Chloride-Induced Pitting Corrosion of Iron in Mildly Alkaline Borate Buffer Solutions: Localized Dissolution Kinetics

2019 ◽  
Vol 1 (4) ◽  
pp. 447-454 ◽  
Author(s):  
Jozef Soltis ◽  
Steve Hodges ◽  
Stephen White ◽  
Anthony Cook ◽  
Nick Laycock
Keyword(s):  
Pitting Corrosion ◽  
Dissolution Kinetics ◽  
Borate Buffer ◽  
Buffer Solutions ◽  
Corrosion Of Iron

scholarly journals Computational modeling of pitting corrosion

2019 ◽  
Vol 37 (5) ◽  
pp. 419-439 ◽  
Author(s):  
Siavash Jafarzadeh ◽  
Ziguang Chen ◽  
Florin Bobaru
Keyword(s):  
Pitting Corrosion ◽  
Computational Models ◽  
Dissolution Kinetics ◽  
Corrosion Damage ◽  
Material Strength ◽  
Unified Framework ◽  
Advantages And Disadvantages ◽  
Phase Field Models ◽  
Classical Transport ◽  
Kinetics Of

AbstractPitting corrosion damage is a major problem affecting material strength and may result in difficult to predict catastrophic failure of metallic material systems and structures. Computational models have been developed to study and predict the evolution of pitting corrosion with the goal of, in conjunction with experiments, providing insight into pitting processes and their consequences in terms of material reliability. This paper presents a critical review of the computational models for pitting corrosion. Based on the anodic reaction (dissolution) kinetics at the corrosion front, transport kinetics of ions in the electrolyte inside the pits, and time evolution of the damage (pit growth), these models can be classified into two categories: (1) non-autonomous models that solve a classical transport equation and, separately, solve for the evolution of the pit boundary; and (2) autonomous models like cellular automata, peridynamics, and phase-field models which address the transport, dissolution, and autonomous pit growth in a unified framework. We compare these models with one another and comment on the advantages and disadvantages of each of them. We especially focus on peridynamic and phase-filed models of pitting corrosion. We conclude the paper with a discussion of open areas for future developments.

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