Time Evolution of the Impedance Response of a Passive Film: A Simple Application to the Li / SOCl2 system

1999 ◽  
Vol 146 (3) ◽  
pp. 933-940 ◽  
Author(s):  
Miran Gaberšček ◽  
Stane Pejovnik
2018 ◽  
Vol 6 (1) ◽  
pp. 202-210 ◽  
Author(s):  
René Antaño-López ◽  
Michel Keddam ◽  
Mireille Turmine ◽  
Vincent Vivier

Author(s):  
Steven D. Toteda

Zirconia oxygen sensors, in such applications as power plants and automobiles, generally utilize platinum electrodes for the catalytic reaction of dissociating O2 at the surface. The microstructure of the platinum electrode defines the resulting electrical response. The electrode must be porous enough to allow the oxygen to reach the zirconia surface while still remaining electrically continuous. At low sintering temperatures, the platinum is highly porous and fine grained. The platinum particles sinter together as the firing temperatures are increased. As the sintering temperatures are raised even further, the surface of the platinum begins to facet with lower energy surfaces. These microstructural changes can be seen in Figures 1 and 2, but the goal of the work is to characterize the microstructure by its fractal dimension and then relate the fractal dimension to the electrical response. The sensors were fabricated from zirconia powder stabilized in the cubic phase with 8 mol% percent yttria. Each substrate was sintered for 14 hours at 1200°C. The resulting zirconia pellets, 13mm in diameter and 2mm in thickness, were roughly 97 to 98 percent of theoretical density. The Engelhard #6082 platinum paste was applied to the zirconia disks after they were mechanically polished ( diamond). The electrodes were then sintered at temperatures ranging from 600°C to 1000°C. Each sensor was tested to determine the impedance response from 1Hz to 5,000Hz. These frequencies correspond to the electrode at the test temperature of 600°C.


1995 ◽  
Vol 31 (7) ◽  
pp. 107-115 ◽  
Author(s):  
Ole Mark ◽  
Cecilia Appelgren ◽  
Torben Larsen

A study has been carried out with the objectives of describing the effect of sediment deposits on the hydraulic capacity of sewer systems and to investigate the sediment transport in sewer systems. A result of the study is a mathematical model MOUSE ST which describes sediment transport in sewers. This paper discusses the applicability and the limitations of various modelling approaches and sediment transport formulations in MOUSE ST. Further, the paper presents a simple application of MOUSE ST to the Rya catchment in Gothenburg, Sweden.


2017 ◽  
Author(s):  
David Hernández-Uribe ◽  
◽  
Chris G. Mattinson ◽  
Owen K. Neill ◽  
Andrew Kylander-Clark ◽  
...  

Author(s):  
Klaus Morawetz

The historical development of kinetic theory is reviewed with respect to the inclusion of virial corrections. Here the theory of dense gases differs from quantum liquids. While the first one leads to Enskog-type of corrections to the kinetic theory, the latter ones are described by quasiparticle concepts of Landau-type theories. A unifying kinetic theory is envisaged by the nonlocal quantum kinetic theory. Nonequilibrium phenomena are the essential processes which occur in nature. Any evolution is built up of involved causal networks which may render a new state of quality in the course of time evolution. The steady state or equilibrium is rather the exception in nature, if not a theoretical abstraction at all.


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