Study of the Dissipation Factor of PbZr[sub 0.7]Ti[sub 0.3]O[sub 3] in the Vicinity of the Curie Point

1969 ◽  
Vol 116 (6) ◽  
pp. 861 ◽  
Author(s):  
Donald F. Weirauch ◽  
Victor J. Tennery
Keyword(s):  
Curie Point ◽  
Dissipation Factor

ELASTIC CONSTANTS OF IRON IN THE VICINITY OF THE CURIE POINT

1971 ◽  
Vol 32 (C1) ◽  
pp. C1-415-C1-416 ◽  
Author(s):  
L. ALBERTS ◽  
M. BOHLMANN ◽  
H. L. ALBERTS
Keyword(s):  
Elastic Constants ◽  
Curie Point

scholarly journals Photoluminescence Spectroscopy Measurements for Effective Condition Assessment of Transformer Insulating Oil

Processes ◽  
2021 ◽  
Vol 9 (5) ◽  
pp. 732
Author(s):  
Abdelrahman M. Alshehawy ◽  
Diaa-Eldin A. Mansour ◽  
Mohsen Ghali ◽  
Matti Lehtonen ◽  
Mohamed M. F. Darwish
Keyword(s):  
Electronic States ◽  
Dissipation Factor ◽  
Condition Assessment ◽  
Transformer Oil ◽  
Term Operation ◽  
Pl Spectra ◽  
Insulating Oil ◽  
Vis Spectroscopy ◽  
Effective Condition ◽  
Dielectric Dissipation Factor

Condition assessment of insulating oil is crucial for the reliable long-term operation of power equipment, especially power transformers. Under thermal aging, critical degradation in oil properties, including chemical, physical, and dielectric properties, occurs due to the generation of aging byproducts. Ultraviolet-visible (UV-Vis) spectroscopy was recently proposed for the condition assessment of mineral oil. However, this absorption technique may involve all electronic states of the investigated material which typically yield a broad spectrum, and thus cannot precisely reflect the electronic structure of aged oil samples. It also cannot be implemented as an online sensor of oil degradation. In this paper, photoluminescence (PL) spectroscopy is introduced, for the first time, for effective condition assessment of insulating oil. The PL technique involves emission processes that only occur between a narrow band of electronic states that are occupied by thermalized electrons and consequently yields a spectrum that is much narrower than that of the absorption spectrum. Aged oil samples with different aging extents were prepared in the laboratory using accelerated aging tests at 120 °C, under which 1 day of laboratory aging is equivalent to approximately 1 year of aging in the field. These aged samples were then tested using PL spectroscopy with a wavelength ranging from 150 nm to 1500 nm. Two main parameters were evaluated for quantitative analysis of PL spectra: The full width at half-maximum and the enclosed area under the PL spectra. These parameters were correlated to the aging extent. In conjunction with PL spectroscopy, the aged oil samples were tested for the dielectric dissipation factor as an indication of the number of aging byproducts. Interestingly, we find a correlation between the PL spectra and the dielectric dissipation factor. The results of PL spectroscopy were compared to those of UV-Vis spectroscopy for the same samples and the parameters extracted from PL spectra were compared to the aging b-products extracted from UV-Vis spectra. Finally, the corresponding physical mechanisms were discussed considering the obtained results and the spectral shift for each spectrum. It was proved that PL spectroscopy is a promising technique for the condition assessment of insulating oil when compared to conventional transformer oil assessment measuring techniques and even to other optical absorption techniques.

scholarly journals Preparation and Characterization of Transparent Polyimide Nanocomposite Films with Potential Applications as Spacecraft Antenna Substrates with Low Dielectric Features and Good Sustainability in Atomic-Oxygen Environments

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1886
Author(s):  
Yan Zhang ◽  
Bo-han Wu ◽  
Han-li Wang ◽  
Hao Wu ◽  
Yuan-cheng An ◽  
...  
Keyword(s):  
Atomic Oxygen ◽  
Composite Films ◽  
Dissipation Factor ◽  
Low Earth Orbit ◽  
Nanocomposite Films ◽  
Dielectric Parameters ◽  
Low Dielectric ◽  
Aerospace Applications ◽  
Optically Transparent ◽  
Order Of Magnitude

Optically transparent polyimide (PI) films with good dielectric properties and long-term sustainability in atomic-oxygen (AO) environments have been highly desired as antenna substrates in low earth orbit (LEO) aerospace applications. However, PI substrates with low dielectric constant (low-Dk), low dielectric dissipation factor (low-Df) and high AO resistance have rarely been reported due to the difficulties in achieving both high AO survivability and good dielectric parameters simultaneously. In the present work, an intrinsically low-Dk and low-Df optically transparent PI film matrix, poly[4,4′-(hexafluoroisopropylidene)diphthalic anhydride-co-2,2-bis(4-(4-aminophenoxy)phenyl)hexafluoropropane] (6FPI) was combined with a nanocage trisilanolphenyl polyhedral oligomeric silsesquioxane (TSP-POSS) additive in order to afford novel organic–inorganic nanocomposite films with enhanced AO-resistant properties and reduced dielectric parameters. The derived 6FPI/POSS films exhibited the Dk and Df values as low as 2.52 and 0.006 at the frequency of 1 MHz, respectively. Meanwhile, the composite films showed good AO resistance with the erosion yield as low as 4.0 × 10−25 cm3/atom at the exposure flux of 4.02 × 1020 atom/cm2, which decreased by nearly one order of magnitude compared with the value of 3.0 × 10−24 cm3/atom of the standard PI-ref Kapton® film.

Curie-point switching in Mn-Bi films

1969 ◽  
Vol 5 (3) ◽  
pp. 298-299 ◽  
Author(s):  
G. Lewicki
Keyword(s):  
Curie Point

Overlapping energy bands and the theory of collective electron ferromagnetism

1953 ◽  
Vol 49 (1) ◽  
pp. 115-129 ◽  
Author(s):  
A. B. Lidiard
Keyword(s):  
Curie Point ◽  
Energy Band ◽  
Spontaneous Magnetization ◽  
Copper Alloys ◽  
Implicit Assumption ◽  
Energy Bands ◽  
Unknown Parameters ◽  
Nickel Copper ◽  
Predicted Values ◽  
A Minor

ABSTRACTThe theory of collective electron ferromagnetism given by Stoner applies to a system of electrons in a single energy band; for iron, cobalt and nickel this is identified with the band of states derived from atomic 3d functions. To bring in the generally assumed overlapping of the 3d band by the wide 4s band in these metals, the theory has been extended to take account of the transfer of electrons from 3d to 4s states with change of temperature. A previous calculation of this transfer effect must be regarded as inadequate, for the part played by the exchange energy in determining the distribution of electrons between the two sets of states was omitted. The general equations are derived in § 2 and used as a basis for discussion of the properties of nickel-copper alloys at absolute zero in § 3. In §§4 and 5 numerical results are presented which show the effect of the overlapping 4s band on the magnetic properties of a system such as nickel both above and below its Curie point. Comparison with the measured paramagnetic susceptibility of pure nickel above the Curie point strongly suggests that for this metal the overlapping 4s band has only a minor influence, although in principle the effect could be very large (cf. Fig. 4). This result is not unambiguous, however, because values thus inferred for the two unknown parameters lead to inaccurate predictions below the Curie point. First, the predicted values for the spontaneous magnetization are too small. Secondly, the theory demands that the nickel-copper alloys should only be ferromagnetic below a copper content of about 20 %, whereas experimentally the limit is known to be about 60 %. In conclusion, it is suggested that the implicit assumption of Stoner's theory that the exchange integrals between all pairs of 3d states are equal to one another is a more serious restriction on the theory than the consideration of only a single energy band.

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