The Parabolic Oxidation Kinetics of Niobium

1966 ◽  
Vol 113 (12) ◽  
pp. 1255 ◽  
Author(s):  
J. S. Sheasby ◽  
G. R. Wallwork ◽  
W. W. Smeltzer
1965 ◽  
Vol 13 (2) ◽  
pp. 55-60 ◽  
Author(s):  
C.J Rosa ◽  
W.W Smeltzer

1989 ◽  
Vol 4 (6) ◽  
pp. 1421-1426 ◽  
Author(s):  
R. A. Konetzki ◽  
Y. A. Chang ◽  
V. C. Marcotte

The solid state oxidation kinetics of Pb–Sn single-phase (2.5 at. % Sn) and eutectic alloys were studied with Auger Electron Spectroscopy combined with sputter depth profiling. The single-phase samples were oxidized in air in the temperature range 22 °C to 250 °C, while the eutectic samples were oxidized from 22 °C to 175 °C. Both alloys oxidize logarithmically between 22 °C and 90 °C and parabolically at temperatures greater than 120 °C. The activation energies for the parabolic oxidation of the single-phase and eutectic alloys are 69.5 and 67.1 ± 8 kJ/mole, respectively.


1969 ◽  
Vol 17 (5) ◽  
pp. 579-584 ◽  
Author(s):  
A Madeyski ◽  
D.J Poulton ◽  
W.W Smeltzer

1995 ◽  
Vol 410 ◽  
Author(s):  
Gerald T. Kraus ◽  
Cory S. Oldweiler ◽  
Emmanuel P. Giannelis

ABSTRACTTantalum nitride thin films were produced by nitridation of sol-gel tantala thin films. The oxidation kinetics and the activation energy for oxidation were investigated and compared to those of sputtered tantalum nitride thin films. Data was gathered from in situ sheet resistance measurements taken between 550 and 720 K. Sol-gel films exhibited parabolic oxidation kinetics and had an activation energy of 1.9 eV. Sputtered films displayed quartic oxidation kinetics at lower temperatures tending toward cubic kinetics at higher temperatures and had an activation energy of 1.6 eV.


1993 ◽  
Vol 12 (3) ◽  
pp. 177-184 ◽  
Author(s):  
Jeanette Persson ◽  
Per-Olov Käll ◽  
Mats Nygren

1964 ◽  
Vol 12 (4) ◽  
pp. 409-415 ◽  
Author(s):  
G.R Wallwork ◽  
W.W Smeltzer ◽  
C.J Rosa

2020 ◽  
Author(s):  
Camilo A. Mesa ◽  
Ludmilla Steier ◽  
Benjamin Moss ◽  
Laia Francàs ◽  
James E. Thorne ◽  
...  

<p><i>Operando</i> spectroelectrochemical analysis is used to determine the water oxidation reaction kinetics for hematite photoanodes prepared using four different synthetic procedures. Whilst these photoanodes exhibit very different current / voltage performance, their underlying water oxidation kinetics are found to be almost invariant. Lower photoanode performance was found to correlate with the observation of optical signals indicative of charge accumulation in mid-gap oxygen vacancy states, indicating these states do not contribute directly to water oxidation.</p>


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