Defect Structure, Ionic Conductivity, and Diffusion in Calcia‐Stabilized Zirconia

1980 ◽  
Vol 127 (11) ◽  
pp. 2325-2333 ◽  
Author(s):  
Akio Nakamura ◽  
J. Bruce Wagner
Keyword(s):  
Ionic Conductivity ◽  
Defect Structure ◽  
Stabilized Zirconia ◽  
And Diffusion

Defect structure of yttria-stabilized zirconia and its influence on the ionic conductivity at elevated temperatures

1999 ◽  
Vol 59 (22) ◽  
pp. 14202-14219 ◽  
Author(s):  
J. P. Goff ◽  
W. Hayes ◽  
S. Hull ◽  
M. T. Hutchings ◽  
K. N. Clausen
Keyword(s):  
Ionic Conductivity ◽  
Defect Structure ◽  
Elevated Temperatures ◽  
Yttria Stabilized Zirconia ◽  
Stabilized Zirconia

Characterizations of Synthetic 8mol% YSZ with Comparison to 3mol %YSZ for HT-SOFC

2020 ◽  
Vol 38 (4A) ◽  
pp. 491-500
Author(s):  
Abeer F. Al-Attar ◽  
Saad B. H. Farid ◽  
Fadhil A. Hashim
Keyword(s):  
Ionic Conductivity ◽  
Electrochemical Impedance ◽  
Structural Information ◽  
Impedance Analysis ◽  
High Energy ◽  
Yttria Stabilized Zirconia ◽  
X Ray Diffraction ◽  
Stabilized Zirconia ◽  
Powder Morphology ◽  
X Ray

In this work, Yttria (Y2O3) was successfully doped into tetragonal 3mol% yttria stabilized Zirconia (3YSZ) by high energy-mechanical milling to synthesize 8mol% yttria stabilized Zirconia (8YSZ) used as an electrolyte for high temperature solid oxide fuel cells (HT-SOFC). This work aims to evaluate the densification and ionic conductivity of the sintered electrolytes at 1650°C. The bulk density was measured according to ASTM C373-17. The powder morphology and the microstructure of the sintered electrolytes were analyzed via Field Emission Scanning Electron Microscopy (FESEM). The chemical analysis was obtained with Energy-dispersive X-ray spectroscopy (EDS). Also, X-ray diffraction (XRD) was used to obtain structural information of the starting materials and the sintered electrolytes. The ionic conductivity was obtained through electrochemical impedance spectroscopy (EIS) in the air as a function of temperatures at a frequency range of 100(mHz)-100(kHz). It is found that the 3YSZ has a higher density than the 8YSZ. The impedance analysis showed that the ionic conductivity of the prepared 8YSZ at 800°C is0.906 (S.cm) and it was 0.214(S.cm) of the 3YSZ. Besides, 8YSZ has a lower activation energy 0.774(eV) than that of the 3YSZ 0.901(eV). Thus, the prepared 8YSZ can be nominated as an electrolyte for the HT-SOFC.

Ionic conductivity, phase composition, and local defect structure of ZrO2-Gd2O3system solid solution crystals

2019 ◽  
Vol 23 (9) ◽  
pp. 2619-2626 ◽  
Author(s):  
Ekaterina A. Agarkova ◽  
Mikhail A. Borik ◽  
Tatiana V. Volkova ◽  
Alexey V. Kulebyakin ◽  
Irina E. Kuritsyna ◽  
...  
Keyword(s):  
Solid Solution ◽  
Phase Composition ◽  
Ionic Conductivity ◽  
Defect Structure ◽  
Local Defect
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