Electrodeposition of Tungsten, Molybdenum and Double Carbides of Tungsten (Molybdenum) and Nickel (Cobalt) from Low-Temperature Halide-Oxide Melts

2019 ◽  
Vol 3 (35) ◽  
pp. 399-414 ◽  
Author(s):  
Hasbi B. Kushkhov ◽  
Marina N. N. Adamokova
2021 ◽  
Vol 279 ◽  
pp. 123633
Author(s):  
Yiqi Tang ◽  
Xin Qu ◽  
Beilei Zhang ◽  
Yan Zhao ◽  
Hongwei Xie ◽  
...  

2012 ◽  
Vol 70 ◽  
pp. 189-192 ◽  
Author(s):  
E. Meza ◽  
J. Ortiz ◽  
D. Ruíz-León ◽  
J.F. Marco ◽  
J.L. Gautier

2012 ◽  
Vol 3 (4) ◽  
pp. 524-531 ◽  
Author(s):  
Paul F. Ndione ◽  
Andres Garcia ◽  
N. Edwin Widjonarko ◽  
Ajaya K. Sigdel ◽  
K. Xerxes Steirer ◽  
...  

2007 ◽  
Vol 62 (12) ◽  
pp. 749-753
Author(s):  
Hasbi Kushkhov ◽  
Marina Adamokova ◽  
Vitalij Kvashin ◽  
Anzor Kardanov ◽  
Svetlana Gramoteeva

Iron, cobalt and nickel powders are used as binding components for the production of articles of tungsten carbide by the hot pressing method. This fact and the unique properties of binary carbides of tungsten-iron triad metals encouraged the search for new ways of their synthesis. In the present work, the attempt to synthezise binary tungsten-nickel (cobalt, iron) carbides in molten KCl-NaCl-CsCl at 823 K was made. As a result of voltammetry research, it was established that in eutectic KCl-NaCl-CsCl melts the deposition potentials ofWand Ni (Co, Fe) differ by 150 - 350 mV from each other, which makes their co-deposition difficult. It is possible to shift the deposition potentials of tungsten and metals of the iron triad metals towards each other by changing the acid-base properties of the melt. The products of electrolysis in these molten system were identified by X-ray analysis. They are mixtures of tungsten and nickel (cobalt, iron) carbides: Ni2W4C, W6C2.54; Co3W3C, Co6W6C, W2C, Co3C; FeW3C.


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