Characterization of Redox States of Nickel Hydroxide Film Electrodes by In Situ Surface Raman Spectroscopy

1988 ◽  
Vol 135 (4) ◽  
pp. 885-892 ◽  
Author(s):  
Johann Desilvestro ◽  
Dennis A. Corrigan ◽  
Michael J. Weaver
Keyword(s):  
Raman Spectroscopy ◽  
Nickel Hydroxide ◽  
Redox States ◽  
Hydroxide Film

In Situ Atomic Force Microscopy Tip-Induced Deformations and Raman Spectroscopy Characterization of Single-Wall Carbon Nanotubes

Nano Letters ◽  
2012 ◽  
Vol 12 (8) ◽  
pp. 4110-4116 ◽  
Author(s):  
P. T. Araujo ◽  
N. M. Barbosa Neto ◽  
H. Chacham ◽  
S. S. Carara ◽  
J. S. Soares ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Raman Spectroscopy ◽  
Atomic Force Microscopy ◽  
Single Wall Carbon Nanotubes ◽  
Single Wall Carbon ◽  
Force Microscopy ◽  
Atomic Force

Prototype Raman Spectroscopic Sensor for in Situ Mineral Characterization on Planetary Surfaces

1998 ◽  
Vol 52 (4) ◽  
pp. 477-487 ◽  
Author(s):  
Alian Wang ◽  
Larry A. Haskin ◽  
Enriqueta Cortez
Keyword(s):  
Raman Spectroscopy ◽  
Planetary Surfaces ◽  
Detailed Characterization ◽  
Raman Spectroscopic ◽  
Fine Grained ◽  
Target Rock ◽  
Reaction With Water ◽  
Probe Head

Raman spectroscopy has the potential to provide definitive identification and detailed characterization of the minerals that comprise rocks and soils on planetary surfaces. We have designed a probe head for Raman spectroscopy that is suitable for use on a spectrometer deployed by a rover or a lander on the surface of a planet such as Mars, the Moon, or an asteroid. The probe head is lightweight, low power, rugged, and simple. It is based on a tiny distributed feedback diode laser and volume holographic components. A protective shell surrounds the probe head and serves as a mechanical stop for the mechanical arm of a planetary rover or lander during placement of the probe head onto the surface of a rock or soil. Pressing the shell against the rough surface of a target rock or soil also places the sampling objective of the probe head in rough focus, and the probe head is designed to be tolerant of focusing errors of ∼5 mm. A breadboard version of the probe head gave spectra of high quality on clean crystals of diamond, sulfur, calcite, quartz, and olivine. The results are qualitatively comparable to those obtained by using a conventional micro-Raman spectrometer on fine-grained travertine and on difficult specimens of basaltic lavas and impactites whose original mineralogy had been altered by reaction with water and air.

scholarly journals Fast real-time monitoring of entacapone crystallization and characterization of polymorphs via Raman spectroscopy, statistics and SWAXS

2014 ◽  
Vol 64 (1) ◽  
pp. 1-13 ◽  
Author(s):  
Tomislav Jednačak ◽  
Aden Hodzic ◽  
Otto Scheibelhofer ◽  
Marijan Marijan ◽  
Johannes G. Khinast ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Optical Probe ◽  
Solvent Mixture ◽  
Binary Solvent ◽  
Solvent Mixtures ◽  
Starting Point ◽  
Principal Components Method ◽  
Components Method

Abstract Crystallization of the drug entacapone from binary solvent mixtures was monitored in situ using a Raman optical probe. The recorded Raman spectra and statistical analysis, which included the principal components method and indirect hard modeling made it possible to estimate the starting point of crystallization, to assess crystallization temperatures and to provide information on the polymorphic content of the mixture. It was established that crystallization temperatures were proportional to the volume content of the solvent in mixtures. The samples were also evaluated off-line via Raman spectroscopy and SWAXS. The collected data showed the presence of forms b and g in all solvent mixtures. In a toluene/methanol 30:70 mixture, in addition to forms b and g, at least one of the forms A, D or a was also indicated by SWAXS. The results have shown that the presence of a particular polymorph is strongly dependent on the nature and portion of the solvent in the binary solvent mixture.

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