Phase Structure, Electrochemical Properties and Cyclic Characteristic of a Rhombohedral-Type Single-Phase Nd2MgNi9Hydrogen Storage Alloy

2016 ◽  
Vol 163 (7) ◽  
pp. A1474-A1483 ◽  
Author(s):  
Wenkai Du ◽  
Lu Zhang ◽  
Yuan Li ◽  
Yumeng Zhao ◽  
Shuqin Yang ◽  
...  
2003 ◽  
Vol 352 (1-2) ◽  
pp. 158-162 ◽  
Author(s):  
S.K. Zhang ◽  
K.Y. Shu ◽  
Y.Q. Lei ◽  
G.L. Lü ◽  
Q.D. Wang

2019 ◽  
Vol 37 (12) ◽  
pp. 1305-1311 ◽  
Author(s):  
Yiming Li ◽  
Zhuocheng Liu ◽  
Guofang Zhang ◽  
Yanghuan Zhang ◽  
Huiping Ren

2002 ◽  
Vol 38 (5) ◽  
pp. 2256-2258 ◽  
Author(s):  
Y. Okada ◽  
K. Kudo ◽  
N. Yoshida ◽  
M. Fuyama ◽  
H. Hoshiya

2014 ◽  
Vol 28 (06) ◽  
pp. 1450043 ◽  
Author(s):  
M. SALEHI ◽  
A. SAIDI ◽  
M. AHMADIAN ◽  
K. RAEISSI

Nanocrystalline Ni – Co alloys are electrodeposited by direct (DC) and pulse current (PC) in an electrolyte solution which consisted of nickel sulfate, cobalt sulfate and boric acid. Electrodeposition parameters including current density, electrolyte pH and pulse times in a single electrolyte bath were changed. XRD pattern showed that the structure of the alloys depends on Co content and the synthesis parameter and changed from single phase structure (fcc) to dual phase structure (fcc + hcp). The Co content in the deposited alloys declined from 70 at.% to 50 at.% by increasing in direct current from 70 mA/cm2 to 115 mA/cm2 and also decreased from 75 at.% to 33 at.% with decrease in pH values from 4 to 2. By applying PC the Co content changed from 76 at.% to 41 at.%. Magnetic properties measurements showed the saturation magnetization (Ms) increased with increasing the Co content. There was no significant effect on coercivity values (Hc) with change in Co content and about 40 Oe was obtained for all samples. The grain size of deposited alloys obtained between 24–58 nm and 15–21 nm by applying DC and PC, respectively.


2015 ◽  
Vol 152 ◽  
pp. 265-273 ◽  
Author(s):  
Yumeng Zhao ◽  
Shumin Han ◽  
Yuan Li ◽  
Jingjing Liu ◽  
Lu Zhang ◽  
...  

2021 ◽  
Author(s):  
Maitê Medeiros de Santana e Silva ◽  
Rafael A. Raimundo ◽  
Luciena S. Ferreira ◽  
Daniel A. Macedo ◽  
Marco A. Morales ◽  
...  

Abstract In this paper we studied the production of single-phase NiFe2O4 powders synthesized by the complexation method combining EDTA-citrate. The structural, optical, magnetic, and electrochemical properties of were studied as a function of the synthesis pH. Powders obtained with pH 9 showed larger crystallite sizes (73 nm) in comparison to those produced with pH 3 (21 nm). The band gap energy was found to be inversely proportional to the crystal size (1.85 and 2.0 eV for powders with crystallites of 73 nm and 21 nm, respectively). The synthesized materials presented an inverse spinel crystalline structure. The samples obtained at higher pH conditions were found to be fully magnetic saturated with a saturation magnetization of 50.5 emu g-1, while that synthesized at pH 3 is unsaturated with a maximum measured magnetization of 48.4 emu g-1. Cyclic voltammetry and charge-discharge curves indicate a battery-type behavior, with an better performance for the material obtained at pH 9 (65 C g-1 at a specific current of 3 A g-1). The remarkable performance of the associated with its by microstructural characteristics (particle size, particle agglomeration and porosity). This work offers an alternative synthesis route for obtaining spinel ferrites for magnetic and electrochemical applications.


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