Solvent Effect in the Electrochemical Reduction of p‐Quinones in Several Aprotic Solvents

1990 ◽  
Vol 137 (8) ◽  
pp. 2437-2443 ◽  
Author(s):  
Kazuo Sasaki ◽  
Tomoyuki Kashimura ◽  
Masahiro Ohura ◽  
Yasushi Ohsaki ◽  
Nobuaki Ohta
Keyword(s):  
Solvent Effect ◽  
Electrochemical Reduction ◽  
Aprotic Solvents

Electrochemical tools to disclose the electrochemical reduction mechanism of CO2 in aprotic solvents and ionic liquids

2021 ◽  
pp. 115411
Author(s):  
Silvia Mena ◽  
Esteve Ribas ◽  
Clara Richard ◽  
Iluminada Gallardo ◽  
Jordi Faraudo ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Electrochemical Reduction ◽  
Aprotic Solvents ◽  
Reduction Mechanism

Molecular Theory of Solvent Effect on Keto−Enol Tautomers of Formamide in Aprotic Solvents:  RISM-SCF Approach

1998 ◽  
Vol 102 (11) ◽  
pp. 2045-2050 ◽  
Author(s):  
Tateki Ishida ◽  
Fumio Hirata ◽  
Hirofumi Sato ◽  
Shigeki Kato
Keyword(s):  
Solvent Effect ◽  
Molecular Theory ◽  
Aprotic Solvents

Studies on the iodide–triiodide equilibrium

1977 ◽  
Vol 55 (5) ◽  
pp. 792-797 ◽  
Author(s):  
Robert L. Benoit ◽  
Michael F. Wilson ◽  
Sing-Yeung Lam
Keyword(s):  
Free Energy ◽  
Solvent Effect ◽  
Gas Phase ◽  
Formation Enthalpy ◽  
Aprotic Solvents ◽  
Free Energies ◽  
Potentiometric Measurements ◽  
Cast Doubt ◽  
Transfer Parameters ◽  
The Enthalpy Of Formation

The solvent effect on the iodide–triiodide equilibrium has been investigated by means of calorimetric and potentiometric measurements. The aprotic solvents studied were nitromethane, nitrobenzene, sulfolane, acetonitrile, propylene carbonate, acetophenone, dimethylformamide, dimethylsulfoxide, and o-dichlorobenzene. The resulting enthalpy and free energy changes imply that the variations of the enthalpies and free energies of transfer of the iodide and triiodide ions probably are small and that there is an important non-coulombic contribution to these transfer parameters. Values were obtained for the enthalpy of formation of two solid triiodides, which together with values for other triiodides, cast doubt on reported calculated lattice enthalpies of triiodides and formation enthalpy of I3− ion in the gas phase. This latter formation enthalpy is found to be, from our solution data, more negative than −22 kcal mol−1.

Electrochemical reduction of 2,2′-dinitrobiphenyl-X type substances in nonaqueous and aprotic solvents

1980 ◽  
Vol 25 (9) ◽  
pp. 1127-1134 ◽  
Author(s):  
J. Volke ◽  
D. Beyrová ◽  
J. Klíma ◽  
V. Volkeová ◽  
J. Hlavatý ◽  
...  
Keyword(s):  
Electrochemical Reduction ◽  
Aprotic Solvents

ChemInform Abstract: FURTHER STUDIES OF THE ELECTROCHEMICAL REDUCTION OF SULFUR IN APROTIC SOLVENTS

1973 ◽  
Vol 4 (39) ◽  
pp. no-no
Author(s):  
ROBERT P. MARTIN ◽  
WILLIAM H. JUN. DOUB ◽  
JULIAN L. JUN. ROBERTS ◽  
DONALD T. SAWYER
Keyword(s):  
Electrochemical Reduction ◽  
Aprotic Solvents
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