Voltammetric and Chronopotentiometric Study of the Anodic Oxidation of Methanol, Formaldehyde, and Formic Acid

1962 ◽  
Vol 109 (11) ◽  
pp. 1005 ◽  
Author(s):  
R. P. Buck ◽  
L. R. Griffith
Keyword(s):  
Formic Acid ◽  
Anodic Oxidation ◽  
Oxidation Of Methanol

Enhancement of anodic oxidation of formic acid on Pd–Fe bimetallic nanoparticles by thermal treatment

2021 ◽  
Vol 46 (17) ◽  
pp. 10239-10246
Author(s):  
Mengyin Liao ◽  
Weiping Li ◽  
Jiaxi Peng ◽  
Fan Zhang ◽  
Wenyuan Xu ◽  
...  
Keyword(s):  
Thermal Treatment ◽  
Formic Acid ◽  
Anodic Oxidation ◽  
Bimetallic Nanoparticles

Influence of manganous ions on the anodic oxidation of methanol

1972 ◽  
Vol 17 (2) ◽  
pp. 271-278 ◽  
Author(s):  
J. Vereecken ◽  
R. Winand
Keyword(s):  
Anodic Oxidation ◽  
Oxidation Of Methanol

scholarly journals Development of Nickel-BTC-MOF-Derived Nanocomposites with rGO Towards Electrocatalytic Oxidation of Methanol and Its Product Analysis

Catalysts ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 856 ◽  
Author(s):  
Lubna Yaqoob ◽  
Tayyaba Noor ◽  
Naseem Iqbal ◽  
Habib Nasir ◽  
Neelam Zaman
Keyword(s):  
Formic Acid ◽  
Metal Organic Framework ◽  
Alkaline Media ◽  
Potential Candidate ◽  
Product Analysis ◽  
X Ray ◽  
Electrochemical Testing ◽  
Oxidation Of Methanol ◽  
Highly Active ◽  
Direct Methanol

In this study, electrochemical oxidation of methanol to formic acid using the economical and highly active catalytic Nickel Benzene tricarboxylic acid metal organic framework (Ni-BTC-MOF) and reduced graphene oxide (rGO) nanocomposites modified glassy carbon electrode GCE in alkaline media, which was examined via cyclic voltammetry technique. Nickel based MOF and rGO nanocomposites were prepared by solvothermal approach, followed by morphological and structural characterization of prepared samples through X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), and energy dispersive X-ray (EDX) analysis. The electrochemical testing of synthesized materials represents the effect of the sequential increase in rGO concentration on electrocatalytic activity. The Ni-BTC/4 wt % rGO composite with a pronounced current density of 200.22 mA/cm2 at 0.69 V versus Hg/HgO electrode at 50 mV/s was found to be a potential candidate for methanol oxidation in Direct Methanol Fuel Cell (DMFC) applications. Product analysis was carried out through Gas Chromatography (GC) and Nuclear Magnetic Resonance (NMR) spectroscopy, which confirmed the formation of formic acid during the oxidation process, with approximately 62% yield.

Micropitting of Titanium during Anodic Oxidation in Formic Acid

Nature ◽  
1961 ◽  
Vol 189 (4760) ◽  
pp. 216-217 ◽  
Author(s):  
R. A. PIGGOTT ◽  
L. L. SHREIR
Keyword(s):  
Formic Acid ◽  
Anodic Oxidation
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