex salts and their single salts with simple counterions as photocatalysts revealed HER activities comparable or superior to existing cobaloxime catalysts and suggests ample opportunities for this compound class in catalyst/photosensitizer dyads and immobilized architectures. Preliminary electrochemical and spectroscopic studies indicate that one key advantage of these charged cobalt complexes is that the reduction potentials as well as the electrostatic interaction with charged photosensitizers can be tuned.

2,2’-Dipyridylamine as Organic Molecular Electrocatalyst for Hydrogen Evolution Reaction in Acidic Electrolytes

2019 ◽  
Author(s):  
Xi Yin ◽  
Ling Lin ◽  
Hoon T. Chung ◽  
Ulises Martinez ◽  
Andrew M. Baker ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Density Functional ◽  
Low Cost ◽  
Membrane Electrode Assembly ◽  
Carbon Surface ◽  
Membrane Electrode ◽  
Durability Test ◽  
Onset Potential ◽  
Precious Metal Catalysts

Finding a low-cost and stable electrocatalyst for hydrogen evolution reaction (HER) as a replacement for scarce and expensive precious metal catalysts has attracted significant interest from chemical and materials research communities. Here, we demonstrate an organic catalyst based on 2,2’-dipyridylamine (dpa) molecules adsorbed on carbon surface, which shows remarkable hydrogen evolution activity and performance durability in strongly acidic polymer electrolytes without involving any metal. The HER onset potential at dpa adsorbed on carbon has been found to be less than 50 mV in sulfuric acid and in a Nafion-based membrane electrode assembly (MEA). At the same time, this catalyst has shown no performance loss in a 60-hour durability test. The HER reaction mechanisms and the low onset overpotential in this system are revealed based on electrochemical study. Density functional theory (DFT) calculations suggest that the pyridyl-N functions as the active site for H adsorption with a free energy of -0.13 eV, in agreement with the unusually low onset overpotential for an organic molecular catalyst.<br>

2,2’-Dipyridylamine as Organic Molecular Electrocatalyst for Hydrogen Evolution Reaction in Acidic Electrolytes

2019 ◽  
Author(s):  
Xi Yin ◽  
Ling Lin ◽  
Hoon T. Chung ◽  
Ulises Martinez ◽  
Andrew M. Baker ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Density Functional ◽  
Low Cost ◽  
Membrane Electrode Assembly ◽  
Carbon Surface ◽  
Membrane Electrode ◽  
Durability Test ◽  
Onset Potential ◽  
Precious Metal Catalysts

Finding a low-cost and stable electrocatalyst for hydrogen evolution reaction (HER) as a replacement for scarce and expensive precious metal catalysts has attracted significant interest from chemical and materials research communities. Here, we demonstrate an organic catalyst based on 2,2’-dipyridylamine (dpa) molecules adsorbed on carbon surface, which shows remarkable hydrogen evolution activity and performance durability in strongly acidic polymer electrolytes without involving any metal. The HER onset potential at dpa adsorbed on carbon has been found to be less than 50 mV in sulfuric acid and in a Nafion-based membrane electrode assembly (MEA). At the same time, this catalyst has shown no performance loss in a 60-hour durability test. The HER reaction mechanisms and the low onset overpotential in this system are revealed based on electrochemical study. Density functional theory (DFT) calculations suggest that the pyridyl-N functions as the active site for H adsorption with a free energy of -0.13 eV, in agreement with the unusually low onset overpotential for an organic molecular catalyst.<br>

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