Sulfur-Polypyrrole Composite Cathodes for Lithium-Sulfur Batteries

2012 ◽  
Vol 159 (9) ◽  
pp. A1420-A1424 ◽  
Author(s):  
Yongzhu Fu ◽  
Yu-Sheng Su ◽  
Arumugam Manthiram
Keyword(s):  
Composite Cathodes ◽  
Lithium Sulfur Batteries ◽  
Polypyrrole Composite ◽  
Lithium Sulfur

scholarly journals Cathode porosity is a missing key parameter to optimize lithium-sulfur battery energy density

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Ning Kang ◽  
Yuxiao Lin ◽  
Li Yang ◽  
Dongping Lu ◽  
Jie Xiao ◽  
...  
Keyword(s):  
Energy Density ◽  
Lithium Ion ◽  
Carbon Matrix ◽  
Reversible Capacity ◽  
High Energy ◽  
Carbon Composite ◽  
Composite Cathodes ◽  
Lithium Sulfur Batteries ◽  
Lithium Sulfur ◽  
Key Parameter

Abstract While high sulfur loading has been pursued as a key parameter to build realistic high-energy lithium-sulfur batteries, less attention has been paid to the cathode porosity, which is much higher in sulfur/carbon composite cathodes than in traditional lithium-ion battery electrodes. For high-energy lithium-sulfur batteries, a dense electrode with low porosity is desired to minimize electrolyte intake, parasitic weight, and cost. Here we report the profound impact on the discharge polarization, reversible capacity, and cell cycling life of lithium-sulfur batteries by decreasing cathode porosities from 70 to 40%. According to the developed mechanism-based analytical model, we demonstrate that sulfur utilization is limited by the solubility of lithium-polysulfides and further conversion from lithium-polysulfides to Li2S is limited by the electronically accessible surface area of the carbon matrix. Finally, we predict an optimized cathode porosity to maximize the cell level volumetric energy density without sacrificing the sulfur utilization.

High Mass Loading Copper Sulfide Based Composite Cathodes for All-Solid-State Lithium Sulfur Batteries Enables High Volumetric Capacity

2020 ◽  
Vol MA2020-01 (4) ◽  
pp. 558-558
Author(s):  
Seyed milad Hosseini ◽  
Seitaro Ito ◽  
Yuichi Aihara ◽  
Alberto Varzi ◽  
Stefano Passerini
Keyword(s):  
Solid State ◽  
Copper Sulfide ◽  
High Mass ◽  
Mass Loading ◽  
Volumetric Capacity ◽  
Composite Cathodes ◽  
Lithium Sulfur Batteries ◽  
Lithium Sulfur

In situ sulfur deposition route to obtain sulfur–carbon composite cathodes for lithium–sulfur batteries

2014 ◽  
Vol 2 (12) ◽  
pp. 4316-4323 ◽  
Author(s):  
W. G. Wang ◽  
X. Wang ◽  
L. Y. Tian ◽  
Y. L. Wang ◽  
S. H. Ye
Keyword(s):  
Reversible Capacity ◽  
Carbon Composite ◽  
Cycle Performance ◽  
Carbon Composites ◽  
Stable Cycle ◽  
Sulfur Deposition ◽  
Composite Cathodes ◽  
Lithium Sulfur Batteries ◽  
Lithium Sulfur

Sulfur–carbon composites were prepared by an in situ sulfur deposition route developed for the heterogeneous nucleation of sulfur into nanopores of conductive carbon black (CCB) by fumigation of Na2S4/CCB powder with HCl. The sulfur–carbon composites demonstrate enhanced reversible capacity and stable cycle performance.

scholarly journals Mesoporous hollow carbon spheres for lithium–sulfur batteries: distribution of sulfur and electrochemical performance

2016 ◽  
Vol 7 ◽  
pp. 1229-1240 ◽  
Author(s):  
Anika C Juhl ◽  
Artur Schneider ◽  
Boris Ufer ◽  
Torsten Brezesinski ◽  
Jürgen Janek ◽  
...  
Keyword(s):  
High Vacuum ◽  
Cycling Performance ◽  
Carbon Spheres ◽  
X Ray Diffraction ◽  
Composite Cathodes ◽  
Lithium Sulfur Batteries ◽  
Cavity Filling ◽  
Hollow Carbon ◽  
Hollow Carbon Spheres ◽  
Lithium Sulfur

Hollow carbon spheres (HCS) with a nanoporous shell are promising for the use in lithium–sulfur batteries because of the large internal void offering space for sulfur and polysulfide storage and confinement. However, there is an ongoing discussion whether the cavity is accessible for sulfur. Yet no valid proof of cavity filling has been presented, mostly due to application of unsuitable high-vacuum methods for the analysis of sulfur distribution. Here we describe the distribution of sulfur in hollow carbon spheres by powder X-ray diffraction and Raman spectroscopy along with results from scanning electron microscopy and nitrogen physisorption. The results of these methods lead to the conclusion that the cavity is not accessible for sulfur infiltration. Nevertheless, HCS/sulfur composite cathodes with areal sulfur loadings of 2.0 mg·cm−2 were investigated electrochemically, showing stable cycling performance with specific capacities of about 500 mAh·g−1 based on the mass of sulfur over 500 cycles.

Enhanced Cycling Stability of Lithium Sulfur Batteries Using Sulfur–Polyaniline–Graphene Nanoribbon Composite Cathodes

2014 ◽  
Vol 6 (17) ◽  
pp. 15033-15039 ◽  
Author(s):  
Lei Li ◽  
Gedeng Ruan ◽  
Zhiwei Peng ◽  
Yang Yang ◽  
Huilong Fei ◽  
...  
Keyword(s):  
Graphene Nanoribbon ◽  
Cycling Stability ◽  
Composite Cathodes ◽  
Lithium Sulfur Batteries ◽  
Lithium Sulfur
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