Corrosion Protection of Cerium Conversion Coating Modified with a Self-Assembled Layer of Phosphoric Acid Mono-n-Alkyl Ester

2006 ◽  
Vol 9 (3) ◽  
pp. B15 ◽  
Author(s):  
Y. Kobayashi ◽  
Y. Fujiwara
Metals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 337
Author(s):  
Ewa Wierzbicka ◽  
Marta Mohedano ◽  
Endzhe Matykina ◽  
Raul Arrabal

REACH (Registration, Evaluation, Authorisation and Restriction of Chemicals) regulations demand for an expedient discovery of a Cr(VI)-free alternative corrosion protection for light alloys even though the green alternatives might never be as cheap as current harmful technologies. In the present work, flash- plasma electrolytic oxidation coatings (FPEO) with the process duration < 90 s are developed on AZ31B alloy in varied mixtures of silicate-, phosphate-, aluminate-, and fluoride-based alkaline electrolytes implementing current density and voltage limits. The overall evaluation of the coatings’ anticorrosion performance (electrochemical impedance spectroscopy (EIS), neutral salt spray test (NSST), paintability) shows that from nine optimized FPEO recipes, two (based on phosphate, fluoride, and aluminate or silicate mixtures) are found to be an adequate substitute for commercially used Cr(VI)-based conversion coating (CCC). The FPEO coatings with the best corrosion resistance consume a very low amount of energy (~1 kW h m−2 µm−1). It is also found that the lower the energy consumption of the FPEO process, the better the corrosion resistance of the resultant coating. The superb corrosion protection and a solid environmentally friendly outlook of PEO-based corrosion protection technology may facilitate the economic justification for industrial end-users of the current-consuming process as a replacement of the electroless CCC process.


2015 ◽  
Vol 3 (8) ◽  
pp. 1667-1676 ◽  
Author(s):  
Jiadi Sun ◽  
Ye Zhu ◽  
Long Meng ◽  
Wei Wei ◽  
Yang Li ◽  
...  

Self-assembled nanoparticles loaded with bioactive agents were electrodeposited to provide the magnesium alloy with controlled release and corrosion resistance properties.


2016 ◽  
Vol 8 (26) ◽  
pp. 16845-16851 ◽  
Author(s):  
Wenrui Zhang ◽  
Mingtao Li ◽  
Aiping Chen ◽  
Leigang Li ◽  
Yuanyuan Zhu ◽  
...  

2018 ◽  
Vol 7 (1) ◽  
pp. 950-960 ◽  
Author(s):  
Ning Pan ◽  
Yongdong Jin ◽  
Xiaoqiang Wang ◽  
Xiaoping Hu ◽  
Fangting Chi ◽  
...  

2018 ◽  
Vol 6 (43) ◽  
pp. 6936-6949 ◽  
Author(s):  
Hao Zhang ◽  
Lingxia Xie ◽  
Xiaolong Shen ◽  
Tengda Shang ◽  
Rifang Luo ◽  
...  

A catechol/polyethyleneimine conversion coating on a MgZnMn alloy possessed good corrosion resistance. Heparin was further grafted on it and this showed the potential for surface modification of magnesium-based vascular implants.


2020 ◽  
Vol 8 (18) ◽  
pp. 6063-6071 ◽  
Author(s):  
Chaoyue Zheng ◽  
Yuan Liao ◽  
Ziyu Xiong ◽  
Ye Zhou ◽  
Su-Ting Han

The multi-terminal memtransistor is fabricated with a self-assembled layer of APTES to mimic the synaptic competitive and cooperative behaviors.


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