Comparison of PVDF and PVDF-TFE-P as Binders for Electrode Materials Showing Large Volume Changes in Lithium-Ion Batteries

2003 ◽  
Vol 150 (8) ◽  
pp. A1073 ◽  
Author(s):  
Zonghai Chen ◽  
L. Christensen ◽  
J. R. Dahn
Keyword(s):  
Lithium Ion Batteries ◽  
Large Volume ◽  
Electrode Materials ◽  
Lithium Ion ◽  
Volume Changes

Two-dimensional SnS2@PANI nanoplates with high capacity and excellent stability for lithium-ion batteries

2015 ◽  
Vol 3 (7) ◽  
pp. 3659-3666 ◽  
Author(s):  
Gang Wang ◽  
Jun Peng ◽  
Lili Zhang ◽  
Jun Zhang ◽  
Bin Dai ◽  
...  
Keyword(s):  
Electron Transport ◽  
Lithium Ion Batteries ◽  
Electrode Materials ◽  
High Capacity ◽  
Lithium Ion ◽  
Two Dimensional ◽  
Volume Changes ◽  
Nanostructured Electrode ◽  
Charge Discharge ◽  
Excellent Stability

Nanostructured electrode materials have been extensively studied with the aim of enhancing lithium ion and electron transport and lowering the stress caused by their volume changes during the charge–discharge processes of electrodes in lithium-ion batteries.

scholarly journals Enhanced Electrochemical Performance of Sb2O3 as an Anode for Lithium-Ion Batteries by a Stable Cross-Linked Binder

2019 ◽  
Vol 9 (13) ◽  
pp. 2677 ◽  
Author(s):  
Yong Liu ◽  
Haichao Wang ◽  
Keke Yang ◽  
Yingnan Yang ◽  
Junqing Ma ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Large Volume ◽  
Polyvinylidene Fluoride ◽  
Electrode Materials ◽  
Lithium Ion ◽  
Cycling Performance ◽  
Electrochemical Stability ◽  
Esterification Reaction ◽  
Conductive Agent ◽  
Enhanced Electrochemical Performance

A binder plays an important role in lithium-ion batteries (LIBs), especially for the electrode materials which have large volume expansion during charge and discharge. In this work, we designed a cross-linked polymeric binder with an esterification reaction of Sodium Carboxymethyl Cellulose (CMC) and Fumaric Acid (FA), and successfully used it in an Sb2O3 anode for LIBs. Compared with conventional binder polyvinylidene fluoride (PVDF) and CMC, the new cross-linked binder improves the electrochemical stability of the Sb2O3 anode. Specifically, with CMC-FA binder, the battery could deliver ~611.4 mAh g−1 after 200 cycles under the current density of 0.2 A g−1, while with PVDF or CMC binder, the battery degraded to 265.1 and 322.3 mAh g−1, respectively. The improved cycling performance is mainly due to that the cross-linked CMC-FA network could not only efficiently improve the contact between Sb2O3 and conductive agent, but can also buffer the large volume charge of the electrode during repeated charge/discharge cycles.

Deposited Layers as Negative Electrodes for Lithium Ion Batteries

2021 ◽  
Vol 105 (1) ◽  
pp. 13-20
Author(s):  
Josef Maca ◽  
Jiri Libich ◽  
Tomas Kazda ◽  
Kamil Jasso ◽  
Pavel Cudek
Keyword(s):  
Thin Layer ◽  
Lithium Ion Batteries ◽  
Large Volume ◽  
3D Structure ◽  
Lithium Ion ◽  
Point Of View ◽  
Volume Changes ◽  
Negative Electrodes ◽  
Main Disadvantage ◽  
Large Volume Change

The battery usage increases every year. The batteries help with development of mobility both from point of view of portable electronic and from view of goods and people transport in electromobility. One of the main parameters is gravimetric and volumetric capacity, which we are trying continually increase. One of the main ways is to change current used material by new ones with better parameters. One of possibilities is to use thin layer and so-called battery conversion principle. Electrodes works on conversion principle have usual higher capacities. The main disadvantage of such system is large volume change of electrode material due charging and discharging. This can be partly solved by special 3D structure which compensate the volume changes. This work focusses on preparing basic thin layer electrode by help of electrodeposition. The electrodes are then cycled against lithium.

The precise synthesis of twin-born Fe3O4/FeS/carbon nanosheets for high-rate lithium-ion batteries

2021 ◽  
Author(s):  
Linlin Ma ◽  
Baoxiu Hou ◽  
Ningzhao Shang ◽  
Shuaihua Zhang ◽  
Chun Wang ◽  
...  
Keyword(s):  
Metal Oxides ◽  
Lithium Ion Batteries ◽  
Large Volume ◽  
Lithium Ion ◽  
High Rate ◽  
Next Generation ◽  
Volume Changes ◽  
Carbon Nanosheets ◽  
Practical Applications ◽  
Ion Conductivities

Metal oxides/sulfides have been considered as promising anode candidates for use in next-generation lithium-ion batteries (LIBs), but the large volume changes and poor electron and ion conductivities limit their practical applications.

scholarly journals Advances in the Applications of Graphene-Based Nanocomposites in Clean Energy Materials

Crystals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 47
Author(s):  
Yiqiu Xiang ◽  
Ling Xin ◽  
Jiwei Hu ◽  
Caifang Li ◽  
Jimei Qi ◽  
...  
Keyword(s):  
Solar Cells ◽  
Fuel Cells ◽  
Lithium Ion Batteries ◽  
Electrode Materials ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Clean Energy ◽  
Proton Exchange ◽  
Energy Storage And Conversion ◽  
Thermoelectric Conversion

Extensive use of fossil fuels can lead to energy depletion and serious environmental pollution. Therefore, it is necessary to solve these problems by developing clean energy. Graphene materials own the advantages of high electrocatalytic activity, high conductivity, excellent mechanical strength, strong flexibility, large specific surface area and light weight, thus giving the potential to store electric charge, ions or hydrogen. Graphene-based nanocomposites have become new research hotspots in the field of energy storage and conversion, such as in fuel cells, lithium-ion batteries, solar cells and thermoelectric conversion. Graphene as a catalyst carrier of hydrogen fuel cells has been further modified to obtain higher and more uniform metal dispersion, hence improving the electrocatalyst activity. Moreover, it can complement the network of electroactive materials to buffer the change of electrode volume and prevent the breakage and aggregation of electrode materials, and graphene oxide is also used as a cheap and sustainable proton exchange membrane. In lithium-ion batteries, substituting heteroatoms for carbon atoms in graphene composite electrodes can produce defects on the graphitized surface which have a good reversible specific capacity and increased energy and power densities. In solar cells, the performance of the interface and junction is enhanced by using a few layers of graphene-based composites and more electron-hole pairs are collected; therefore, the conversion efficiency is increased. Graphene has a high Seebeck coefficient, and therefore, it is a potential thermoelectric material. In this paper, we review the latest progress in the synthesis, characterization, evaluation and properties of graphene-based composites and their practical applications in fuel cells, lithium-ion batteries, solar cells and thermoelectric conversion.

Graphite@Silicon embedded in Carbon Conformally Coated Tiny SiO2 Nanoparticles Matrix for High-Performance Lithium-Ion Batteries

2021 ◽  
Author(s):  
Huitian Liu ◽  
Xu Liu ◽  
Zhaolin Liu ◽  
Junyan Tao ◽  
Xiaoqian Dai ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Large Volume ◽  
Volume Expansion ◽  
Anode Materials ◽  
High Performance ◽  
Lithium Ion ◽  
Sio2 Nanoparticles ◽  
Carbon Composites ◽  
Effective Strategy ◽  
Si Anode

Engineering of graphite@Si/carbon composites is considered as an effective strategy to surmount the shortcomings of low conductivity and large volume expansion of bare Si anode materials for lithium-ion batteries. Nevertheless,...

Recent Developments on and Prospects for Electrode Materials with Hierarchical Structures for Lithium-Ion Batteries

2017 ◽  
Vol 8 (6) ◽  
pp. 1701415 ◽  
Author(s):  
Limin Zhou ◽  
Kai Zhang ◽  
Zhe Hu ◽  
Zhanliang Tao ◽  
Liqiang Mai ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Electrode Materials ◽  
Hierarchical Structures ◽  
Lithium Ion ◽  
Recent Developments

scholarly journals Aging Mechanisms of Electrode Materials in Lithium-Ion Batteries for Electric Vehicles

2015 ◽  
Vol 2015 ◽  
pp. 1-11 ◽  
Author(s):  
Cheng Lin ◽  
Aihua Tang ◽  
Hao Mu ◽  
Wenwei Wang ◽  
Chun Wang
Keyword(s):  
Lithium Ion Batteries ◽  
Electrode Materials ◽  
Electrochemical Behaviour ◽  
Lithium Ion ◽  
Storage Conditions ◽  
Carbon Anode ◽  
Side Reactions ◽  
Metallic Oxide ◽  
Lithium Ions ◽  
Aging Mechanisms

Electrode material aging leads to a decrease in capacity and/or a rise in resistance of the whole cell and thus can dramatically affect the performance of lithium-ion batteries. Furthermore, the aging phenomena are extremely complicated to describe due to the coupling of various factors. In this review, we give an interpretation of capacity/power fading of electrode-oriented aging mechanisms under cycling and various storage conditions for metallic oxide-based cathodes and carbon-based anodes. For the cathode of lithium-ion batteries, the mechanical stress and strain resulting from the lithium ions insertion and extraction predominantly lead to structural disordering. Another important aging mechanism is the metal dissolution from the cathode and the subsequent deposition on the anode. For the anode, the main aging mechanisms are the loss of recyclable lithium ions caused by the formation and increasing growth of a solid electrolyte interphase (SEI) and the mechanical fatigue caused by the diffusion-induced stress on the carbon anode particles. Additionally, electrode aging largely depends on the electrochemical behaviour under cycling and storage conditions and results from both structural/morphological changes and side reactions aggravated by decomposition products and protic impurities in the electrolyte.

Self-assembly synthesis of nitrogen-doped mesoporous carbons used as high-performance electrode materials in lithium-ion batteries and supercapacitors

2017 ◽  
Vol 41 (21) ◽  
pp. 12901-12909 ◽  
Author(s):  
Chunfeng Shao ◽  
Ziqiang Wang ◽  
Errui Wang ◽  
Shujun Qiu ◽  
Hailiang Chu ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Self Assembly ◽  
High Performance ◽  
Electrode Materials ◽  
Lithium Ion ◽  
Mesoporous Carbons ◽  
Nitrogen Doped ◽  
First Time ◽  
Enhanced Electrochemical Performance

Guanine was, for the first time, used as a nitrogen source during the synthesis of nitrogen-doped porous carbons (NMCs) with enhanced electrochemical performance.

LixCn as Anode Material for Lithium Ion Batteries

2006 ◽  
Vol 972 ◽  
Author(s):  
Haiming Xie ◽  
Haiying Yu ◽  
Abraham F. Jalbout ◽  
Guiling Yang ◽  
Xiumei Pan ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
Cathode Materials ◽  
Electrode Materials ◽  
Lithium Ion ◽  
Limiting Factors ◽  
Discharge Process ◽  
Metal Foil ◽  
Lithium Metal ◽  
Lithium Secondary Batteries

AbstractWe design a way that the anode hosts provide lithium ion in lithium ion battery operation. If the limiting factors of the cathode materials are less, there will be more alternatives for it. It was proven to be successful by two kinds of test cells based on LixCn as anode material, and β-FeOOH or Cr8O21 as cathode materials. Their theoretical capacities are much higher than those present electrode materials. Unlike the lithium secondary batteries with lithium metal foil or lithium alloy as anode, this type of lithium ion batteries with LixCn as anode prohibit dendrite formation during charging-discharge process. The idea of lithium ion sources coming from the anode can come true successfully as a result that steady protecting solution be sought for LixCn.

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