Cathodic Instability in Solid Copper Ion Battery Electrolytes: A Suggested General Mechanism

1976 ◽  
Vol 123 (7) ◽  
pp. 1063-1065 ◽  
Author(s):  
Douglas O. Raleigh
Keyword(s):  
Copper Ion ◽  
General Mechanism ◽  
Solid Copper

High-conductivity solid copper ion conductors: the sulphonium halide-copper(I) halide systems

1977 ◽  
Vol 7 (3) ◽  
pp. 253-256 ◽  
Author(s):  
T. Takahashi ◽  
N. Wakabayashi ◽  
O. Yamamoto
Keyword(s):  
Copper Ion ◽  
High Conductivity ◽  
Solid Copper ◽  
Ion Conductors

Further Evidence for Energy Landscape Flattening in the Superionic Argyrodites Li6+xP1−xMxS5I (M = Si, Ge, Sn)

2019 ◽  
Author(s):  
Saneyuki Ohno ◽  
Bianca Helm ◽  
Till Fuchs ◽  
Georg Dewald ◽  
Marvin Kraft ◽  
...  
Keyword(s):  
Solid State ◽  
Activation Barrier ◽  
Energy Landscape ◽  
General Mechanism ◽  
Ionic Conductors ◽  
Energy Storage Devices ◽  
Ion Conductor ◽  
Storage Devices ◽  
Open Questions ◽  
Sudden Decrease

<p>All-solid-state batteries are promising candidates for next-generation energy storage devices. Although the list of candidate materials for solid electrolytes has grown in the past decade, there are still many open questions concerning the mechanisms behind ionic migration in materials. In particular, the lithium thiophosphate family of materials has shown very promising properties for solid-state battery applications. Recently, the Ge-substituted Li<sub>6</sub>PS<sub>5</sub>I argyrodite was shown to be a very fast Li-ion conductor, despite the poor ionic conductivity of the unsubstituted Li<sub>6</sub>PS<sub>5</sub>I. Therein, the conductivity was enhanced by over three orders of magnitude due to the emergence of I<sup>−</sup>/S<sup>2−</sup>exchange, <i>i.e.</i>site-disorder, which led to a sudden decrease of the activation barrier with a concurrent flattening of the energy landscapes. Inspired by this work, two series of elemental substitutions in Li<sub>6+<i>x</i></sub>P<sub>1−<i>x</i></sub><i>M<sub>x</sub></i>S<sub>5</sub>I (<i>M</i>= Si and Sn) were investigated in this study and compared to the Ge-analogue. A sharp reduction in the activation energy was observed at the same <i>M</i><sup>4+</sup>/P<sup>5+</sup>composition as previously found in the Ge-analogue, suggesting a more general mechanism at play. Furthermore, structural analyses with X-ray and neutron diffraction indicate that similar changes in the Li-sublattice occur despite a significant variation in the size of the substituents, suggesting that in the argyrodites, the lithium substructure is most likely influenced by the occurring Li<sup>+</sup>– Li<sup>+</sup>interactions. This work provides further evidence that the energy landscape of ionic conductors can be tailored by inducing local disorder.</p>

Copper–oxygen Dynamics in Tyrosinase

2019 ◽  
Author(s):  
Nobutaka Fujieda ◽  
Sachiko Yanagisawa ◽  
Minoru Kubo ◽  
Genji Kurisu ◽  
Shinobu Itoh
Keyword(s):  
Catalytic Mechanism ◽  
Substrate Binding ◽  
Active Form ◽  
Copper Ion ◽  
Atomic Resolution ◽  
Oxygen Species ◽  
X Ray ◽  
Oxygen Dynamics ◽  
Insight Into ◽  
Copper Centre

To unveil the activation of dioxygen on the copper centre (Cu<sub>2</sub>O<sub>2</sub>core) of tyrosinase, we performed X-ray crystallograpy with active-form tyrosinase at near atomic resolution. This study provided a novel insight into the catalytic mechanism of the tyrosinase, including the rearrangement of copper-oxygen species as well as the intramolecular migration of copper ion induced by substrate-binding.<br>

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