Preparation of PtRu/C Anode Electrocatalysts using NaBH4 as Reducing Agent and OH- ions as Stabilizing Agent

2019 ◽  
Vol 5 (1) ◽  
pp. 89-94 ◽  
Author(s):  
Estevam V. Spinace ◽  
Luis Antonio Indelicato do Vale ◽  
Almir Oliveira Neto ◽  
Marcelo Linardi
2013 ◽  
Vol 341-342 ◽  
pp. 233-236 ◽  
Author(s):  
Yong Qiang He ◽  
Ru Qiang Li ◽  
Di Wu ◽  
Yong Li Zhang ◽  
Jian Ping Gao ◽  
...  

An green method to reduce graphene oxide (RGO) was developed by using polysaccharide as both a reducing agent and a stabilizing agent. The RGO was characterized and the factors that affect the reduction of graphene oxide (GO) were explored to obtain optimum reaction conditions. Analysis shows that GO can be reduced at a comparatively low temperature by polysaccharide and forms a stable RGO aqueous dispersion owing to the dispersion of polysaccharide. This approach provides a new green method for GO reduction that has great value for graphene applications.


RSC Advances ◽  
2016 ◽  
Vol 6 (14) ◽  
pp. 11099-11108 ◽  
Author(s):  
Karuna A. Rawat ◽  
Suresh Kumar Kailasa

2,3,4-trihydroxy benzophenone acts as a novel reducing and stabilizing agent for one-step synthesis of size-optimized Au NPs and used as a probe for colorimetric sensing of adenine.


RSC Advances ◽  
2014 ◽  
Vol 4 (28) ◽  
pp. 14432-14440 ◽  
Author(s):  
Riyaz Ahmad Dar ◽  
Ninad G. Khare ◽  
Daniel P. Cole ◽  
Shashi P. Karna ◽  
Ashwini Kumar Srivastava

We report a facile and green synthetic approach to synthesize a silver nanoparticle (AgNPs)–graphene oxide (GO) composite using beta cyclodextrin as a stabilizing agent and ascorbic acid as a reducing agent.


2014 ◽  
Vol 1015 ◽  
pp. 480-483
Author(s):  
Men Wu ◽  
Dong Sheng Wang

Silk sericin is used as a biotemplate to redox silver nanoparticles in situ at room temperature. Silk sericin provides multiple functions in the whole reaction system, serving as the reducing agent of Ag+, and the dispersing and stabilizing agent of the resulted silver nanoparticles. The effect of the concentration of sericin on size and shape of the reduced silver nanoparticles is studied. UV-vis spectra and TEM are used to detected the characteristic plasmon and the appearance of the obtained silver nanoparticles.


1961 ◽  
Vol 06 (03) ◽  
pp. 435-444 ◽  
Author(s):  
Ricardo H. Landaburu ◽  
Walter H. Seegers

SummaryAn attempt was made to obtain Ac-globulin from bovine plasma. The concentrates contain mostly protein, and phosphorus is also present. The stability characteristics vary from one preparation to another, but in general there was no loss before 1 month in a deep freeze or before 1 week in an icebox, or before 5 hours at room temperature. Reducing agents destroy the activity rapidly. S-acetylmercaptosuccinic anhydride is an effective stabilizing agent. Greatest stability was at pH 6.0.In the purification bovine plasma is adsorbed with barium carbonate and diluted 6-fold with water. Protein is removed at pH 6.0 and the Ac-globulin is precipitated at pH 5.0. Rivanol and alcohol fractionation is followed by chromatography on Amberlite IRC-50 or DEAE-cellulose. The final product is obtained by isoelectric precipitation.


INEOS OPEN ◽  
2020 ◽  
Vol 3 ◽  
Author(s):  
O. I. Afanasyev ◽  
◽  
D. Chusov ◽  

Carbon monoxide is a unique reducing agent that is only gaining popularity in organic chemistry. This review highlights the main approaches to the application of CO as a reducing agent, summarizes and critically analyzes the key trends in this field, and describes the current development prospects. Potentially the most selective and efficient route for the realization of these processes is demonstrated.


1967 ◽  
Vol 56 (1_Suppl) ◽  
pp. S62
Author(s):  
M. Wenzel ◽  
K. Pollow
Keyword(s):  

2018 ◽  
Author(s):  
Chandan Dey ◽  
Ronny Neumann

<p>A manganese substituted Anderson type polyoxometalate, [MnMo<sub>6</sub>O<sub>24</sub>]<sup>9-</sup>, tethered with an anthracene photosensitizer was prepared and used as catalyst for CO<sub>2</sub> reduction. The polyoxometalate-photosensitizer hybrid complex, obtained by covalent attachment of the sensitizer to only one face of the planar polyoxometalate, was characterized by NMR, IR and mass spectroscopy. Cyclic voltammetry measurements show a catalytic response for the reduction of carbon dioxide, thereby suggesting catalysis at the manganese site on the open face of the polyoxometalate. Controlled potentiometric electrolysis showed the reduction of CO<sub>2</sub> to CO with a TOF of ~15 sec<sup>-1</sup>. Further photochemical reactions showed that the polyoxometalate-anthracene hybrid complex was active for the reduction of CO<sub>2</sub> to yield formic acid and/or CO in varying amounts dependent on the reducing agent used. Control experiments showed that the attachment of the photosensitizer to [MnMo<sub>6</sub>O<sub>24</sub>]<sup>9-</sup> is necessary for photocatalysis.</p><div><br></div>


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