Microstructural Effects on the Oxygen Exchange Kinetics of La0.7Sr0.3MnO3 Thin Films

2019 ◽  
Vol 35 (1) ◽  
pp. 2063-2075 ◽  
Author(s):  
Lu Yan ◽  
Balasubramaniam Kavaipatti ◽  
Kee-Chul Chang ◽  
Hoydoo You ◽  
Paul Salvador
Keyword(s):  
Thin Films ◽  
Oxygen Exchange ◽  
Microstructural Effects ◽  
Exchange Kinetics ◽  
Kinetics Of

Fast oxygen exchange kinetics of pore-free Bi1−xSrxFeO3−δ thin films

2011 ◽  
Vol 13 (37) ◽  
pp. 16530 ◽  
Author(s):  
Anja Wedig ◽  
Rotraut Merkle ◽  
Benjamin Stuhlhofer ◽  
Hanns-Ulrich Habermeier ◽  
Joachim Maier ◽  
...  
Keyword(s):  
Thin Films ◽  
Oxygen Exchange ◽  
Exchange Kinetics ◽  
Kinetics Of

Oxygen Exchange Kinetics of Epitaxial PrBaCo2O5+x and LaBaCo2O5+x Thin Films

2008 ◽  
Author(s):  
Allan Jacobson ◽  
Xuening Jiang ◽  
Susan Wang ◽  
Guntae Kim ◽  
Jian Liu ◽  
...  
Keyword(s):  
Thin Films ◽  
Oxygen Exchange ◽  
Exchange Kinetics ◽  
Kinetics Of

scholarly journals Oxygen exchange kinetics of epitaxial PrBaCo2O5+δ thin films

2006 ◽  
Vol 88 (2) ◽  
pp. 024103 ◽  
Author(s):  
G. Kim ◽  
S. Wang ◽  
A. J. Jacobson ◽  
Z. Yuan ◽  
W. Donner ◽  
...  
Keyword(s):  
Thin Films ◽  
Oxygen Exchange ◽  
Exchange Kinetics ◽  
Kinetics Of

scholarly journals Influence of Heterointerfaces on the Kinetics of Oxygen Surface Exchange on Epitaxial La1.85Sr0.15CuO4 Thin Films

2021 ◽  
Vol 11 (9) ◽  
pp. 3778
Author(s):  
Gene Yang ◽  
So-Yeun Kim ◽  
Changhee Sohn ◽  
Jong K. Keum ◽  
Dongkyu Lee
Keyword(s):  
Thin Films ◽  
Oxygen Vacancies ◽  
Elevated Temperatures ◽  
Surface Exchange ◽  
Electrical Conductivity Relaxation ◽  
Exchange Kinetics ◽  
Relaxation Curves ◽  
Kinetics Of ◽  
Oxygen Surface Exchange ◽  
Oxygen Surface

Considerable attention has been directed to understanding the influence of heterointerfaces between Ruddlesden–Popper (RP) phases and ABO3 perovskites on the kinetics of oxygen electrocatalysis at elevated temperatures. Here, we report the effect of heterointerfaces on the oxygen surface exchange kinetics by employing heteroepitaxial oxide thin films formed by decorating LaNiO3 (LNO) on La1.85Sr0.15CuO4 (LSCO) thin films. Regardless of LNO decoration, tensile in-plane strain on LSCO films does not change. The oxygen surface exchange coefficients (kchem) of LSCO films extracted from electrical conductivity relaxation curves significantly increase with partial decorations of LNO, whereas full LNO coverage leads to the reduction in the kchem of LSCO films. The activation energy for oxygen exchange in LSCO films significantly decreases with partial LNO decorations in contrast with the full coverage of LNO. Optical spectroscopy reveals the increased oxygen vacancies in the partially covered LSCO films relative to the undecorated LSCO film. We attribute the enhanced oxygen surface exchange kinetics of LSCO to the increased oxygen vacancies by creating the heterointerface between LSCO and LNO.

Ultrafast oxygen exchange kinetics on highly epitaxial PrBaCo2O5+δ thin films

2012 ◽  
Vol 100 (19) ◽  
pp. 193903 ◽  
Author(s):  
Jian Liu ◽  
Gregory Collins ◽  
Ming Liu ◽  
Chonglin Chen ◽  
Jie He ◽  
...  
Keyword(s):  
Thin Films ◽  
Oxygen Exchange ◽  
Exchange Kinetics

Surface Oxygen Exchange Kinetics of Solid Oxide Ion Conductors

1993 ◽  
pp. 167-180 ◽  
Author(s):  
B. A. Boukamp ◽  
I. C. Vinke ◽  
K. J. Vries ◽  
A. J. Burggraaf
Keyword(s):  
Oxygen Exchange ◽  
Solid Oxide ◽  
Surface Oxygen ◽  
Exchange Kinetics ◽  
Kinetics Of ◽  
Oxide Ion Conductors ◽  
Oxide Ion ◽  
Ion Conductors
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