scholarly journals Nickel Hydroxide as an Active Material for the Positive Electrode in Rechargeable Alkaline Batteries

1999 ◽  
Vol 146 (10) ◽  
pp. 3606-3612 ◽  
Author(s):  
J. Chen ◽  
D. H. Bradhurst ◽  
S. X. Dou ◽  
H. K. Liu
2000 ◽  
Vol 658 ◽  
Author(s):  
V. Pralong ◽  
A. Delahaye-Vidal ◽  
B. Beaudoin ◽  
J-M. Tarascon

ABSTRACTIn this study we investigated the evolution of nickel hydroxide, which acts at the positive electrode of the Ni/Cd, Ni/MH and Ni/H2 alkaline batteries. We found that the addition of bismuth oxide in the course of the active material preparation prevents the dissolution-re-crystallization processes of the nickel hydroxide that are harmful to the electrode efficiency. From XRD and SEM studies, it is shown that treatment of the bismuth doped-nickel hydroxide by hydrogen in 5 N KOH electrolyte prevents metallic nickel formation. Moreover, it appears to stabilize the α-type nickel hydroxide structure, preventing its transformation into the β-Ni(OH)2 phase. Finally, an implementation of these findings towards the most efficient use of nickel positive electrodes is shown.


Nanoscale ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 3581-3587
Author(s):  
Junpeng Li ◽  
Guobang Zhao ◽  
Hongyang Zhao ◽  
Ningning Zhao ◽  
Leilei Lu ◽  
...  

In this work, cerium (Ce)-doped NiCo-MOF (metal organic framework) was investigated for its application as a cathode material of alkaline batteries.


2018 ◽  
Vol 131 (4) ◽  
pp. 1008-1013 ◽  
Author(s):  
Chuangwei Jiao ◽  
Zumin Wang ◽  
Xiaoxian Zhao ◽  
Huan Wang ◽  
Jing Wang ◽  
...  

RSC Advances ◽  
2017 ◽  
Vol 7 (14) ◽  
pp. 8561-8566 ◽  
Author(s):  
Hongyuan Chen ◽  
Sha Zeng ◽  
Minghai Chen ◽  
Yongyi Zhang ◽  
Qingwen Li

In symmetric supercapacitors based on MnO2, only MnO2 on the negative electrode serves as the electrochemically active material. MnO2 on the negative electrode dissolves and re-deposites on the positive electrode, thus induces a decrease in specific capacitance.


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