Oxidation of Copper Single Crystals in Aqueous Solutions of Inorganic Salts

1966 ◽  
Vol 113 (9) ◽  
pp. 883 ◽  
Author(s):  
D. B. Scott ◽  
G. Tyler Miller
2014 ◽  
Vol 70 (9) ◽  
pp. 876-881 ◽  
Author(s):  
Erik Hennings ◽  
Horst Schmidt ◽  
Wolfgang Voigt

Single crystals of calcium bromide enneahydrate, CaBr2·9H2O, calcium iodide octahydrate, CaI2·8H2O, calcium iodide heptahydrate, CaI2·7H2O, and calcium iodide 6.5-hydrate, CaI2·6.5H2O, were grown from their aqueous solutions at and below room temperature according to the solid–liquid phase diagram. The crystal structure of CaI2·6.5H2O was redetermined. All four structures are built up from distorted Ca(H2O)8antiprisms. The antiprisms of the iodide hydrate structures are connected eitherviatrigonal-plane-sharing or edge-sharing, forming dimeric units. The antiprisms in calcium bromide enneahydrate are monomeric.


1990 ◽  
Vol 55 (2) ◽  
pp. 345-353 ◽  
Author(s):  
Ivan Halaša ◽  
Milica Miadoková

The authors investigated periodic potential changes measured on oriented sections of Al single crystals during spontaneous dissolution in dilute aqueous solutions of KOH, with the aim to find optimum conditions for the formation of potential oscillations. It was found that this phenomenon is related with the kinetics of the reaction investigated, whose rate also changed periodically. The mechanism of the oscillations is discussed in view of the experimental findings.


1975 ◽  
Vol 25 (1) ◽  
pp. 57-59 ◽  
Author(s):  
S. Okuda ◽  
H. Mizubayashi

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