Why is the Solid-Electrolyte-Interphase Selective? Through-Film Ferrocenium Reduction on Highly Oriented Pyrolytic Graphite

2012 ◽  
Vol 159 (12) ◽  
pp. A1922-A1927 ◽  
Author(s):  
Maureen Tang ◽  
John Newman
Keyword(s):  
Solid Electrolyte ◽  
Pyrolytic Graphite ◽  
Solid Electrolyte Interphase ◽  
Highly Oriented Pyrolytic Graphite

scholarly journals Formation of the Solid Electrolyte Interphase at Constant Potentials: a Model Study on Highly Oriented Pyrolytic Graphite

2018 ◽  
Vol 1 (3) ◽  
pp. 96-96
Author(s):  
Byron K. Antonopoulos ◽  
Filippo Maglia ◽  
Felix Schmidt-Stein ◽  
Jan P. Schmidt ◽  
Harry E. Hoster
Keyword(s):  
Solid Electrolyte ◽  
Pyrolytic Graphite ◽  
Solid Electrolyte Interphase ◽  
Highly Oriented Pyrolytic Graphite ◽  
Model Study

scholarly journals Formation of the Solid Electrolyte Interphase at Constant Potentials: A Model Study on Highly Oriented Pyrolytic Graphite

2018 ◽  
Vol 1 (3) ◽  
pp. 110-121 ◽  
Author(s):  
Byron K. Antonopoulos ◽  
Filippo Maglia ◽  
Felix Schmidt-Stein ◽  
Jan P. Schmidt ◽  
Harry E. Hoster
Keyword(s):  
Solid Electrolyte ◽  
Pyrolytic Graphite ◽  
Solid Electrolyte Interphase ◽  
Highly Oriented Pyrolytic Graphite ◽  
Model Study

Effects of Wet Chemical Oxidation on Surface Functionalization and Morphology of Highly Oriented Pyrolytic Graphite

2020 ◽  
Author(s):  
Mikhail Trought ◽  
Isobel Wentworth ◽  
Timothy Leftwich ◽  
Kathryn Perrine
Keyword(s):  
Surface Functionalization ◽  
Functional Group ◽  
Pyrolytic Graphite ◽  
Surface Oxidation ◽  
Chemical Oxidation ◽  
Synthesis Methods ◽  
Acid Solutions ◽  
Highly Oriented Pyrolytic Graphite ◽  
Wet Chemical ◽  
Surface Morphologies

The knowledge of chemical functionalization for area selective deposition (ASD) is crucial for designing the next generation heterogeneous catalysis. Surface functionalization by oxidation was studied on the surface of highly oriented pyrolytic graphite (HOPG). The HOPG surface was exposed to with various concentrations of two different acids (HCl and HNO3). We show that exposure of the HOPG surface to the acid solutions produce primarily the same -OH functional group and also significant differences the surface topography. Mechanisms are suggested to explain these strikingly different surface morphologies after surface oxidation. This knowledge can be used to for ASD synthesis methods for future graphene-based technologies.

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