Co-continuous Polymer Blend Based Lithium-Ion Conducting Gel-Polymer Electrolytes

2001 ◽  
Vol 4 (8) ◽  
pp. A124 ◽  
Author(s):  
S. Passerini ◽  
F. Alessandrini ◽  
T. Momma ◽  
H. Ohta ◽  
H. Ito ◽  
...  
Keyword(s):  
Polymer Blend ◽  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Gel Polymer Electrolytes ◽  
Ion Conducting

Single-ion conducting gel polymer electrolytes: design, preparation and application

2020 ◽  
Vol 8 (4) ◽  
pp. 1557-1577 ◽  
Author(s):  
Kuirong Deng ◽  
Qingguang Zeng ◽  
Da Wang ◽  
Zheng Liu ◽  
Zhenping Qiu ◽  
...  
Keyword(s):  
Polymer Electrolytes ◽  
Ionic Conductivities ◽  
Lithium Ion ◽  
Transference Numbers ◽  
Gel Polymer Electrolytes ◽  
Ion Conducting

Single-ion conducting gel polymer electrolytes possess both unity lithium ion transference numbers (∼0.98) and high ionic conductivities (∼5.8 mS cm−1).

Study of PVAc-PMMA-LiCl polymer blend electrolyte and the effect of plasticizer ethylene carbonate and nanofiller titania on PVAc-PMMA-LiCl polymer blend electrolyte

2017 ◽  
Vol 37 (6) ◽  
pp. 617-631 ◽  
Author(s):  
Manuel Victor Leena Chandra ◽  
Shunmugavel Karthikeyan ◽  
Subramanian Selvasekarapandian ◽  
Manavalan Premalatha ◽  
Sampath Monisha
Keyword(s):  
Impedance Spectroscopy ◽  
Polymer Electrolyte ◽  
Polymer Blend ◽  
Polymer Electrolytes ◽  
Ethylene Carbonate ◽  
Lithium Ion ◽  
Ac Impedance ◽  
Ac Impedance Spectroscopy ◽  
Ion Conducting ◽  
Polymer Blend Electrolyte

Abstract lithium ion conducting polymer electrolyte is one of the essential components of modern rechargeable lithium batteries because of its good interfacial contact with electrodes and effective mechanical properties. A solid lithium ion conducting polymer blend electrolyte is prepared using poly (vinyl acetate) (PVAc) and poly (methyl methacrylate) (PMMA) polymers with different molecular weight percentages (wt%) of lithium chloride (LiCl) by the solution casting technique with tetrahydrofuran as a solvent. The polymer electrolytes were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), Thermogravimetry (TG), AC impedance spectroscopy and ionic transport measurements. XRD and FTIR studies confirm the amorphous nature of the polymer electrolyte and the complexation of salt with polymer. The thermal behavior of polymer electrolytes has been studied from DSC and TG. The highest conductivity obtained using AC impedance spectroscopy is 1.03×10−5 Scm−1 at 303 K for 70 wt%PVAc:30 wt%PMMA:0.8 wt% of LiCl polymer-salt complex. The plasticizer ethylene carbonate (EC) and nanofiller titania (TiO2) were added to the optimized high conducting blend polymer electrolyte. An enhancement in conductivity by one order of magnitude was observed for the plasticized 70 wt%PVAc-30 wt%PMMA-0.8 wt% LiCl polymer electrolyte at ambient temperature. The ionic conductivity value obtained using AC impedance spectroscopy for the plasticized 70 wt%PVAc-30 wt%PMMA-0.8 wt% LiCl polymer electrolyte was 1.03×10−4 Scm−1. The highest conductivity obtained for 70 wt%PVAc-30 wt%PMMA-0.8% LiCl-6 mg TiO2 was 4.45×10−4 Scm−1. Dielectric properties of polymer films are studied and discussed. The electrochemical stability of 1.69 V and 2.69 V was obtained for 70 wt%PVAc-30 wt%PMMA-0.8% LiCl and 70 wt%PVAc-30 wt%PMMA-0.8% LiCl-6 mg TiO2 polymer electrolytes, respectively, using linear sweep voltammetry. The value of Li+ ion transference number was estimated by the DC polarization method and was found to be 0.99 for the highest conducting 70 wt%PVAc-30 wt%PMMA-0.8 wt% LiCl-6 mg TiO2 nanocomposite polymer electrolyte.

Preparation of LAGP/P(VDF-HFP) polymer electrolytes for Li-ion batteries

RSC Advances ◽  
2015 ◽  
Vol 5 (80) ◽  
pp. 65395-65401 ◽  
Author(s):  
Qingqing Zhang ◽  
Fei Ding ◽  
Wenbin Sun ◽  
Lin Sang
Keyword(s):  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Electrochemical Performances ◽  
Gel Polymer Electrolytes ◽  
Li Ion Batteries ◽  
Conducting Filler ◽  
Li Ion ◽  
Ion Conducting

LAGP as a lithium ion conducting filler, was added into P(VDF-HFP) based gel polymer electrolytes to improve electrochemical performances.

Lithium ion conduction and ion–polymer interaction in PVdF-HFP based gel polymer electrolytes

2014 ◽  
Vol 268 ◽  
pp. 288-293 ◽  
Author(s):  
K.B.Md. Isa ◽  
Z. Osman ◽  
A.K. Arof ◽  
L. Othman ◽  
N.H. Zainol ◽  
...  
Keyword(s):  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Gel Polymer Electrolytes ◽  
Ion Conduction ◽  
Lithium Ion Conduction ◽  
Polymer Interaction

Immobilized cation functional gel polymer electrolytes with high lithium transference number for lithium ion batteries

2019 ◽  
Vol 572 ◽  
pp. 382-389 ◽  
Author(s):  
Chih-Hao Tsao ◽  
Hou-Ming Su ◽  
Hsiang-Ting Huang ◽  
Ping-Lin Kuo ◽  
Hsisheng Teng
Keyword(s):  
Lithium Ion Batteries ◽  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Transference Number ◽  
Gel Polymer Electrolytes
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