UV-Curable Polyester Acrylate Coatings: Barrier Properties and Ion Transport Kinetics Along Polymer/Metal Interfaces

2011 ◽  
Vol 158 (6) ◽  
pp. C185 ◽  
Author(s):  
R. Posner ◽  
P. E. Sundell ◽  
T. Bergman ◽  
P. Roose ◽  
M. Heylen ◽  
...  
Keyword(s):  
Ion Transport ◽  
Barrier Properties ◽  
Transport Kinetics ◽  
Uv Curable ◽  
Polyester Acrylate ◽  
Polymer Metal ◽  
Metal Interfaces

scholarly journals Preparation of alkali-resistant PVDF membranes via immobilization of sodium lauryl sulfate (SDS) on surface

2021 ◽  
Vol 11 (3) ◽  
Author(s):  
Gongpu Wen ◽  
Kun Chen ◽  
Yanhong Zhang ◽  
Yue Zhou ◽  
Jun Pan ◽  
...  
Keyword(s):  
Sodium Lauryl Sulfate ◽  
Alkali Treatment ◽  
Membrane Surface ◽  
Alkali Resistance ◽  
Lauryl Sulfate ◽  
Uv Curable ◽  
Pvdf Membrane ◽  
Glycol Diacrylate ◽  
Polyester Acrylate ◽  
Uv Curable Resin

AbstractA novel strategy was proposed to fabricate alkali-resistant PVDF membrane via sodium lauryl sulfate (SDS) attached to the surface of membrane and immobilized by UV-curable polyester acrylate and tri(propylene glycol) diacrylate (TPGDA). The attached anionic surfactant, SDS, on the membrane surface can resist the alkali corrosion by NaOH, and the curing of the resin can immobilize the SDS on the membrane firmly. Due to the unique alkali resistance of SDS and resin formed, the UV-curable resin-modified PVDF membrane showed greatly enhanced alkali-resistant ability. Characterization of SEM and FTIR showed that polyester acrylate and TPGDA were cured successfully under the action of 1-hydroxycyclohexyl phenyl ketone (184) and ultraviolet light. Whiteness, differential scanning calorimeter and X-ray photoelectron spectrometer characterization showed that the modified PVDF membrane had a lower degree of dehydrofluorination than the pristine PVDF membrane after alkali treatment. Results of the detailed alkali-resistant analysis indicated that the F/C ratio of the UV-curable resin-modified PVDF membrane decreased by 2.6% after alkali treatment compared to pristine PVDF membrane decreased by 19.28%. The alkali-resistant performance was mainly attributed to the immobilized SDS. This study provided a facile and scalable method for designing alkali-resistant PVDF membrane, which shows a promising potential in the treatment of alkaline wastewater and alkaline-cleaning PVDF membrane.

Model Compound Approach for Polymer-Metal InterFaces: ESCA Studies

1984 ◽  
Vol 40 ◽  
Author(s):  
P. N. Sanda ◽  
J. W. Bartha ◽  
B. D. Silverman ◽  
P. S. Ho ◽  
A. R. Rossi
Keyword(s):  
Model Compound ◽  
Amino Groups ◽  
Ether Linkage ◽  
Cu Films ◽  
Polymer Metal ◽  
Terminal Amino ◽  
Metal Interfaces ◽  
Imide Group

AbstractESCA studies of two molecules which are similar in structure to the PMDA and ODA constituents of the PMDA-ODA polyimide monomer are discussed. Their interaction with in-situ evaporated Cr and Cu films are compared. The PMDA model compound interacts with Cr through the imide group, while very little interaction is observed with Cu. The ODA model compound (oxydianiline) interacts with Cr via the ether linkage and the terminal amino groups, whereas very little interaction is observed with Cu.

Charactervation of Adhesion in Thin-Film Materials by the Blister Test

1992 ◽  
Vol 276 ◽  
Author(s):  
Y Z. Chu ◽  
H. S. Jeong ◽  
R. C. White ◽  
C. J. Durning
Keyword(s):  
Fluid Pressure ◽  
Structural Features ◽  
Adhesion Energy ◽  
Pressure Data ◽  
Blister Test ◽  
Constant Rate ◽  
Polymer Metal ◽  
Metal Interfaces ◽  
Peel Tests ◽  
Microscopic Dynamic

ABSTRACTIn this work a blister test is applied to study the adhesion of thin films to substrates. In the blister test one injects a fluid at constant rate at the interface between the substrate and an overlayer to create a “blister”. The fluid pressure is measured as function of time. An analysis gives a reliable way of calculating the adhesion energy Ga. from the time-dependent pressure data. The method was applied to a variety of systems including polymer/polymer, polymer/silicon and polymer/metal interfaces. The results show that the test is very sensitive and is able to determine small adhesion energies inaccessible in conventional peel tests. This work demonstrates that the blister test provides a means of relating the mechanical strength of an interface to its microscopic dynamic and structural features.

Studies on polymer-metal interfaces

Polymer ◽  
1999 ◽  
Vol 40 (14) ◽  
pp. 3989-3994 ◽  
Author(s):  
Dong Ha Kim ◽  
Won Ho Jo
Keyword(s):  
Polymer Metal ◽  
Metal Interfaces

Interfacial Versus Cohesive Failure on Polymer-Metal Interfaces in Electronic Packaging—Effects of Interface Roughness

2002 ◽  
Vol 124 (2) ◽  
pp. 127-134 ◽  
Author(s):  
Qizhou Yao ◽  
Jianmin Qu
Keyword(s):  
Surface Roughness ◽  
Fracture Mechanics ◽  
Electronic Packaging ◽  
Interfacial Adhesion ◽  
Interfacial Strength ◽  
Interface Roughness ◽  
Cohesive Failure ◽  
Mechanics Model ◽  
Polymer Metal ◽  
Metal Interfaces

Debonding of polymer-metal interfaces often involves both interfacial and cohesive failure. Since the cohesive strength of polymers is usually much greater than the polymer-metal interfacial strength, cohesive failure near the interface is usually desired for enhancing the interfacial adhesion. Roughened surfaces generally produce more cohesive failure; therefore, they are used commonly in practice to obtain better adhesion. This paper develops a fracture mechanics model that can be used to quantitatively predict the amount of cohesive failure once the surface roughness data are given. An epoxy/Al interface was investigated using this fracture mechanics model. The predicted amount of cohesive failure as a function of surface roughness compares very well with the experimentally measured values. It is believed that this model can be extended to other polymer–metal interfaces. Contributed by the Electronic and Photonic Packaging Division for publication in the JOURNAL OF ELECTRONIC PACKAGING. Manuscript received by the EPPD.

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