The Anodic Deposition of Oxide Films on Platinum from Ferrous Sulfate Solutions

1972 ◽  
Vol 119 (8) ◽  
pp. 987 ◽  
Author(s):  
J. -L. Leibenguth ◽  
Morris Cohen
2014 ◽  
Vol 926-930 ◽  
pp. 932-937 ◽  
Author(s):  
Wen Po Li ◽  
Xiu Li Zuo ◽  
Tang Man Lv ◽  
Sheng Tao Zhang

Nanostructured manganese oxide films were obtained by electro-oxidation of manganese films electrodeposited at two typical cathodic currents of 65 mA cm-2 (EDM-65 oxide) and 150 mA cm-2 (EDM-150 oxide) from sulfate solutions with additives. Obtained Mn oxide films were studied by scanning electron microscope, X-ray photoelectron spectroscopy, cyclic voltammetry and AC impedance. SEM study revealed that the Mn oxide films were mesoporous nanostructures on the EDM-150 oxide surface, while the EDM-65 oxide coating is homogeneous and compact. XPS results indicate that EDM-150 oxide had a higher content of anhydrous Mn oxide and structure water, which means that it had more anhydrous characteristics as compared to EDM-65 oxide. It was shown that porous nanostructured films showed good capacitive behavior for applications in electrochemical supercapacitors. The porous nanostructured films prepared at 150 mA cm-2 showed higher specific capacitance (SC) compared to the SC of the EDM-65 oxide films. The highest SC of 148 F g-1 in a voltage window of 0.8 V was obtained in 0.1 M Na2SO4 solutions at a scan rate of 25 mV s-1.


1945 ◽  
Vol 37 (5) ◽  
pp. 429-431 ◽  
Author(s):  
Kenneth A. Kobe ◽  
William Dickey

1993 ◽  
Vol 57 (1) ◽  
pp. 280-282 ◽  
Author(s):  
R. S. Stahl ◽  
D. S. Fanning ◽  
B. R. James

1951 ◽  
Vol 73 (2) ◽  
pp. 852-852 ◽  
Author(s):  
Harris Holtzman ◽  
Leonard May

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