Direct Determination of Diffusion Coefficients in Commercial Li-Ion Batteries

2018 ◽  
Vol 165 (5) ◽  
pp. A847-A855 ◽  
Author(s):  
Maria Angeles Cabañero ◽  
Nicola Boaretto ◽  
Manuel Röder ◽  
Jana Müller ◽  
Josef Kallo ◽  
...  
Author(s):  
Lei Xu ◽  
Yi Yang ◽  
Ye Xiao ◽  
Wen-Long Cai ◽  
Yu-Xing Yao ◽  
...  
Keyword(s):  

2016 ◽  
Vol 163 (8) ◽  
pp. H672-H678 ◽  
Author(s):  
Jonathan Moldenhauer ◽  
Madeline Meier ◽  
David W. Paul

2020 ◽  
Author(s):  
Trinidad Mendez-Morales ◽  
Zhujie Li ◽  
Mathieu Salanne

Water-in-salts form a new family of electrolytes with properties distinct from the ones of conventional aqueous systems and ionic liquids. They are currently investigated for Li-ion batteries and supercapacitors applications, but to date most of the focus was put on the system based on the LiTFSI salt. Here we study the structure and the dynamics of a series of water-in-salts with different anions. They have a similar parent structure but they vary systematically through their symmetric/asymmetric feature and the length of the fluorocarbonated chains. The simulations allow to determine their tendency to nanosegregate, as well as their transport properties (viscosity, ionic conductivity, diffusion coefficients) and the amount of free water, providing useful data for potential applications in energy storage devices.


1975 ◽  
Vol 30 (8) ◽  
pp. 951-954 ◽  
Author(s):  
K. Frohnecke ◽  
H. Fischbach

Abstract Direct Determination of the Rate Constants for the Sr-and Ba-exchange Between the Small and Large Channels in LMS 13X The rate constants for the intracristalline Sr-and Ba-exchange between the small and large diameter channels of LMS 13X were measured. For this matter the method of interrupting the ion exchange was modified. It is assumed, that a first order reaction takes place. Using the rate constants and the diffusion coefficients, which were measured by Hoinkis and Levi, the total exchange of Sr 2+ and Ba 2+ could be calculated.


2010 ◽  
Vol 183 (1) ◽  
pp. 218-222 ◽  
Author(s):  
L. Aldon ◽  
A. Perea ◽  
M. Womes ◽  
C.M. Ionica-Bousquet ◽  
J.-C. Jumas
Keyword(s):  

2020 ◽  
Author(s):  
Trinidad Mendez-Morales ◽  
Zhujie Li ◽  
Mathieu Salanne

Water-in-salts form a new family of electrolytes with properties distinct from the ones of conventional aqueous systems and ionic liquids. They are currently investigated for Li-ion batteries and supercapacitors applications, but to date most of the focus was put on the system based on the LiTFSI salt. Here we study the structure and the dynamics of a series of water-in-salts with different anions. They have a similar parent structure but they vary systematically through their symmetric/asymmetric feature and the length of the fluorocarbonated chains. The simulations allow to determine their tendency to nanosegregate, as well as their transport properties (viscosity, ionic conductivity, diffusion coefficients) and the amount of free water, providing useful data for potential applications in energy storage devices.


1999 ◽  
Vol 77 (2) ◽  
pp. 198-201 ◽  
Author(s):  
Yanko M. Todorov ◽  
Yasufumi Hideshima ◽  
Hideyuki Noguchi ◽  
Masaki Yoshio

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