Standard Electrode Potentials of Li/Li+, Na/Na+, and K/K+ in Propylene Carbonate and Its Mixture with Dimethyl Sulfoxide from Free Energies of Ionic Solvation

1990 ◽  
Vol 137 (12) ◽  
pp. 3876-3878 ◽  
Author(s):  
Subhra Ray Basumallick ◽  
Indra N. Basumallick
Keyword(s):  
Dimethyl Sulfoxide ◽  
Propylene Carbonate ◽  
Free Energies ◽  
Ionic Solvation ◽  
Electrode Potentials ◽  
Standard Electrode Potentials

Spectroscopic studies of ionic solvation in propylene carbonate

1973 ◽  
Vol 77 (20) ◽  
pp. 2407-2410 ◽  
Author(s):  
Howard L. Yeager ◽  
John D. Fedyk ◽  
Richard J. Parker
Keyword(s):  
Propylene Carbonate ◽  
Spectroscopic Studies ◽  
Ionic Solvation

Reversible electrode potentials for formation of solid and liquid chlorozirconate and chlorohafnate compounds

1993 ◽  
Vol 71 (9) ◽  
pp. 1283-1289 ◽  
Author(s):  
G.J. Kipouros ◽  
S.N. Flengas
Keyword(s):  
Thermal Decomposition ◽  
Alkali Metal ◽  
Electrochemical Behaviour ◽  
Thermochemical Data ◽  
Dilute Solutions ◽  
Alkali Metal Chlorides ◽  
Metal Chlorides ◽  
Electrode Potentials ◽  
Standard Electrode Potentials

The standard electrode potentials for the formation of the pure solid and molten compounds Li2ZrCl6, Li2HfCl6, Na2ZrCl6, Na2HfCl6, K2ZrCl6, K2HfCl6, Cs2ZrCl6, and Cs2HfCl6 have been calculated from measured vapour pressures corresponding to their thermal decomposition at equilibrium and from available thermochemical data. Reversible potentials for the formation of Na2ZrCl6 and of K2ZrCl6 in solution according to the reaction[Formula: see text]where A is Na or K, have been calculated from available equilibrium vapour pressures as functions of the mole fractions of the alkali hexachlorocompounds. Standard potentials for the above reaction and "formal" potentials are also given. The latter are useful in predicting the electrochemical behaviour of dilute solutions of the hexachlorozirconates in alkali metal chlorides.

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