scholarly journals Thermodynamic Treatment of Multicomponent Fused Salt Solutions: Common Anion Reactive Systems Approximation

1990 ◽  
Vol 1990-17 (1) ◽  
pp. 68-97
Author(s):  
S.N. Flengas
Keyword(s):  
Reactive Systems ◽  
Salt Solutions ◽  
Common Anion ◽  
Fused Salt

Thermodynamic treatment of multicomponent fused salt solutions: common anion reactive systems approximation

1991 ◽  
Vol 69 (5) ◽  
pp. 870-883 ◽  
Author(s):  
S. N. Flengas
Keyword(s):  
Molten Salt ◽  
Binary Systems ◽  
Reactive Systems ◽  
Thermodynamic Cycle ◽  
Ternary Systems ◽  
Salt Solutions ◽  
Partial Molar Property ◽  
Salt Systems ◽  
Common Anion ◽  
Fused Salt

From a modified F.F.G. (1) thermodynamic cycle, equations have been developed from which the molar and partial molar excess thermodynamic properties of j-component molten salt solutions may be predicted from binary data.The theory is applicable to reactive molten salt systems and particularly to charge asymmetric fused salt solutions with common anions.It is shown that for a system having j + 1 components, such as [Formula: see text], any molar or partial molar property of mixing for MXq, may be calculated from available data on corresponding j-binary systems, such as MXq–AX, MXq–BX, and [Formula: see text].The equations are of the general form,[Formula: see text]The latter is applicable only when the multicomponent and the binary solutions have the same MXq content and same temperature.The theoretical expressions have been found to predict quite well available data on ternary and quarternary systems. New composition parameters for expressing the compositions in quarternary and quinary systems have been established. Key words: molten salt solutions, multicomponent systems, ternary systems, quarternary systems, quinary systems.

Nature of sulfur species in fused salt solutions

1971 ◽  
Vol 93 (24) ◽  
pp. 6691-6693 ◽  
Author(s):  
D. M. Gruen ◽  
R. L. McBeth ◽  
A. J. Zielen
Keyword(s):  
Salt Solutions ◽  
Sulfur Species ◽  
Fused Salt
Sign in / Sign up

Export Citation Format

Share Document