The Mechanism of the Cathodic Hydrogen Evolution Reaction

1952 ◽  
Vol 99 (4) ◽  
pp. 169 ◽  
Author(s):  
J. O'M. Bockris ◽  
E. C. Potter
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Cathodic Hydrogen Evolution

Impedance spectra of the cathodic hydrogen evolution reaction on polycrystalline rhenium

2016 ◽  
Vol 41 (8) ◽  
pp. 4660-4669 ◽  
Author(s):  
R. Garcia-Garcia ◽  
J.G. Rivera ◽  
R. Antaño-Lopez ◽  
F. Castañeda-Olivares ◽  
G. Orozco
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Impedance Spectra ◽  
Cathodic Hydrogen Evolution

Phosphorus modified mesoporous AuRh film as efficient bifunctional electrocatalysts for urea-assisted energy saving hydrogen production

2022 ◽  
Author(s):  
Mei Zhang ◽  
Zhongyao Duan ◽  
Lin Cui ◽  
Hongjie Yu ◽  
Ziqiang Wang ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Energy Saving ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Oxidation Reaction ◽  
Water Electrolysis ◽  
Global Energy ◽  
Bifunctional Electrocatalysts ◽  
Cathodic Hydrogen Evolution ◽  
Electrolysis System

Hybrid water electrolysis system composed of anodic urea oxidation reaction (UOR) and cathodic hydrogen evolution reaction (HER) has been regarded as a green and sustainable route to alleviate global energy...

Solar-assisted co-electrolysis of glycerol and water for concurrent production of formic acid and hydrogen

2021 ◽  
Author(s):  
Zunjian Ke ◽  
Nicholas Williams ◽  
Xingxu Yan ◽  
Sabrina Younan ◽  
Dong He ◽  
...  
Keyword(s):  
Formic Acid ◽  
Hydrogen Evolution ◽  
Water Splitting ◽  
Hydrogen Evolution Reaction ◽  
Fossil Fuels ◽  
Water Electrolysis ◽  
Renewable Electricity ◽  
Promising Alternative ◽  
Cathodic Hydrogen Evolution

Renewable electricity-driven water splitting provides a pathway to manufacturing hydrogen as a promising alternative to fossil fuels. A typical water electrolysis device is comprised of a cathodic hydrogen evolution reaction...

A crystalline–amorphous Ni–Ni(OH)2 core–shell catalyst for the alkaline hydrogen evolution reaction

2020 ◽  
Vol 8 (44) ◽  
pp. 23323-23329
Author(s):  
Jing Hu ◽  
Siwei Li ◽  
Yuzhi Li ◽  
Jing Wang ◽  
Yunchen Du ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Electrocatalytic Activity ◽  
Core Shell ◽  
Alkaline Conditions

Crystalline–amorphous Ni–Ni(OH)2 core–shell assembled nanosheets exhibit outstanding electrocatalytic activity and stability for hydrogen evolution under alkaline conditions.

Cobaloxime-Based Double Complex Salts as Efficient and Versatile Catalysts for the Light-Driven Hydrogen Evolution Reaction

2020 ◽  
Author(s):  
Elisabeth Hofmeister ◽  
Jisoo Woo ◽  
Tobias Ullrich ◽  
Lydia Petermann ◽  
Kevin Hanus ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Systematic Study ◽  
Cobalt Complexes ◽  
Spectroscopic Studies ◽  
Double Complex ◽  
Double Complex Salts ◽  
Noble Metal Catalysts ◽  
Reduction Potentials ◽  
Complex Salts

Cobaloximes and their BF<sub>2</sub>-bridged analogues have emerged as promising non-noble metal catalysts for the photocatalytic hydrogen evolution reaction (HER). Herein we report the serendipitous discovery that double complex salts such as [Co(dmgh)<sub>2</sub>py<sub>2</sub>]<sup>+</sup>[Co(dmgBPh<sub>2</sub>)<sub>2</sub>Cl<sub>2</sub>]<sup>-</sup> can be obtained in good yields by treatment of commercially available [Co(dmgh)<sub>2</sub>pyCl] with triarylboranes. A systematic study on the use of such double complex salts and their single salts with simple counterions as photocatalysts revealed HER activities comparable or superior to existing cobaloxime catalysts and suggests ample opportunities for this compound class in catalyst/photosensitizer dyads and immobilized architectures. Preliminary electrochemical and spectroscopic studies indicate that one key advantage of these charged cobalt complexes is that the reduction potentials as well as the electrostatic interaction with charged photosensitizers can be tuned.

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