Electrochemical Behavior of the SmF3 in Alkali Chloride Melts

2020 ◽  
Vol 98 (10) ◽  
pp. 425-433
Author(s):  
Yuriy V. Stulov ◽  
Sergey A. Kuznetsov
Keyword(s):  
Electrochemical Behavior ◽  
Alkali Chloride ◽  
Chloride Melts

Electrochemical Behavior of the SmF3 in Alkali Chloride Melts

2020 ◽  
Vol MA2020-02 (59) ◽  
pp. 2944-2944
Author(s):  
Yuriy V. Stuliov ◽  
Sergey A. Kuznetsov
Keyword(s):  
Electrochemical Behavior ◽  
Alkali Chloride ◽  
Chloride Melts

ELECTRODE POTENTIALS OF THORIUM TETRACHLORIDE IN ALKALI CHLORIDE MELTS

1964 ◽  
Vol 42 (6) ◽  
pp. 1315-1322 ◽  
Author(s):  
R. Srinivasan ◽  
S. N. Flengas
Keyword(s):  
Silver Chloride ◽  
Gravimetric Method ◽  
Reference Electrode ◽  
The Other ◽  
Alkali Chloride ◽  
Electrode Potentials ◽  
Silver Chloride Reference Electrode ◽  
Chloride Melts ◽  
Silver Silver ◽  
Silver Silver Chloride

The electrode potentials of the system Th, ThCl4 (KCl, NaCl) were measured at various concentrations of thorium chloride, and at temperatures between 670 °C and 850 °C, using a silver – silver chloride reference electrode. It was shown by a direct gravimetric method that the reaction,Th(metal) + ThCl4(melt) = 2ThCl2(in melt),postulated by previous investigators, did not take place.The activity coefficients, and the other partial molal properties of the solutions of ThCl4, in the equimolar mixture of potassium and sodium chlorides, were calculated as a function of temperature from the e.m.f. measurements.

Kinetics of aluminium deposition from aluminium chloride—alkali chloride melts

1982 ◽  
Vol 27 (11) ◽  
pp. 1595-1598 ◽  
Author(s):  
R. Ødegard ◽  
A. Bjørgum ◽  
Å. Sterten ◽  
J. Thonstad ◽  
R. Tunold
Keyword(s):  
Aluminium Chloride ◽  
Alkali Chloride ◽  
Chloride Melts ◽  
Kinetics Of

Ab Initio Estimation of NbF−6 , NbClF2−6 , and NbF2− 7 Complexes Stability in Alkali Chloride Melts

2010 ◽  
Vol 65 (11) ◽  
pp. 1020-1026 ◽  
Author(s):  
Vyacheslav G. Kremenetsky ◽  
Sergey A. Kuznetsov ◽  
Olga V. Kremenetskaya ◽  
Veniamin V. Soloviev ◽  
Lyudmila A. Chernenko ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Relative Stability ◽  
Quantum Chemical ◽  
Molten Salts ◽  
Alkali Chloride ◽  
Chlorine Anion ◽  
The Third ◽  
Chloride Melts ◽  
Stable Particles ◽  
Particle Geometry

Quantum-chemical calculations of the parameters of the nM+・NbClF2−6 type particles have been performed, where M stands for Na, K, Cs and n = 0 - 6. Under certain conditions such particles may exist in melts of alkali metal chlorides.Within the framework of this approximation, compositions for themost stable particles in molten salts were obtained. Relative stability of the particles containing the NbF−6 , NbClF2−6 , and NbF2−7 complexes has been calculated. Energies and some other characteristics of the electron structure and the particle geometry structure were determined depending on the n and M values. For estimation of the third sphere’s influence, the systems (M2NbF7 +8MCl) and (M2NbF7 +15MCl) are surveyed. The chlorine anion enters the first coordination sphere in the Nasystem only, i. e. in this system the true complex NbClF3−7 is formed.

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