An Investigation of the Electrochemistry of a Series of Metal Dioxides with Rutile‐Type Structure: MoO2,  WO 2, ReO2, RuO2, OsO2, and IrO2

1977 ◽  
Vol 124 (8) ◽  
pp. 1202-1207 ◽  
Author(s):  
Jean Horkans ◽  
M. W. Shafer
Keyword(s):  
Type Structure ◽  
Metal Dioxides

Structural Studies of Rutile-Type Metal Dioxides

1997 ◽  
Vol 53 (3) ◽  
pp. 373-380 ◽  
Author(s):  
A. A. Bolzan ◽  
C. Fong ◽  
B. J. Kennedy ◽  
C. J. Howard
Keyword(s):  
Neutron Diffraction ◽  
Rietveld Refinement ◽  
Type Structure ◽  
Structural Studies ◽  
Rutile Structure ◽  
Space Group ◽  
Structure Space ◽  
Germanium Tin ◽  
Thermal Vibrations ◽  
Metal Dioxides

The structures of the four metal dioxides GeO2, SnO2, RuO2 and IrO2 (germanium, tin, ruthenium and iridium dioxides, respectively) have been redetermined by Rietveld refinement from neutron diffraction powder data. The four dioxides all adopt the rutile-type structure, space group P42/mnm (no. 136), with a = 4.4066 (1), 4.7374 (1), 4.4968 (2) and 4.5051 (3), c = 2.8619 (1), 3.1864 (1), 3.1049 (1) and 3.1586 (2) Å, and x = 0.3060 (1), 0.3056 (1), 0.3053 (1) and 0.3077 (3), respectively. These results are compared with those for other metal dioxides that adopt the rutile structure and trends in structural and thermal vibrations for a series of 11 metal dioxides which adopt the rutile-type structure are described.

New semiconducting compounds of diamond type structure

Physica ◽  
1954 ◽  
Vol 3 (7-12) ◽  
pp. 1107-1109 ◽  
Author(s):  
C GOODMAN ◽  
R DOUGLAS
Keyword(s):  
Type Structure ◽  
Semiconducting Compounds ◽  
Diamond Type

Study of Natural Minerals of U-Ryrochlore-Type Structure as Analogues of Plutonium Ceramic Waste-form

2002 ◽  
Vol 713 ◽  
Author(s):  
Roman V. Bogdanov ◽  
Yuri F. Batrakov ◽  
Elena V. Puchkova ◽  
Andrey S. Sergeev ◽  
Boris E. Burakov
Keyword(s):  
Chemical Shifts ◽  
Pyrochlore Structure ◽  
Type Structure ◽  
Waste Form ◽  
X Ray ◽  
Ceramic Waste ◽  
Natural Minerals ◽  
The Us ◽  
Pyrochlore Type

ABSTRACTAt present, crystalline ceramic based on titanate pyrochlore, (Ca,Gd,Hf,Pu,U)2Ti2O7, is considered as the US candidate waste form for the immobilization of weapons grade plutonium. Naturally occuring U-bearing minerals with pyrochlore-type structure: hatchettolite, betafite, and ellsworthite, were studied in orders to understand long-term radiation damage effects in Pu ceramic waste forms. Chemical shifts (δ) of U(Lδ1)– and U(Lβ1) – X-ray emission lines were measured by X-ray spectrometry. Calculations were performed on the basis of a two-dimensional δLá1- and δLδ1- correlation diagram. It was shown that 100% of uranium in hatchettolite and, probably, 95-100% of uranium in betafite are in the form of (UO2)2+. formal calculation shows that in ellsworthite only 20% of uranium is in the form of U4+ and 80% of the rest is in the forms of U5+ and U6+. The conversion of the initial U4+ ion originally occurring in the pyrochlore structure of natural minerals to (UO2)2+ due to metamict decay causes a significant increase in uranium mobility.

SEARCH FOR A NEW MANAGEMENT MODEL FOR THE DEVELOPMENT, PRODUCTION AND IMPLEMENTATION OF WORLD-CLASS HYDROGEN TECHNOLOGIES

2020 ◽  
Vol 3 (7) ◽  
pp. 114-119
Author(s):  
V. F. UKOLOV ◽  
◽  
E. N. OZHIGANOV ◽  
Yu. V. RAGULINA ◽  
V. V. ARKHIPOV ◽  
...  
Keyword(s):  
Large Scale ◽  
The State ◽  
Type Structure ◽  
Management Model ◽  
World Class ◽  
Hydrogen Technologies

After the research, the authors came to the conclusion: it is necessary to get a new, interstate platform-type structure for the development, production and large-scale implementation of civil hydrogen technologies for various fields of activity and the state.

Optical Spectra, EPR, and Spin–Lattice Relaxation of Yb3+ Ions in Crystals Having Perovskite-Type Structure

1977 ◽  
Vol 81 (1) ◽  
pp. 287-293 ◽  
Author(s):  
A. A. Antipin ◽  
A. V. Vinokurov ◽  
M. P. Davydova ◽  
S. L. Korableva ◽  
A. L. Stolov ◽  
...  
Keyword(s):  
Lattice Relaxation ◽  
Optical Spectra ◽  
Type Structure ◽  
Spin Lattice Relaxation ◽  
Spin Lattice ◽  
Perovskite Type ◽  
Perovskite Type Structure
Sign in / Sign up

Export Citation Format

Share Document