Deposition of Copper Nanofilms by Surface-Limited Redox Replacement of Underpotentially Deposited Lead on Polycrystalline Gold

2018 ◽  
Vol 166 (1) ◽  
pp. D3001-D3005
Author(s):  
Johannes Dornhof ◽  
Gerald A. Urban ◽  
Jochen Kieninger
Author(s):  
Faro Hechenberger ◽  
Siegfried Kollotzek ◽  
Lorenz Ballauf ◽  
Felix Duensing ◽  
Milan Ončák ◽  
...  

Collisions of N+ and N2+ with C3 hydrocarbons, represented by a self assembled monolayer of propanethiol on a polycrystalline gold surface, were investigated by experiments over the incident energy range between 5 eV and 100 eV.


2009 ◽  
Vol 13 (01) ◽  
pp. 35-40 ◽  
Author(s):  
Rudy Martin ◽  
Roberto Cao ◽  
Ana M. Esteva ◽  
Franz-Peter Montforts

A new ruthenium(II) porphyrin disulphide derivative, [ Ru ( Pds )( CO )], was obtained from ruthenium(II)(carbonyl)deuteroporphyrin(IX), [ Ru ( DPdc )( CO )] and cystamine. The interaction of this complex with nitric oxide was studied spectrophotometrically and a bathochromic shift of the charge transfer band and considerable change in the α and β bands of the complex were observed. According to the IR spectrum, the product of this interaction is [ Ru ( DmDP )( NO +)( NO 2-)]. [ Ru ( Pds )( CO )] was then self-assembled on polycrystalline gold and characterized by X-ray photoelectron spectroscopy. [ Ru ( Pds )( CO )] was also self-assembled on gold electrode beads and its interaction with nitric oxide in aqueous solution was studied by cyclic voltammetry. A shift in the ruthenium redox process and a new irreversible cathodic peak at -0.59 V were observed, both indicating coordination of NO .


2005 ◽  
Vol 17 (14) ◽  
pp. 1251-1259 ◽  
Author(s):  
Rafaela Fernanda Carvalhal ◽  
Renato Sanches Freire ◽  
Lauro Tatsuo Kubota

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