The Hydrogen Overvoltage and the Anodic Behavior of Tungsten in Aqueous Solutions of Potassium Hydroxide

1935 ◽  
Vol 67 (1) ◽  
pp. 71 ◽  
Author(s):  
M. de Kay Thompson ◽  
C. W. Rice
Keyword(s):  
Aqueous Solutions ◽  
Potassium Hydroxide ◽  
Anodic Behavior ◽  
Hydrogen Overvoltage

Anodic behavior of a BK8 type tungsten-cobalt alloy in organo-aqueous solutions of sodium nitrate

2000 ◽  
Vol 36 (3) ◽  
pp. 232-234
Author(s):  
A. V. Balmasov ◽  
N. B. Kozlova ◽  
S. A. Lilin ◽  
E. M. Rumyantsev
Keyword(s):  
Aqueous Solutions ◽  
Sodium Nitrate ◽  
Anodic Behavior ◽  
Cobalt Alloy

Molar Volumes and Heat Capacities of Aqueous Solutions of Potassium Hydroxide and for Water Ionization up to 573 K at 10 MPa

2017 ◽  
Vol 62 (9) ◽  
pp. 2959-2972 ◽  
Author(s):  
Lubomir Hnedkovsky ◽  
Sebastian Bochmann ◽  
Peter M. May ◽  
Glenn Hefter
Keyword(s):  
Aqueous Solutions ◽  
Potassium Hydroxide ◽  
Heat Capacities ◽  
Molar Volumes

scholarly journals Crevice Repassivation Potential of Alloy 22 in High-Nitrate Dust Deliquescence Type Environments

2007 ◽  
Author(s):  
Tiangan Lian ◽  
Gregory E. Gdowski ◽  
Phillip D. Hailey ◽  
Raul B. Rebak
Keyword(s):  
Aqueous Solutions ◽  
Crevice Corrosion ◽  
Anodic Behavior ◽  
Nitrate Ion ◽  
Electrochemical Tests ◽  
Desert Dust ◽  
Nitrate Ions ◽  
Alloy 22 ◽  
Low Humidity ◽  
High Chloride

The nitrate ion (NO3−) is an inhibitor for crevice corrosion of Alloy 22 (N06022) in chloride (Cl−) aqueous solutions. Naturally formed electrolytes may contain both chloride and nitrate ions. The higher the ratio R = [NO3−]/[Cl−] in the solution the stronger the inhibition of crevice corrosion. Atmospheric desert dust contains both chloride and nitrate salts, generally based on sodium (Na+) and potassium (K+). Some of these salts may deliquescence at relatively low humidity at temperatures on the order of 150°C and higher. The resulting deliquescent brines are highly concentrated and especially rich in nitrate. Electrochemical tests have been performed to explore the anodic behavior of Alloy 22 in high chloride high nitrate electrolytes at temperatures as high as 150°C at ambient atmospheres. Naturally formed brines at temperatures higher than 120°C do not induce crevice corrosion in Alloy 22 because they contain high levels of nitrate. The inhibitive effect of nitrate on crevice corrosion is still active for temperatures higher than 100°C.

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