Lithium-Ion Transfer at the Interface Between Lithium-Ion Conductive Ceramic Electrolyte and Liquid Electrolyte-A Key to Enhancing the Rate Capability of Lithium-Ion Batteries

2005 ◽  
Vol 152 (11) ◽  
pp. A2151 ◽  
Author(s):  
Takeshi Abe ◽  
Fumihiro Sagane ◽  
Masahiro Ohtsuka ◽  
Yasutoshi Iriyama ◽  
Zempachi Ogumi
Keyword(s):  
Lithium Ion Batteries ◽  
Rate Capability ◽  
Lithium Ion ◽  
Liquid Electrolyte ◽  
Ion Transfer ◽  
Ceramic Electrolyte

scholarly journals DEVELOPMENT AND RESEARCH OF COMPOSITE ELECTROLYTE BASED ON LATP/LIPF6 SYSTEM FOR LITHIUM BATTERIES

2020 ◽  
Vol 86 (10) ◽  
pp. 75-87
Author(s):  
Ivan Lisovskyi ◽  
Serhii Solopan ◽  
Anatolii Belous ◽  
Volodymyr Khomenko ◽  
Viacheslav Barsukov
Keyword(s):  
Cathode Material ◽  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
High Energy ◽  
Liquid Electrolyte ◽  
High Energy Density ◽  
Composite Electrolyte ◽  
Power Sources ◽  
Ceramic Electrolyte ◽  
Two Samples

Electrochemical power sources (EPSs) have been an integral part of every modern person’s life for a long time. Lithium-ion batteries (LIB) are the most common among the modern EPSs. They are widely used in the various electronic devices such as smartphones, cameras, laptops, electric vehicles etc. LIBs are considered to be the best power sources for mass use due to their high energy density. However, the low level of safety has always been a weakness of the conventional lithium-ion batteries with a polymer separator impregnated with a liquid electrolyte. The paper shows the fundamental possibility to develop the lithium-ion batteries with a composite electrolyte based on a porous ceramic matrix LATP, impregnated with 1M solution of LiPF6 in a mixture of ethylene carbonate and dimethyl carbonate (1:1). Two samples of composite electrolyte of different thickness (0.8 mm and 1.6 mm) were produced. The specific capacity of the cathode material in the elements with a composite electrolyte equals 140.5 and 138.2 mAh/g, which is not significantly less than the corresponding value for the cells with a liquid electrolyte (145.6 mAh/g). The decrease in the capacity of the cathode material in the elements with a composite electrolyte is primarily connected with the non-optimal thickness of the ceramic electrolyte and, accordingly, with the increase in the internal resistance of the cell. It is established that prototypes of lithium-ion batteries with a composite electrolyte show higher stability of capacitive characteristics during long cycling. Also, the proposed composite electrolyte allows solving the problems of lithium-ion batteries associated with electrolyte leakage (liquid electrolyte is immobilized only in the pores of ceramics) and fire hazard, primarily by levelling the formation of lithium dendrites in the interelectrode space. Further research will be aimed at the reducing the thickness of the ceramic electrolyte and developing a process for applying a protective layer to eliminate the recovery of LATP with lithium metal.

A SnO2@carbon nanocluster anode material with superior cyclability and rate capability for lithium-ion batteries

Nanoscale ◽  
2013 ◽  
Vol 5 (8) ◽  
pp. 3298 ◽  
Author(s):  
Min He ◽  
Lixia Yuan ◽  
Xianluo Hu ◽  
Wuxing Zhang ◽  
Jie Shu ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
Rate Capability ◽  
Lithium Ion

FEC-LiTFSI-Pyr1ATFSI Ionic Liquid Electrolyte to Improve Low Temperature Performance of Lithium-Ion Batteries

2014 ◽  
Vol 986-987 ◽  
pp. 80-83
Author(s):  
Xiao Xue Zhang ◽  
Zhen Feng Wang ◽  
Cui Hua Li ◽  
Jian Hong Liu ◽  
Qian Ling Zhang
Keyword(s):  
Low Temperature ◽  
Lithium Ion Batteries ◽  
Low Temperatures ◽  
Freezing Point ◽  
Lithium Ion ◽  
Liquid Electrolyte ◽  
Capacity Retention ◽  
Composite Electrolyte ◽  
Ionic Liquid Electrolyte ◽  
Fluoroethylene Carbonate

N-methyl-N-allylpyrrolidinium bis (trifluoromethanesulfonyl) imide (PYR1ATFSI) with substantial supercooling behavior is synthesized to develop low temperature electrolyte for lithium-ion batteries. Additive fluoroethylene carbonate (FEC) in LiTFSI/PYR1ATFSI/EC/PC/EMC is found that it can reduce the freezing point. LiFePO4/Li coin cells with the FEC-PYR1ATFSI electrolyte exhibit good capacity retention, reversible cycling behavior at low temperatures. The good performance can be attributed to the decrease in the freezing point and the polarization of the composite electrolyte.

SiO2@NiO core–shell nanocomposites as high performance anode materials for lithium-ion batteries

RSC Advances ◽  
2015 ◽  
Vol 5 (77) ◽  
pp. 63012-63016 ◽  
Author(s):  
Yourong Wang ◽  
Wei Zhou ◽  
Liping Zhang ◽  
Guangsen Song ◽  
Siqing Cheng
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Materials ◽  
High Performance ◽  
Coulombic Efficiency ◽  
Rate Capability ◽  
Lithium Ion ◽  
Cycling Stability ◽  
Core Shell ◽  
Excellent Cycling Stability

A SiO2@NiO core–shell electrode exhibits almost 100% coulombic efficiency, excellent cycling stability and rate capability after the first few cycles.

A comparative study of ordered mesoporous carbons with different pore structures as anode materials for lithium-ion batteries

RSC Advances ◽  
2015 ◽  
Vol 5 (53) ◽  
pp. 42922-42930 ◽  
Author(s):  
Diganta Saikia ◽  
Tzu-Hua Wang ◽  
Chieh-Ju Chou ◽  
Jason Fang ◽  
Li-Duan Tsai ◽  
...  
Keyword(s):  
Comparative Study ◽  
Lithium Ion Batteries ◽  
Anode Materials ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Cycling Stability ◽  
Mesoporous Carbons ◽  
Ordered Mesoporous Carbons ◽  
Ordered Mesoporous

Ordered mesoporous carbons CMK-3 and CMK-8 with different mesostructures are evaluated as anode materials for lithium-ion batteries. CMK-8 possesses higher reversible capacity, better cycling stability and rate capability than CMK-3.

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