Thermodynamic Study of Ga‐Ge‐Zn Ternary Alloys by EMF Measurements

1980 ◽  
Vol 127 (5) ◽  
pp. 1157-1163 ◽  
Author(s):  
C. Girard ◽  
R. Baret ◽  
J. Riou ◽  
J. P. Bros
2017 ◽  
Vol 2017 ◽  
pp. 1-9 ◽  
Author(s):  
Dunya Mahammad Babanly ◽  
Qorkhmaz Mansur Huseynov ◽  
Ziya Saxaveddin Aliev ◽  
Dilgam Babir Tagiyev ◽  
Mahammad Baba Babanly

The solid-phase diagram of the Tl-TlBr-S system was clarified and the fundamental thermodynamic properties of Tl6SBr4 compound were studied on the basis of electromotive force (EMF) measurements of concentration cells relative to a thallium electrode. The EMF results were used to calculate the relative partial thermodynamic functions of thallium in alloys and the standard integral thermodynamic functions (-ΔfG0, -ΔfH0, and S0298) of Tl6SBr4 compound. All data regarding thermodynamic properties of thallium chalcogen-halides are generalized and comparatively analyzed. Consequently, certain regularities between thermodynamic functions of thallium chalcogen-halides and their binary constituents as well as degree of ionization (DI) of chemical bonding were revealed.


1997 ◽  
Vol 101 (8) ◽  
pp. 1136-1145 ◽  
Author(s):  
Felipe Hernández-Luis ◽  
Luis Fernández-Mérida ◽  
Miguel A. Esteso ◽  
Héctor R. Galleguillos-Castro

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