Cerium(III) Inhibition of Corrosion-Driven Organic Coating Delamination Studied Using a Scanning Kelvin Probe Technique [Journal of The Electrochemical Society, 149, B154 (2002)]

2002 ◽  
Vol 149 (6) ◽  
pp. L4 ◽  
Author(s):  
G. Williams ◽  
H. N. McMurray ◽  
D. A. Worsley
Keyword(s):  
Organic Coating ◽  
Kelvin Probe ◽  
Probe Technique ◽  
Electrochemical Society ◽  
Scanning Kelvin Probe ◽  
Coating Delamination

scholarly journals Nondestructive Evaluation of Urethane-Ester Coating Systems Using the Scanning Kelvin Probe Technique

CORROSION ◽  
10.5006/3020 ◽  
2019 ◽  
Vol 75 (5) ◽  
pp. 457-464
Author(s):  
David J. Borth ◽  
Erick B. Iezzi ◽  
Douglas S. Dudis ◽  
Douglas C. Hansen
Keyword(s):  
Nondestructive Evaluation ◽  
Kelvin Probe ◽  
Probe Technique ◽  
Scanning Kelvin Probe

Investigation Of Blister Formed On Coated Mild Steel Using Scanning Kelvin Probe

2012 ◽  
Author(s):  
Zalilah Sharer Sahir ◽  
John Malcolm Sykes
Keyword(s):  
Mild Steel ◽  
Key Words ◽  
Ammonium Chloride ◽  
Chloride Solution ◽  
Organic Coating ◽  
Kelvin Probe ◽  
Scanning Kelvin Probe ◽  
Coated Metal ◽  
Potential Map ◽  
Electrochemical Potentials

Degradasi pada besi bersalut cat dari segi gelembung yang terbentuk telah dikaji selepas direndam di dalam larutan 3% natrium klorida dan 3% ammonium klorida. Imbasan probe Kelvin (SKP) telah digunakan untuk menghasilkan peta keupayaan kimia–elektro bagi mengenal pasti kawasan anod dan katod dibawah gelembung dan kawasan persekitarannya. Bagi gelembung yang terhasil pada panel yang direndam dalam larutan 3% sodium klorida, peta upaya SKP menunjukkan gelembung yang terbentuk adalah di kawasan katod yang disebabkan oleh alkali, dimana kawasan anod juga dilihat terbentuk berdekatan. Walhal bagi peta upaya SKP untuk gelembung yang terhasil pada panel yang direndam di dalam larutan 3% ammonium klorida menunjukkan kehadiran kawasan katod dikelilingi oleh kawasan anod. Kata kunci: Cat organik; imbasan probe Kelvin; gelembung The degradation of a coated metal in term of the area underneath a blister has been studied after being immersed in 3% sodium chlorida and 3% ammonium chloride solution. Scanning Kelvin probe (SKP) was used to map electrochemical potentials, identifying anodic and cathodic regions underneath a blister and the surrounding coating. For blisters formed on coated panel immersed in sodium chlorida solution, SKP potential map reveals that the blister has formed at a cathode due to alkali but anodes form nearby (not remote). Meanwhile SKP potential map for blister formed on coated panel in 3% ammonium chloride reveals the presence of cathodic regions within the anodic areas. Key words: Organic coating; scanning Kelvin Probe; blister

Hydrogen detection in high strength dual phase steel using scanning Kelvin probe technique and XPS analyses

2021 ◽  
pp. 110072
Author(s):  
Flavien Vucko ◽  
Shinji Ootsuka ◽  
Stéphane Rioual ◽  
Erwan Diler ◽  
Andrej Nazarov ◽  
...  
Keyword(s):  
Dual Phase Steel ◽  
High Strength ◽  
Dual Phase ◽  
Kelvin Probe ◽  
Hydrogen Detection ◽  
Probe Technique ◽  
Scanning Kelvin Probe

scholarly journals A mechanistic investigation of corrosion-driven organic coating failure on magnesium and its alloys

2019 ◽  
Vol 3 (1) ◽  
Author(s):  
Geraint Williams ◽  
Christos Kousis ◽  
Neil McMurray ◽  
Patrick Keil
Keyword(s):  
Hydrogen Evolution ◽  
Ionic Current ◽  
Time Lapse ◽  
Organic Coating ◽  
Kelvin Probe ◽  
Group I ◽  
Mechanistic Investigation ◽  
Filiform Corrosion ◽  
Coating Delamination ◽  
Chloride Salts

AbstractThe failure mechanism of model organic coatings from Mg alloy surfaces is characterised by a combination in-situ scanning Kelvin probe analysis and time lapse photography. Initiation of underfilm corrosion by application of group I chloride salts to a penetrative coating defect produces an apparent cathodic-driven coating delamination, where the disbondment distance increases linearly with time at high relative humidity, although filiform corrosion (FFC) is also observed in the vicinity of the defect. The disbondment process occurs both in the presence and absence of oxygen, indicating that hydrogen evolution comprises the predominant underfilm cathodic reaction. Post-corrosion elemental analysis of the delaminated region shows an abundance of group I cation, but no chloride. When magnesium chloride or HCl are used to initiate corrosion, then only FFC is produced. The mechanism is discussed in terms of net anodic dissolution at the defect coupled with underfilm cathodic hydrogen evolution, producing organic coating disbondment under conditions where cations are able to transport ionic current within a zone of increased pH.

Inhibitor pretreatment synergies demonstrated using a scanning Kelvin probe technique

2003 ◽  
Vol 38 (2) ◽  
pp. 112-118 ◽  
Author(s):  
H. N. McMurray ◽  
D. Williams ◽  
G. Williams ◽  
D. Worsley
Keyword(s):  
Kelvin Probe ◽  
Probe Technique ◽  
Scanning Kelvin Probe
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