Performance of Sm0.95Ce0.05Fe1-xNixO3-δPerovskite as Anode Materials under Methane Fuel for Low Temperature Solid Oxide Fuel Cells (LT -SOFC)

2019 ◽  
Vol 35 (1) ◽  
pp. 1539-1544 ◽  
Author(s):  
Syed M. Bukhari ◽  
Javier B. Giorgi
Author(s):  
Bo Feng ◽  
Cheng-Yang Wang ◽  
Bin Zhu

In this paper, novel anode materials for solid oxide fuel cells which can directly operate liquid fuels at intermediate or low temperature were investigated. These materials were based on the activated carbons supported transition metal catalysts (AC-M) and the solid carbonate-ceria composite (SCC) materials, which were prepared via the sol-gel route. The SCCs possess both oxide-ion and proton conductivity, being used as multi-ion conductors. Activated carbons supported transition metals were used to improve the characters of anode materials and especially to enhance the anode catalyst function to liquid fuels, e.g., methanol. The internal reforming of liquid fuels was proved. There is no external reforming system needed. We used also the chemical methods to improve the commercial activated carbons. The microstructure, conductivity and electrochemical properties of anode materials were investigated as functions of the activated carbon pre-treating condition. Using these novel materials, the power intensity of 0.2 W/cm2 was achieved for fuel cells directly operating the methanol at 600 °C.


2016 ◽  
Vol 163 (10) ◽  
pp. F1198-F1205 ◽  
Author(s):  
A. Mohammed Hussain ◽  
Ke-Ji Pan ◽  
Ian A. Robinson ◽  
Thomas Hays ◽  
Eric D. Wachsman

2019 ◽  
Vol 45 (17) ◽  
pp. 21688-21697 ◽  
Author(s):  
Saleem Mumtaz ◽  
M. Ashfaq Ahmad ◽  
Rizwan Raza ◽  
M. Ajmal Khan ◽  
M. Naeem Ashiq ◽  
...  

2015 ◽  
Vol 30 (10) ◽  
pp. 1043
Author(s):  
CHANG Xi-Wang ◽  
CHEN Ning ◽  
WANG Li-Jun ◽  
BIAN Liu-Zhen ◽  
LI Fu-Shen ◽  
...  

2019 ◽  
Vol 2 (2) ◽  
pp. 1210-1220 ◽  
Author(s):  
Sun Jae Kim ◽  
Taner Akbay ◽  
Junko Matsuda ◽  
Atsushi Takagaki ◽  
Tatsumi Ishihara

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1715
Author(s):  
Lubov Skutina ◽  
Elena Filonova ◽  
Dmitry Medvedev ◽  
Antoine Maignan

The chemical design of new functional materials for solid oxide fuel cells (SOFCs) is of great interest as a means for overcoming the disadvantages of traditional materials. Redox stability, carbon deposition and sulfur poisoning of the anodes are positioned as the main processes that result in the degradation of SOFC performance. In this regard, double perovskite molybdates are possible alternatives to conventional Ni-based cermets. The present review provides the fundamental properties of four members: Sr2NiMoO6-δ, Sr2MgMoO6-δ, Sr2FeMoO6-δ and Sr2Fe1.5Mo0.5O6-δ. These properties vary greatly depending on the type and concentration of the 3d-element occupying the B-position of A2BB’O6. The main emphasis is devoted to: (i) the synthesis features of undoped double molybdates, (ii) their electrical conductivity and thermal behaviors in both oxidizing and reducing atmospheres, as well as (iii) their chemical compatibility with respect to other functional SOFC materials and components of gas atmospheres. The information provided can serve as the basis for the design of efficient fuel electrodes prepared from complex oxides with layered structures.


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