The Role of Low-Dimensional Systems in Electrochemical Phase Formation and Dissolution Processes

2002 ◽  
Vol 149 (12) ◽  
pp. K47 ◽  
Author(s):  
W. J. Lorenz ◽  
G. Staikov ◽  
W. Schindler ◽  
W. Wiesbeck
1997 ◽  
Vol 75 (11) ◽  
pp. 1624-1634 ◽  
Author(s):  
G. Staikov ◽  
W.J. Lorenz

The role of different crystal imperfections and surface inhomogeneities in the processes of electrochemical phase formation and crystal growth is discussed on the basis of experimental results obtained by electrodeposition of metals on native and foreign single crystal substrates in selected model systems. The major role of screw dislocations in the electrochemical growth of real crystals is demonstrated in the case of silver electrodeposition on silver single crystal faces prepared by the so-called capillary technique. Experimental results show that the electrochemical spiral growth of silver crystal faces with low dislocation density can be used for a preparation of surfaces with a defined and uniform density of monatomic steps. Combined electrochemical and in situ scanning probe microscopy (SPM) studies of underpotential deposition (UPD) of metals on foreign single crystal substrates show that surface inhomogeneities induce a stepwise formation of different low-dimensional (0D, 1D, and 2D) metal phases. The thermodynamic, kinetic, and structural aspects of the stepwise formation of Me phases of different dimensionality in the UPD range are discussed on an atomic level using results of electrochemical and in situ SPM measurements in various systems. Keywords: electrocrystallization, screw dislocations, spiral growth, surface inhomogeneities, underpotential deposition, low-dimensional phases, scanning tunneling microscopy.


ChemInform ◽  
2003 ◽  
Vol 34 (9) ◽  
Author(s):  
W. J. Lorenz ◽  
G. Staikov ◽  
W. Schindler ◽  
W. Wiesbeck

ChemNanoMat ◽  
2021 ◽  
Author(s):  
Dirk Vanderzande ◽  
Wouter Van Gompel ◽  
Roald Herckens ◽  
Martijn Mertens ◽  
Paul-Henry Denis ◽  
...  

2021 ◽  
Vol 9 ◽  
Author(s):  
Noa Raindel ◽  
Yuvalal Liron ◽  
Uri Alon

Comprehending the meaning of body postures is essential for social organisms such as humans. For example, it is important to understand at a glance whether two people seen at a distance are in a friendly or conflictual interaction. However, it is still unclear what fraction of the possible body configurations carry meaning, and what is the best way to characterize such meaning. Here, we address this by using stick figures as a low-dimensional, yet evocative, representation of body postures. We systematically scanned a set of 1,470 upper-body postures of stick figures in a dyad with a second stick figure with a neutral pose. We asked participants to rate the stick figure in terms of 20 emotion adjectives like sad or triumphant and in terms of eight active verbs that connote intent like to threaten and to comfort. The stick figure configuration space was dense with meaning: people strongly agreed on more than half of the configurations. The meaning was generally smooth in the sense that small changes in posture had a small effect on the meaning, but certain small changes had a large effect. Configurations carried meaning in both emotions and intent, but the intent verbs covered more configurations. The effectiveness of the intent verbs in describing body postures aligns with a theory, originating from the theater, called dramatic action theory. This suggests that, in addition to the well-studied role of emotional states in describing body language, much can be gained by using also dramatic action verbs which signal the effort to change the state of others. We provide a dictionary of stick figure configurations and their perceived meaning. This systematic scan of body configurations might be useful to teaching people and machines to decipher body postures in human interactions.


2010 ◽  
Vol 107 (9) ◽  
pp. 093515 ◽  
Author(s):  
S. Gaudet ◽  
C. Coia ◽  
P. Desjardins ◽  
C. Lavoie

2021 ◽  
Vol 104 (8) ◽  
Author(s):  
Jun Liu ◽  
Yongxin Yao ◽  
Jianhua Zhang ◽  
Kai-Ming Ho ◽  
Cai-Zhuang Wang

2020 ◽  
Vol 49 (21) ◽  
pp. 7123-7132 ◽  
Author(s):  
Nandhini J. Usharani ◽  
Rajat Shringi ◽  
Harshil Sanghavi ◽  
S. Subramanian ◽  
S. S. Bhattacharya

Presence of multivalency/non-stoichiometry to accommodate a different-sized cation and maintaining electroneutrality were identified as the critical criteria for single-phase formation in multicomponent/high entropy systems.


2000 ◽  
Vol 284-288 ◽  
pp. 1563-1564
Author(s):  
V.G Peschansky ◽  
G Ivanovski ◽  
O.V Kirichenko ◽  
D Krstovska

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