Characterization of Ionic Conductivity Profiles within Proton Exchange Membrane Fuel Cell Gas Diffusion Electrodes by Impedance Spectroscopy

1999 ◽  
Vol 2 (6) ◽  
pp. 259 ◽  
Author(s):  
Mark C. Lefebvre
Keyword(s):  
Fuel Cell ◽  
Ionic Conductivity ◽  
Impedance Spectroscopy ◽  
Proton Exchange Membrane ◽  
Gas Diffusion ◽  
Proton Exchange ◽  
Gas Diffusion Electrodes ◽  
Exchange Membrane

scholarly journals Modelling of Humidity Dynamics for Open-Cathode Proton Exchange Membrane Fuel Cell

2021 ◽  
Vol 12 (3) ◽  
pp. 106
Author(s):  
Fengxiang Chen ◽  
Liming Zhang ◽  
Jieran Jiao
Keyword(s):  
Fuel Cell ◽  
Mass Flow ◽  
Proton Exchange Membrane ◽  
Flow Model ◽  
Transport Theory ◽  
Gas Diffusion ◽  
Proton Exchange ◽  
Operating Conditions ◽  
Output Performance ◽  
Exchange Membrane

The durability and output performance of a fuel cell is highly influenced by the internal humidity, while in most developed models of open-cathode proton exchange membrane fuel cells (OC-PEMFC) the internal water content is viewed as a fixed value. Based on mass and energy conservation law, mass transport theory and electrochemistry principles, the model of humidity dynamics for OC-PEMFC is established in Simulink® environment, including the electrochemical model, mass flow model and thermal model. In the mass flow model, the water retention property and oxygen transfer characteristics of the gas diffusion layer is modelled. The simulation indicates that the internal humidity of OC-PEMFC varies with stack temperature and operating conditions, which has a significant influence on stack efficiency and output performance. In order to maintain a good internal humidity state during operation, this model can be used to determine the optimal stack temperature and for the design of a proper control strategy.

Predicting Liquid Water Saturation Through Differently Structured Cathode Gas Diffusion Media of a Proton Exchange Membrane Fuel Cell

2012 ◽  
Vol 9 (2) ◽  
Author(s):  
N. Akhtar ◽  
P. J. A. M. Kerkhof
Keyword(s):  
Fuel Cell ◽  
Liquid Water ◽  
Proton Exchange Membrane ◽  
Water Saturation ◽  
Catalyst Layer ◽  
Gas Diffusion ◽  
Proton Exchange ◽  
Diffusion Media ◽  
Exchange Membrane

The role of gas diffusion media with differently structured properties have been examined with emphasis on the liquid water saturation within the cathode of a proton exchange membrane fuel cell (PEMFC). The cathode electrode consists of a gas diffusion layer (GDL), a micro-porous layer and a catalyst layer (CL). The liquid water saturation profiles have been calculated for varying structural and physical properties, i.e., porosity, permeability, thickness and contact angle for each of these layers. It has been observed that each layer has its own role in determining the liquid water saturation within the CL. Among all the layers, the GDL is the most influential layer that governs the transport phenomena within the PEMFC cathode. Besides, the thickness of the CL also affects the liquid water saturation and it should be carefully controlled.

Pore Structure Modeling of Flow in Gas Diffusion Layers of Proton Exchange Membrane Fuel Cells

2010 ◽  
Author(s):  
Zhongying Shi ◽  
Xia Wang
Keyword(s):  
Fuel Cell ◽  
Pore Structure ◽  
Proton Exchange Membrane ◽  
Cell Model ◽  
Transport Phenomena ◽  
Pem Fuel Cell ◽  
Gas Diffusion ◽  
Proton Exchange ◽  
Structure Model ◽  
Exchange Membrane

The gas diffusion layer (GDL) in a proton exchange membrane (PEM) fuel cell has a porous structure with anisotropic and non-homogenous properties. The objective of this research is to develop a PEM fuel cell model where transport phenomena in the GDL are simulated based on GDL’s pore structure. The GDL pore structure was obtained by using a scanning electron microscope (SEM). GDL’s cross-section view instead of surface view was scanned under the SEM. The SEM image was then processed using an image processing tool to obtain a two dimensional computational domain. This pore structure model was then coupled with an electrochemical model to predict the overall fuel cell performance. The transport phenomena in the GDL were simulated by solving the Navier-Stokes equation directly in the GDL pore structure. By comparing with the testing data, the fuel cell model predicted a reasonable fuel cell polarization curve. The pore structure model was further used to calculate the GDL permeability. The numerically predicted permeability was close to the value published in the literature. A future application of the current pore structure model is to predict GDL thermal and electric related properties.

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