The Role of Hydroxide in the Electrochemical Impedance Response of Passive Films in Corrosion Environments

2006 ◽  
Vol 153 (3) ◽  
pp. B101 ◽  
Author(s):  
Román Cabrera-Sierra ◽  
M. A. Pech-Canul ◽  
Ignacio González
Keyword(s):  
Electrochemical Impedance ◽  
Passive Films ◽  
Impedance Response

scholarly journals Pitting Corrosion of Type 316L Stainless Steel Elaborated by the Selective Laser Melting Method: Influence of Microstructure

2021 ◽  
Author(s):  
V. Vignal ◽  
C. Voltz ◽  
S. Thiébaut ◽  
M. Demésy ◽  
O. Heintz ◽  
...  
Keyword(s):  
Corrosion Behavior ◽  
316L Stainless Steel ◽  
Electrochemical Impedance ◽  
Chemical Properties ◽  
Passive Films ◽  
First Order ◽  
Average Grain Size ◽  
Type 316L ◽  
Pure Matrix ◽  
Type 316L Stainless Steel

AbstractThe microstructure of two sets of 316L alloys (SLM and wrought structure) is determined using SPECTROMAXx stationary metal analyzer, FE-SEM/EDS and XRD. The physical–chemical properties of the passive films are also investigated by means of XPS, Auger after sputtering and electrochemical impedance spectroscopy measurements. Differences and similarities between the two sets of alloys are then identified. The corrosion behavior of alloys is investigated in NaCl solution at the macro- and microscale (microcapillary technique). It was found that the inclusion/particles cleanliness is the first-order parameter explaining differences between 316L(WS) and 316L(SLM). In the absence of particles (pure matrix), the two sets of alloys have the same corrosion behavior. Residual stresses, the average grain size, the PREN and the passive films properties are of second order.

scholarly journals Effect of Mechanical Surface Treatments on the Surface State and Passive Behavior of 304L Stainless Steel

Metals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 135
Author(s):  
Kathleen Jaffré ◽  
Benoît Ter-Ovanessian ◽  
Hiroshi Abe ◽  
Nicolas Mary ◽  
Bernard Normand ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Stainless Steel ◽  
Surface State ◽  
Electrochemical Impedance ◽  
Passive Films ◽  
Surface Finishing ◽  
Ultrafine Grain ◽  
304L Stainless Steel ◽  
Passive Behavior

The effect of dry grinding on 304L stainless steel’s passive behavior is compared to two other surface finishing (mechanical polishing down to 2400 with SiC emery paper and 1 µm with diamond paste, respectively). The characterization of the surface state was performed using scanning electron microscopy, transmission electron microscopy, 3D optical profilometer, and X-ray diffraction. Results indicate that each surface treatment leads to different surface states. The ground specimens present an ultrafine grain layer and a strong plastic deformation underneath the surface, while an ultrafine grain layer characterizes the subsurface of the polished specimens. Grinding induces high residual compressive stresses and high roughness compared to polishing. The characterization of the passive films was performed by electrochemical impedance spectroscopy and Mott–Schottky analysis. The study shows that the semiconductor properties and the thickness of the passive films are dependent on the surface state of the 304L stainless steel.

Role of chromium in anomalous behaviour of the passive layer in Ni-Cr-Mo alloys in 1M HCl solution

CORROSION ◽  
10.5006/3767 ◽  
2022 ◽  
Author(s):  
Malvika Karri ◽  
Amit Verma ◽  
J.B. Singh ◽  
Sunil Kumar Bonagani ◽  
U.K. Goutam
Keyword(s):  
Corrosion Resistance ◽  
Electrochemical Impedance ◽  
Corrosion Behaviour ◽  
Underlying Mechanism ◽  
Passive Layer ◽  
X Ray ◽  
Superior Corrosion Resistance ◽  
Hcl Solution ◽  
Cr2o3 Layer

This work seeks to understand the underlying mechanism involved in passivity of Ni-Cr-Mo alloys in a less concentrated HCl solution (1M) by systematically varying contents of Cr and Mo solutes in model Ni-Cr-Mo alloys. Corrosion behaviour was evaluated based on potentiodynamic polarisation tests carried out in conjunction with electrochemical impedance and x-ray photoelectron spectroscopies of passive films that formed on alloys during their exposure to the HCl solution. Results have shown that an increase in Mo alone is not sufficient to improve the corrosion resistance of the alloys at lower concentrations of HCl. Optimum concentrations of Cr and Mo solutes have been found to be in the vicinity of ~17 wt.% Cr and ~19 wt.% Mo for superior corrosion resistance of the alloys. This was attributed to the protection of the Cr2O3 layer as a consequence of the enrichment of Mo6+ ions in the passive film in 1M HCl solution.

Effect of Synthesis Conditions on Pseudocapacitance Properties of Nitrogen-Doped Porous Carbon Materials

2019 ◽  
Vol 59 ◽  
pp. 112-125
Author(s):  
Volodymyr Boichuk ◽  
Volodymyr Kotsyubynsky ◽  
Andrii Kachmar ◽  
Sergiy Budzulyak ◽  
Ivan Budzulyak ◽  
...  
Keyword(s):  
Carbon Materials ◽  
Aqueous Electrolyte ◽  
Electrochemical Impedance ◽  
Galvanostatic Charge ◽  
Discharge Data ◽  
Synthesis Conditions ◽  
Capacitive Properties ◽  
Charge Discharge ◽  
Redox Capacitance

The electrochemical properties of the nitrogen-enriched carbons obtained by plant raw treatment as electrode material for supercapacitors were investigated by electrochemical impedance spectroscopy, cycling voltammetry and galvanostatic charge-discharge cycling in KOH aqueous electrolyte. The effect of activation agent (NaOH) concentration and carbonization temperature were analyzed. The separation of double layer and redox capacitance components was done. The dominating role of microporosity for capacitive properties was demonstrated. The capacitance of model capacitors based on carbons obtained at different modes was calculated from both from cycling voltammetry and galvanostatic charge-discharge data. The maximal values of specific capacitance of carbon materials carbonized at 600°C and 900°C are about 100 and 120 F/g, respectively.

Role of direct and inverted undoped spiro-OMeTAD–perovskite architectures in determining solar cells performances: an investigation via electrical impedance spectroscopy

2019 ◽  
Vol 21 (12) ◽  
pp. 6613-6621 ◽  
Author(s):  
Marianna Ambrico ◽  
Paolo F. Ambrico ◽  
Luisa De Marco ◽  
Rosabianca Iacobellis ◽  
Arianna D’Abramo ◽  
...  
Keyword(s):  
Solar Cells ◽  
Impedance Spectroscopy ◽  
Electrical Impedance ◽  
Electrical Impedance Spectroscopy ◽  
Impedance Response ◽  
Inverse Structure

Spiro-OMeTAD/perovskite direct and inverse structure architectures’ influence on the performance of solar cells are elucidated via the analysis of the structure impedance response.

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