Abnormal Photoelectric and Magnetic Properties of Three-Dimensional Super-Structure Sb Nanocages and One-Dimensional Nanowires

2013 ◽  
Vol 2 (3) ◽  
pp. Q45-Q49 ◽  
Author(s):  
Wei Li ◽  
Yanchao Mao ◽  
Mingyang Li ◽  
Yiming Li ◽  
Yexiang Tong ◽  
...  
2014 ◽  
Vol 70 (12) ◽  
pp. 1169-1173 ◽  
Author(s):  
Hong Shen

A one-dimensional cyanide-bridged coordination polymer, poly[[aquadi-μ-cyanido-κ4C:N-hexacyanido-κ6C-(dimethylformamide-κO)bis(3,4,7,8-tetramethyl-1,10-phenanthroline-κ2N,N′)terbium(III)molybdate(V)] 4.5-hydrate], [MoTb(CN)8(C16H16N2)2(C3H7NO)(H2O)]·4.5H2O}n, has been prepared and characterized through IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. The compound consists of one-dimensional chains in which cationic [Tb(tmphen)2(DMF)(H2O)]3+(tmphen is 3,4,7,8-tetramethyl-1,10-phenanthroline) and anionic [MoV(CN)8]3−units are linked in an alternating fashion through bridging cyanide ligands. Neighbouring chains are connected by three types of hydrogen bonds (O—H...O, O—H...N and C—H...O) and by π–π interactions to form a three-dimensional supramolecular structure. In addition, magnetic investigations show that ferromagnetic interactions exist in the compound.


2013 ◽  
Vol 66 (8) ◽  
pp. 963 ◽  
Author(s):  
Jiong Wen ◽  
Jing-Yun Hu ◽  
E. Carolina Sañudo ◽  
Min Chen ◽  
Chun-Sen Liu

Five new Cu(ii) complexes have been prepared by employing 2,3-naphthalenedicarboxylic acid (H2ndc) and different N-donor co-ligands, namely, [Cu(ndc)(H2O)]n (1), [Cu(ndc)(H2O)2]n (2), {[Cu1.5(ndc)(OH)(H2O)2]·2.5H2O}n (3), {[Cu(ndc)(phen)(H2O)]·CH3OH}n (4) (phen = 1,10-phenanthroline), and {[Cu2(H0.5ndc)2(4bpy)3](ClO4)·2H2O}n (5) (4bpy = 4,4′-bipyridine). Complex 1 displays a two-dimensional (2D) (4,6)-connected (32.44)2(34.42.64.75)(34.43.64.74) coordination network. Complex 2 shows a 2D 3-connected hcb network which is further interlinked via the interlayered C–H⋯π interactions to result in a three-dimensional (3D) supramolecular network. Complex 3 is a one-dimensional (1D) coordination chain which is further interlinked by the C–H⋯π and π⋯π interactions to lead to the formation of the final 3D supramolecular network. When the N-donor co-ligands phen and 4,4′-bipyridine (4bpy) were introduced, the 1D complex 4 and the 4-connected sql layered complex 5 were constructed, respectively. The final supramolecular frameworks of 4 (2D) and 5 (3D) are extended by hydrogen-bonding and C–H⋯π interactions. The structural diversity of the complexes was triggered by different reaction conditions and N-donor co-ligands. Moreover, the magnetic properties of the complexes have also been investigated and discussed.


2010 ◽  
Vol 148-149 ◽  
pp. 1036-1041
Author(s):  
Shuang Juan Shen ◽  
Li Qin Jiang ◽  
Ke Hua Zhong ◽  
Zhi Gao Chen ◽  
Zhi Gao Huang

Based on Monte Carlo (MC) simulation, the magnetization behavior of mixed ferrimagnetic spin system with single-ion anisotropy under external field is investigated. It is assumed that the element of the mixed system is composed of spin-1 and spin-3/2 by turns. The simulated results indicate that there exist the magnetization curves at the ground state on the one-dimensional spin chain, two-dimensional spin system as well as three-dimensional spin system. It found that the size, anisotropy constant and spin configurations influence evidently the magnetic properties of the mixed system. Moreover, the magnetic plateaus and the phase diagrams of the systems can be well interpreted in terms of the simple calculation of energy.


Author(s):  
Peter Sterling

The synaptic connections in cat retina that link photoreceptors to ganglion cells have been analyzed quantitatively. Our approach has been to prepare serial, ultrathin sections and photograph en montage at low magnification (˜2000X) in the electron microscope. Six series, 100-300 sections long, have been prepared over the last decade. They derive from different cats but always from the same region of retina, about one degree from the center of the visual axis. The material has been analyzed by reconstructing adjacent neurons in each array and then identifying systematically the synaptic connections between arrays. Most reconstructions were done manually by tracing the outlines of processes in successive sections onto acetate sheets aligned on a cartoonist's jig. The tracings were then digitized, stacked by computer, and printed with the hidden lines removed. The results have provided rather than the usual one-dimensional account of pathways, a three-dimensional account of circuits. From this has emerged insight into the functional architecture.


2008 ◽  
Vol 67 (1) ◽  
pp. 51-60 ◽  
Author(s):  
Stefano Passini

The relation between authoritarianism and social dominance orientation was analyzed, with authoritarianism measured using a three-dimensional scale. The implicit multidimensional structure (authoritarian submission, conventionalism, authoritarian aggression) of Altemeyer’s (1981, 1988) conceptualization of authoritarianism is inconsistent with its one-dimensional methodological operationalization. The dimensionality of authoritarianism was investigated using confirmatory factor analysis in a sample of 713 university students. As hypothesized, the three-factor model fit the data significantly better than the one-factor model. Regression analyses revealed that only authoritarian aggression was related to social dominance orientation. That is, only intolerance of deviance was related to high social dominance, whereas submissiveness was not.


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