Cyclic Voltammetry in Solutions of Aluminum Bromide and KBr in Aromatic Hydrocarbons: III . The Behavior of Ag and Cu

1984 ◽  
Vol 131 (9) ◽  
pp. 2058-2062 ◽  
Author(s):  
M. Elam ◽  
E. Peled ◽  
E. Gileadi
Keyword(s):  
Cyclic Voltammetry ◽  
Aromatic Hydrocarbons ◽  
Aluminum Bromide

Electron affinities and Marcus reorganization energies. A correlation between gas phase electron affinities and solution phase redox potentials

1989 ◽  
Vol 67 (1) ◽  
pp. 171-175 ◽  
Author(s):  
Dennis D. Tanner ◽  
Natasha Deonarian ◽  
Abdelmajid Kharrat
Keyword(s):  
Cyclic Voltammetry ◽  
Aromatic Hydrocarbons ◽  
Solvation Energy ◽  
Polynuclear Aromatic Hydrocarbons ◽  
Redox Potentials ◽  
Electron Affinities ◽  
Solvation Energies ◽  
Linear Plot ◽  
Reorganization Energies ◽  
Linear Correlations

Redox potentials determined by cyclic voltammetry were used in conjunction with published electron affinities to determine the solvation energies for series of three classes of compounds: substituted benzoquinones, substituted nitrobenzenes, and polynuclear aromatic hydrocarbons. Excellent linear correlations were obtained between the measured electron affinities and the E0 of the substrates. The calculated electron affinities, EA (E0), were computed using the average solvation energies for the three classes of compounds, and were found to be in excellent agreement with the measured values. The nitrobenzenes and quinones had one solvation energy, while the aromatic hydrocarbons were correlated with a significantly different value. The solvation energy of a variety of compounds could also be related to their Marcus reorganization energiesλ(0), by a linear plot with a high correlation coefficient. From simple electrochemical measurements of similar compounds, either electron affinities or Marcus λ(0) values can be estimated. Keywords: electron affinities, Marcus reorganization energies, cyclic voltammetry.

Complexes of Aluminum Bromide with Aromatic Hydrocarbons in Solution1,2

1966 ◽  
Vol 88 (18) ◽  
pp. 4128-4133 ◽  
Author(s):  
Sang Up Choi ◽  
William C. Frith ◽  
Herbert C. Brown
Keyword(s):  
Aromatic Hydrocarbons ◽  
Aluminum Bromide

scholarly journals Attempted characterisation of phenanthrene-4,5-quinone and electrochemical synthesis of violanthrone-16,17-quinone. How does the stability of bay quinones correlate with structural and electronic parameters?

RSC Advances ◽  
2020 ◽  
Vol 10 (62) ◽  
pp. 38004-38012
Author(s):  
Dylan Wilkinson ◽  
Giacomo Cioncoloni ◽  
Mark D. Symes ◽  
Götz Bucher
Keyword(s):  
Cyclic Voltammetry ◽  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Electrochemical Synthesis ◽  
Carbonyl Oxygen ◽  
Computational Work ◽  
Polycyclic Aromatic ◽  
Electronic Parameters ◽  
The Stability ◽  
Oxygen Atoms

Bay quinones have the carbonyl oxygen atoms in the bay region of polycyclic aromatic hydrocarbons. This study presents cyclic voltammetry and computational work helping to understand when bay quinones can be expected to be isolable, and when not.

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