Internal and External Oxidation of Pt(Al) Solid Solution at Elevated Temperatures

2000 ◽  
Vol 147 (1) ◽  
pp. 283 ◽  
Author(s):  
Makoto Nanko ◽  
Masahiro Ozawa ◽  
Toshio Maruyama
Keyword(s):  
Solid Solution ◽  
Elevated Temperatures ◽  
External Oxidation

High-Temperature Instability of A Cr2Nb-Nb(Cr) Microlaminate Composite

1996 ◽  
Vol 54 ◽  
pp. 374-375
Author(s):  
M. Larsen ◽  
R.G. Rowe ◽  
D.W. Skelly
Keyword(s):  
Heat Treatment ◽  
Solid Solution ◽  
High Temperature ◽  
Elevated Temperatures ◽  
Aircraft Engine ◽  
Lattice Parameter ◽  
Microstructural Stability ◽  
Elevated Temperature Strength ◽  
Cross Sectional ◽  
Bcc Structure

Microlaminate composites consisting of alternating layers of a high temperature intermetallic compound for elevated temperature strength and a ductile refractory metal for toughening may have uses in aircraft engine turbines. Microstructural stability at elevated temperatures is a crucial requirement for these composites. A microlaminate composite consisting of alternating layers of Cr2Nb and Nb(Cr) was produced by vapor phase deposition. The stability of the layers at elevated temperatures was investigated by cross-sectional TEM.The as-deposited composite consists of layers of a Nb(Cr) solid solution with a composition in atomic percent of 91% Nb and 9% Cr. It has a bcc structure with highly elongated grains. Alternating with this Nb(Cr) layer is the Cr2Nb layer. However, this layer has deposited as a fine grain Cr(Nb) solid solution with a metastable bcc structure and a lattice parameter about half way between that of pure Nb and pure Cr. The atomic composition of this layer is 60% Cr and 40% Nb. The interface between the layers in the as-deposited condition appears very flat (figure 1). After a two hour, 1200 °C heat treatment, the metastable Cr(Nb) layer transforms to the Cr2Nb phase with the C15 cubic structure. Grain coarsening occurs in the Nb(Cr) layer and the interface between the layers roughen. The roughening of the interface is a prelude to an instability of the interface at higher heat treatment temperatures with perturbations of the Cr2Nb grains penetrating into the Nb(Cr) layer.

CARLSON ALLOY C600 and C600 ESR

Alloy Digest ◽  
1994 ◽  
Vol 43 (11) ◽  
Keyword(s):  
Mechanical Properties ◽  
Solid Solution ◽  
Fracture Toughness ◽  
Cold Working ◽  
Elevated Temperatures ◽  
High Strength ◽  
Heat Treating ◽  
Solid Solution Alloy ◽  
Resistance To Oxidation ◽  
Good Workability

Abstract CARLSON ALLOYS C600 AND C600 ESR have excellent mechanical properties from sub-zero to elevated temperatures with excellent resistance to oxidation at high temperatures. It is a solid-solution alloy that can be hardened only by cold working. High strength at temperature is combined with good workability. This datasheet provides information on composition, physical properties, elasticity, and tensile properties as well as fracture toughness. It also includes information on corrosion resistance as well as forming, heat treating, and machining. Filing Code: Ni-470. Producer or source: G.O. Carlson Inc.

Decomposition of Solid Solution of the AA5083 Alloy upon Exposure to Elevated Temperatures

2000 ◽  
Vol 331-337 ◽  
pp. 1089-1094 ◽  
Author(s):  
D. Sampath ◽  
S. Moldenhauer ◽  
H.R. Schipper ◽  
K. Mechsner ◽  
A. Haszler
Keyword(s):  
Solid Solution ◽  
Elevated Temperatures ◽  
Decomposition Of Solid Solution ◽  
Aa5083 Alloy

Understanding solid solution strengthening at elevated temperatures in a creep-resistant Mg–Gd–Ca alloy

2019 ◽  
Vol 181 ◽  
pp. 185-199 ◽  
Author(s):  
Ning Mo ◽  
Ingrid McCarroll ◽  
Qiyang Tan ◽  
Anna Ceguerra ◽  
Ying Liu ◽  
...  
Keyword(s):  
Solid Solution ◽  
Elevated Temperatures ◽  
Solid Solution Strengthening ◽  
Solution Strengthening

scholarly journals The Importance of Diffusivity and Partitioning Behavior of Solid Solution Strengthening Elements for the High Temperature Creep Strength of Ni-Base Superalloys

2020 ◽  
Vol 51 (12) ◽  
pp. 6195-6206 ◽  
Author(s):  
S. Giese ◽  
A. Bezold ◽  
M. Pröbstle ◽  
A. Heckl ◽  
S. Neumeier ◽  
...  
Keyword(s):  
Solid Solution ◽  
High Temperature ◽  
Creep Resistance ◽  
Elevated Temperatures ◽  
Solid Solution Hardening ◽  
Stress Regime ◽  
Solid Solution Strengthening ◽  
Solution Strengthening ◽  
The Individual ◽  
Partitioning Behavior

AbstractThe creep resistance of single-crystalline Ni-base superalloys at elevated temperatures depends among others on solid solution strengthening of the γ-matrix. To study the influence of various solid solution strengtheners on the mechanical properties, a series of Ni-base superalloys with the same content of different alloying elements (Ir, Mo, Re, Rh, Ru, W) or element combinations (MoW, ReMo, ReW) was investigated. Nanoindentation measurements were performed to correlate the partitioning behavior of the solid solution strengtheners with the hardness of the individual phases. The lowest γ′/γ-hardness ratio was observed for the Re-containing alloy with the strongest partitioning of Re to the γ-matrix. As a result of the creep experiments in the high-temperature/low-stress regime (1373 K (1100 °C)/140 MPa), it can be concluded that solid solution hardening in the γ-phase plays an essential role. The stronger the partitioning to the γ-phase and the lower the interdiffusion coefficient of the alloying element, the better the creep resistance. Therefore, the best creep behavior is found for alloys containing high contents of slow-diffusing elements that partition preferably to the γ-phase, particularly Re followed by W and Mo.

Investigating the Relationships Between Structures and Properties of Al Alloys Incorporated With Ti and Mg Inclusions

2016 ◽  
Vol 138 (3) ◽  
Author(s):  
Halil Ibrahim Kurt ◽  
Ibrahim H. Guzelbey ◽  
Serdar Salman ◽  
Razamzan Asmatulu ◽  
Mustafa Dere
Keyword(s):  
Solid Solution ◽  
Grain Size ◽  
Elevated Temperatures ◽  
Solidification Process ◽  
Optical Microscope ◽  
Industrial Applications ◽  
Al Alloys ◽  
Average Grain Size ◽  
Solidification Processes ◽  
Grain Size And Shape

This study investigates the influence of titanium (Ti) and magnesium (Mg) additions on aluminum (Al) alloys in order to evaluate the relationship between the structure and properties of the new alloys. The alloys obtained at elevated temperatures mainly consist of Al–2Mg–1Ti, Al–2Mg–3Ti, Al–4Mg–2Ti, and Al–6Mg–2Ti alloys, as well as α and τ solid solution phases of intermetallic structures. Microstructural analyses were performed using X-ray diffraction (XRD), optical microscope, and energy dispersive spectrometry (EDS) techniques. Test results show that the average grain size of the alloys decreased with the addition of Ti inclusions during the casting and solidification processes, and the smallest grain size was found to be 90 μm for the Al–6Mg–3Ti alloy. In addition, tensile properties of the Al–Mg–Ti alloys were initially improved and then worsened after the addition of higher concentrations of Ti. The highest tensile and hardness values of the alloys were Al–4Mg–2Ti (205 MPa) and Al–6Mg–3Ti (80 BHN). The primary reasons for having higher mechanical properties may be attributed to strengthening of the solid solution and refinement of the grain size and shape during the solidification process. For this study, the optimum concentrations of Ti and Mg added to the Al alloys were 4 and 2 wt.%, respectively. This study may be useful for field researchers to develop new classes of Al alloys for various industrial applications.

scholarly journals Configurational Entropy in Multicomponent Alloys: Matrix Formulation from Ab Initio Based Hamiltonian and Application to the FCC Cr-Fe-Mn-Ni System

Entropy ◽  
2019 ◽  
Vol 21 (1) ◽  
pp. 68 ◽  
Author(s):  
Antonio Fernández-Caballero ◽  
Mark Fedorov ◽  
Jan Wróbel ◽  
Paul Mummery ◽  
Duc Nguyen-Manh
Keyword(s):  
Solid Solution ◽  
Monte Carlo ◽  
Monte Carlo Simulations ◽  
Ab Initio ◽  
Density Functional ◽  
Elevated Temperatures ◽  
Thermodynamic Integration ◽  
Matrix Formulation ◽  
Configuration Entropy ◽  
Multi Body

Configuration entropy is believed to stabilize disordered solid solution phases in multicomponent systems at elevated temperatures over intermetallic compounds by lowering the Gibbs free energy. Traditionally, the increment of configuration entropy with temperature was computed by time-consuming thermodynamic integration methods. In this work, a new formalism based on a hybrid combination of the Cluster Expansion (CE) Hamiltonian and Monte Carlo simulations is developed to predict the configuration entropy as a function of temperature from multi-body cluster probability in a multi-component system with arbitrary average composition. The multi-body probabilities are worked out by explicit inversion and direct product of a matrix formulation within orthonomal sets of point functions in the clusters obtained from symmetry independent correlation functions. The matrix quantities are determined from semi canonical Monte Carlo simulations with Effective Cluster Interactions (ECIs) derived from Density Functional Theory (DFT) calculations. The formalism is applied to analyze the 4-body cluster probabilities for the quaternary system Cr-Fe-Mn-Ni as a function of temperature and alloy concentration. It is shown that, for two specific compositions (Cr 25Fe 25Mn 25Ni 25 and Cr 18Fe 27Mn 27Ni 28), the high value of probabilities for Cr-Fe-Fe-Fe and Mn-Mn-Ni-Ni are strongly correlated with the presence of the ordered phases L1 2 -CrFe 3 and L1 0-MnNi, respectively. These results are in an excellent agreement with predictions of these ground state structures by ab initio calculations. The general formalism is used to investigate the configuration entropy as a function of temperature and for 285 different alloy compositions. It is found that our matrix formulation of cluster probabilities provides an efficient tool to compute configuration entropy in multi-component alloys in a comparison with the result obtained by the thermodynamic integration method. At high temperatures, it is shown that many-body cluster correlations still play an important role in understanding the configuration entropy before reaching the solid solution limit of high-entroy alloys (HEAs).

ATI 720

Alloy Digest ◽  
2009 ◽  
Vol 58 (6) ◽  
Keyword(s):  
Solid Solution ◽  
Corrosion Resistance ◽  
Elevated Temperatures ◽  
Base Alloy ◽  
High Strength ◽  
Heat Treating ◽  
Nickel Base Alloy ◽  
Temperature Performance ◽  
Nickel Base ◽  
Strength Retention

Abstract ATI 720 is a nickel-base alloy, solid solution strengthened with tungsten and molybdenum and precipitation hardened with titanium and aluminum. The alloy combines high strength with metallurgical stability as demonstrated by excellent impact strength retention after long exposures at elevated temperatures. This datasheet provides information on composition, physical properties, and tensile properties. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Ni-669. Producer or source: Allvac, An Allegheny Technologies Company.

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