An Automated Procedure for Obtaining Steady-State Current-Potential Relationship

1971 ◽  
Vol 118 (4) ◽  
pp. 583 ◽  
Author(s):  
G. Bélanger
Author(s):  
Gabriel Ybarra ◽  
Carlos Moina ◽  
María Inés Florit ◽  
Dionisio Posadas

<p class="PaperAbstract"><span lang="EN-US">In this work, the mediated reduction and oxidation of Fe(CN)<sub>6</sub><sup>3-/4-</sup> and Fe<sup>3+ </sup>in poly(o-aminophenol) coated electrodes is analyzed by means of diagnosis diagram based on the features of steady state current-potential curves. This analysis allows to identify the current determining process and to reproduce the experimental characteristics of the polarization curve from the relevant kinetic and thermodynamical parameters with a minimum amount of experimental measurements. </span></p>


2018 ◽  
Vol 8 (4) ◽  
pp. 271-280
Author(s):  
Gabriel Ybarra ◽  
Carlos Moina ◽  
María Inés Florit ◽  
Dionisio Posadas

In this work, the mediated reduction of Fe(CN)63- and Fe3+ in poly(o-aminophenol) coated electrodes is analyzed by means of a diagnosis diagram based on the features of the steady state current-potential curves. This analysis allows to identify the current determining process and to reproduce the experimental characteristics of the polarization curve from the relevant kinetic and thermodynamic parameters with a minimum amount of experimental measurements.


2021 ◽  
Vol 11 (15) ◽  
pp. 6920
Author(s):  
Oldřich Coufal

Two infinitely long parallel conductors of arbitrary cross section connected to a voltage source form a loop. If the source voltage depends on time, then due to induction there is no constant current density in the loop conductors. It is only recently that a method has been published for accurately calculating current density in a group of long parallel conductors. The method has thus far been applied to the calculation of steady-state current density in a loop connected to a sinusoidal voltage source. In the present article, the method is used for an accurate calculation of transient current using transient current density. The transient current is analysed when connecting and short-circuiting the sources of sinusoidal, constant and sawtooth voltages. For circular cross section conductors, the dependences of maximum current density, maximum current and the time of achieving steady state on the source frequency, the distance of the conductors and their resistivity when connecting the source of sinusoidal voltage are examined.


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