Separation of Lanthanides and Actinides in a Chloride Melt - Liquid Metal System: The Effect of Phase Composition

2016 ◽  
Vol 75 (15) ◽  
pp. 397-408 ◽  
Author(s):  
V. A. Volkovich ◽  
D. S. Maltsev ◽  
S. Y. Melchakov ◽  
L. F. Yamshchikov ◽  
A. V. Novoselova ◽  
...  
Keyword(s):  
Phase Composition ◽  
Liquid Metal ◽  
Metal System ◽  
Chloride Melt ◽  
Liquid Metal System

Electrochemical and Thermodynamic Properties of Lanthanum in a Chloride Melt - Liquid Metal System

2016 ◽  
Vol 75 (15) ◽  
pp. 265-274 ◽  
Author(s):  
A. S. Dedyukhin ◽  
A. V. Shchetinskiy ◽  
E. A. Kharina ◽  
I. E. Shchepin ◽  
V. A. Volkovich ◽  
...  
Keyword(s):  
Liquid Metal ◽  
Thermodynamic Properties ◽  
Metal System ◽  
Chloride Melt ◽  
Liquid Metal System

Thermodynamic Modeling of Phase Equilibrium in Fe-Y-Cr-C-O Liquid Metal System

2017 ◽  
Vol 265 ◽  
pp. 862-867 ◽  
Author(s):  
G.G. Mikhailov ◽  
L.A. Makrovets
Keyword(s):  
Liquid Metal ◽  
Chemical Reactions ◽  
Equilibrium Constants ◽  
Oxide System ◽  
Critical Parameters ◽  
Low Carbon ◽  
Metal System ◽  
Oxide Melt ◽  
Liquid Metal System ◽  
Existence Domain

The thermodynamic characteristics of processes in the liquid metal system Fe–Y–Cr–C–O are considered as applied to low-carbon and low-alloy metal. The critical parameters for the state diagram of the oxide system Y2O3–Cr2O3 were established based on the values quoted in literature. The temperature dependence of the melting reaction constant Y2O3·Cr2O3 was determined. The coordinates of eutectic transformation points for the system Y2O3–Cr2O3 were calculated. In accordance with subregular solution theory, the energetic parameters which are necessary to calculate the activities Cr2O3 and Y2O3 of oxide melts in the system Y2O3–Cr2O3 were determined. The energetic parameters of subregular solution theories for the oxide system FeO–Cr2O3–Y2O3 were determined based on the values for the binary systems FeO–Y2O3, FeO–Cr2O3 and Y2O3–Cr2O3. The view of this diagram, as coupled with the existence domain of liquid metal within the framework of the quaternary system Fe–Y–Cr–O–С, suggests that low-carbon chromic liquid metal when injected with yttrium can form the following non-metallic inclusions: |Cr2O3|, |Y2O3|, |FeO·Cr2O3|, |Y2O3·Cr2O3| or oxide melt (FeO, Y2O3, Cr2O3). Oxide melt may contain up to 2 % of divalent chrome (Cr2+). The equilibrium constants for the main reactions of steel deoxidation with the formation of liquid, solid and gas products of chemical reactions were also established. The activity of components dissolved in metal was calculated using interaction parameters. The set of derived expressions for the activity of components and the dependences of equilibrium constants of chemical reactions and phase transformations allowed us to diagram the surface of component solubility in liquid metal (SCSM). SCSM diagrams show the compositions of liquid metal and indicate oxide phases which are in equilibrium with liquid metal.

Mechanism of volume viscosity in the liquid metal system lead‐bismuth

1974 ◽  
Vol 60 (11) ◽  
pp. 4390-4395 ◽  
Author(s):  
Jane M. Flinn ◽  
P. K. Gupta ◽  
T. A. Litovitz
Keyword(s):  
Liquid Metal ◽  
Metal System ◽  
Liquid Metal System ◽  
Volume Viscosity

scholarly journals THE LITHIUM-SODIUM LIQUID METAL SYSTEM

1954 ◽  
Author(s):  
O. Salmon ◽  
D. Ahmann
Keyword(s):  
Liquid Metal ◽  
Metal System ◽  
Liquid Metal System

A General Equivalent Circuit Model for a Metal/Organic/Liquid/Metal System

2018 ◽  
Vol 65 (10) ◽  
pp. 4555-4562 ◽  
Author(s):  
Nicolo Lago ◽  
Marco Buonomo ◽  
Nicola Wrachien ◽  
Federico Prescimone ◽  
Marco Natali ◽  
...  
Keyword(s):  
Liquid Metal ◽  
Equivalent Circuit ◽  
Organic Liquid ◽  
Equivalent Circuit Model ◽  
Circuit Model ◽  
Metal System ◽  
Liquid Metal System ◽  
Metal Organic

Actinides recovery from molten salt/liquid metal system by electrochemical methods

1997 ◽  
Vol 247 ◽  
pp. 183-190 ◽  
Author(s):  
Masatoshi Iizuka ◽  
Tadafumi Koyama ◽  
Naruhito Kondo ◽  
Reiko Fujita ◽  
Hiroshi Tanaka
Keyword(s):  
Liquid Metal ◽  
Molten Salt ◽  
Electrochemical Methods ◽  
Metal System ◽  
Liquid Metal System
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