In Situ Studies of Cu Deposition in the Presence of Quaternary Ammonium Salts

1998 ◽  
Vol 145 (4) ◽  
pp. 1218-1226 ◽  
Author(s):  
Elias D. Eliadis ◽  
Richard C. Alkire
Keyword(s):  
Quaternary Ammonium ◽  
Quaternary Ammonium Salts ◽  
Ammonium Salts ◽  
In Situ Studies

Cationic quaternary ammonium salt-catalyzed LED-induced living radical polymerization with in situ halogen exchange

2020 ◽  
Vol 11 (23) ◽  
pp. 3876-3883
Author(s):  
Feifei Li ◽  
Wanting Yang ◽  
Mengmeng Li ◽  
Lin Zhou ◽  
Lin Lei
Keyword(s):  
Radical Polymerization ◽  
Quaternary Ammonium ◽  
Light Emitting Diode ◽  
Quaternary Ammonium Salts ◽  
Living Radical Polymerization ◽  
Ammonium Salts ◽  
Light Emitting ◽  
Halogen Exchange ◽  
Methacrylate Monomers

Cationic quaternary ammonium salts were employed as organocatalysts for light-emitting diode (LED)-induced living radical polymerization (LRP) with the in situ halogen exchange of methacrylate monomers.

scholarly journals Exploring the Scope of Tandem Palladium and Isothiourea Relay Catalysis for the Synthesis of α-Amino Acid Derivatives

Molecules ◽  
2020 ◽  
Vol 25 (10) ◽  
pp. 2463
Author(s):  
Jacqueline Bitai ◽  
Alexandra M. Z. Slawin ◽  
David B. Cordes ◽  
Andrew D. Smith
Keyword(s):  
Amino Acid ◽  
Transition State ◽  
Quaternary Ammonium ◽  
Palladium Catalyst ◽  
Quaternary Ammonium Salts ◽  
Sigmatropic Rearrangement ◽  
Ammonium Salts ◽  
Amino Acid Derivatives ◽  
Substitution Pattern

The scope and limitations of a tandem N-allylation/[2,3]-rearrangement protocol are investigated through the incorporation of a variety of functional groups within an allylic phosphate precursor. This method uses readily accessible N,N-dimethylglycine aryl esters and functionalized allylic phosphates, forming quaternary ammonium salts in situ in the presence of a palladium catalyst. Subsequent enantioselective [2,3]-sigmatropic rearrangement, promoted by the chiral isothiourea tetramisole, generates α-amino acid derivatives with two contiguous stereocenters. The incorporation of electron-withdrawing ester and amide groups gave the best results, furnishing the desired products in moderate to good yields (29–70%), with low diastereocontrol (typically 60:40 dr) but high enantioselectivity (up to 90:10 er). These results indicate that substrate–catalyst interactions in the proposed transition state are sensitive to the substitution pattern of the substrates.

Synthesis of Amidation Agents and their Reactivity in Condensation Reactions

Synthesis ◽  
2020 ◽  
Author(s):  
Roberto Sole ◽  
Vanessa Gatto ◽  
Silvia Conca ◽  
Lodovico Agostinis ◽  
Noemi Bardella ◽  
...  
Keyword(s):  
Quaternary Ammonium ◽  
Quaternary Ammonium Salts ◽  
Ammonium Salts ◽  
The Novel ◽  
Reaction Conditions ◽  
1H And 13C Nmr ◽  
Full Characterization ◽  
Ft Ir

Nowadays, the development of new approaches which smartly bypass the use of harsh reaction conditions and hazardous chemicals covers a pivotal role. In this research paper the synthesis, characterization and application of novel libraries of triazine bis-quaternary ammonium salts, employed as coupling agents to produce amides, is reported. Full characterization of the novel compounds by 1H and 13C NMR, FT-IR spectroscopy, ESI-HRMS and elemental analysis (EA) is provided. Furthermore, a comparison in terms of activity of the preformed triazine compounds versus in situ formulations has been evaluated for the formation of amides in the presence of phenylethylamine and different aliphatic or aromatic acids. A possible correlation between the chemical structure of the triazine and their reactivity for the formation of the triazine bis-quaternary ammonium salts is also reported. Moreover, best performing condensation agents have been further tested for the cross-linking of collagen powder as possible wet white tanning systems, for sustainable and environmentally friendly leather tanning.

Synthesis and stability of 1-aminoalkylphosphonic acid quaternary ammonium salts

2021 ◽  
Author(s):  
Tomasz K. Olszewski ◽  
Anna Brol
Keyword(s):  
Phosphonic Acid ◽  
Quaternary Ammonium ◽  
Alkylating Agent ◽  
Quaternary Ammonium Salts ◽  
Ammonium Salts ◽  
Aminoalkylphosphonic Acid

An effective protocol for quaternization of simple 1-aminoalkylphosphonic acids under basic conditions and using Me2SO4 as convenient alkylating agent is reported. In the course of reaction phosphonic acid quaternary ammonium...

scholarly journals Green Accelerated Synthesis, Antimicrobial Activity and Seed Germination Test of Quaternary Ammonium Salts of 1,2-bis(4-pyridyl)ethane

Molecules ◽  
2019 ◽  
Vol 24 (13) ◽  
pp. 2424 ◽  
Author(s):  
Tăbăcaru ◽  
Botezatu ◽  
Horincar ◽  
Furdui ◽  
Dinică
Keyword(s):  
Escherichia Coli ◽  
Triticum Aestivum ◽  
Seed Germination ◽  
Quaternary Ammonium ◽  
Pathogenic Bacteria ◽  
Classical Method ◽  
Triticum Aestivum L ◽  
Quaternary Ammonium Salts ◽  
Ammonium Salts ◽  
Radicle Growth

A family of fifteen quaternary ammonium salts (QAs), bearing the 1,2-bis(4-pyridyl)ethane core, were obtained using for the first time two different green methods, such as microwave (MW) and ultrasounds (US) irradiation, with very good yields and in much shorter times compared to the classical method, and an assay on their antimicrobial action against Escherichia coli (E. coli) was carried out. While 12 to 24 hours were required for complete alkylation of 1,2-bis(4-pyridyl)ethane by reactive halogenated derivatives in anhydrous solvent under reflux conditions, MW and US irradiation reduced the reaction time and the desired products were achieved in a few min. One of the aims of this study was to evaluate the antibacterial potential of the synthesized QAs against pathogenic bacteria, along with their impact on germination activity of wheat seeds (Triticum aestivum L.). The antibacterial activity of the QAs against Escherichia coli was explored by determining the minimum inhibitory concentration (MIC). The MIC values varied from 0.312 to 2.5 mg/mL, highlighting the lowest values attained for the derivatives containing methoxy, chlorine and benzofurane functional groups. The viability of aerobic bacteria was determined with the Tetrazolium/Formazan Test, a method that was found to be the best alternative approach with respect to the difuzimetric method. Seeds of Triticum aestivum L. were used for the evaluation of the germination indicators, such as seed germination (SG), the relative seed germination (RSG), the relative radicle growth (RRG), and the seed germination index (GI). The toxicity studies of QAs 1, 4 and 7, at two different concentrations, showed no inhibitory effect on seed germination.

Interaction of water-insoluble quaternary ammonium salts with the hydrated silica surface

1996 ◽  
Vol 32 (6) ◽  
pp. 331-334
Author(s):  
V. V. Turov ◽  
O. A. Zaporozhets ◽  
O. Yu. Nadzhafova ◽  
V. V. Sukhan
Keyword(s):  
Quaternary Ammonium ◽  
Silica Surface ◽  
Quaternary Ammonium Salts ◽  
Ammonium Salts ◽  
Hydrated Silica
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