Carbon-Supported Pd-Co Alloy Electrocatalysts for Methanol Tolerant Oxygen Reduction

2019 ◽  
Vol 11 (1) ◽  
pp. 1379-1386 ◽  
Author(s):  
Wenming Wang ◽  
Hui Yang ◽  
Jianyu Cao Cao ◽  
Qinghong Huang ◽  
Zhiqing Zou ◽  
...  
2019 ◽  
Vol 16 (2) ◽  
pp. 613-619 ◽  
Author(s):  
Wenming M. Wang ◽  
Zhilin L. Li ◽  
Zhiqing Zou ◽  
Hui Yang ◽  
Songlin Feng

2008 ◽  
Vol 10 (9) ◽  
pp. 1396-1399 ◽  
Author(s):  
Wenming Wang ◽  
Qinghong Huang ◽  
Juanyin Liu ◽  
Zhiqing Zou ◽  
Zhilin Li ◽  
...  

Author(s):  
A. Mary Remona ◽  
K. L. N. Phani

Carbon-supported platinum and Pt–Pd alloy electrocatalysts with different Pt/Pd atomic ratios were synthesized by a microemulsion method at room temperature (metal loading is 10 wt %). The Pt–Pd/C bimetallic catalysts showed a single-phase fcc structure and the mean particle size of Pt–Pd/C catalysts was found to be lower than that of Pt/C. The methanol-tolerant studies of the catalysts were carried out by activity evaluation of oxygen reduction reaction (ORR) on Pt–Pd catalysts using a rotating disk electrode (RDE). The studies indicated that the order of methanol tolerance was found to be PtPd3/C>PtPd/C>Pt3Pd/C. The oxygen reduction activities of all Pt–Pd/C were considerably larger than that of Pt/C with respect to onset and overpotential values. The Pd-loaded catalysts shift the onset potential of ORR by 125 mVMSE, 53 mVMSE, and 41 mVMSE to less cathodic potentials for Pt3Pd/C, PtPd/C, and PtPd3/C, respectively, with reference to Pt/C and the Pt3Pd/C catalyst showed greater shift in the onset value than the other PtPd catalysts reported in literature. Moreover, the Pt–Pd/C catalysts exhibited much higher methanol tolerance during ORR than the Pt/C, assessing that these catalysts may function as a methanol-tolerant cathode catalysts in a direct methanol fuel cell.


ChemCatChem ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 1278-1285 ◽  
Author(s):  
Zhikang Bao ◽  
Hu Zhou ◽  
Xin Song ◽  
Yijing Gao ◽  
Guilin Zhuang ◽  
...  

2008 ◽  
Vol 182 (1) ◽  
pp. 91-94 ◽  
Author(s):  
Lifeng Cheng ◽  
Zhonghua Zhang ◽  
Wenxin Niu ◽  
Guobao Xu ◽  
Liande Zhu

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