Electrocatalytic Activities of La0.6Ca0.4CoO3 and La0.6Ca0.4CoO3-Carbon Composites Toward the Oxygen Reduction Reaction in Concentrated Alkaline Electrolytes

2011 ◽  
Vol 158 (5) ◽  
pp. A597 ◽  
Author(s):  
XiaoXia Li ◽  
Wei Qu ◽  
JiuJun Zhang ◽  
HaiJiang Wang
2016 ◽  
Vol 3 (10) ◽  
pp. 1570-1579 ◽  
Author(s):  
Ana M. Gómez-Marín ◽  
José Luiz Bott-Neto ◽  
João B. Souza ◽  
Tiago L. Silva ◽  
Watson Beck ◽  
...  

2016 ◽  
Vol 187 ◽  
pp. 291-300 ◽  
Author(s):  
Luis Alberto Estudillo-Wong ◽  
Yun Luo ◽  
Jesús Adrián Díaz-Real ◽  
Nicolas Alonso-Vante

2012 ◽  
Vol 535-537 ◽  
pp. 2104-2107 ◽  
Author(s):  
Lei Ding ◽  
Li Xu ◽  
Ling Ling Liu ◽  
Jin Li Qiao ◽  
Yu Yu Liu

Effect of heat-treatment on the activity of nickel phthalocyanine (NiPc) catalysts for oxygen reduction reaction (ORR) was studied in both acid and alkaline electrolytes. The catalytic activity was found to depend strongly on the electrolyte and heat treatment temperature. High ORR activity was demonstrated on 40%NiPc/C electrode in 0.1M KOH solution, and the heat-treatment of 800oC is optimal for the catalyst synthesized. Further using rotating disk electrode (RDE) measurements and Koutechy-Levich analysis, the overall electron transfer number in the catalyzed ORR on 40%NiPc/C was found to be 2.8, suggesting the catalyzed ORR proceeds via both the 2e- transfer reduction and the 4e- transfer reduction.


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