Analysis of Cathode Catalyst Layer Structure and Cell Performance in PEFC

2014 ◽  
Vol 64 (3) ◽  
pp. 305-312 ◽  
Author(s):  
S. Akabori ◽  
K. Suzuki ◽  
Y. Tabe ◽  
T. Chikahisa
Author(s):  
Hidetoshi Matsuda ◽  
Kazuyoshi Fushinobu ◽  
Atsushi Ohma ◽  
Ken Okazaki

The structure of cathode catalyst layer (CCL) has strong relationship with the performance of polymer electrolyte fuel cells (PEFCs). We investigated the relationship between the catalyst layer structure and the cell performance experimentally. Multi-layered CCL is used to investigate the effect of the layer design on the cell performance. Membrane side of CCL works, as a reaction area, more actively than the gas diffusion layer (GDL) side at low relative humidity (RH) due to the lower proton conductivity. On the other hand, when the cathode gas has less oxygen partial pressure at high RH, GDL side is more active than membrane side owing to low diffusivity of oxygen. We suggest that the volumetric catalyst concentration of the CCL membrane side should be higher at low RH, however at high RH with lower oxygen partial pressure in cathode gas, the GDL side should have higher concentration. Simple theoretical model is employed to see the behavior of the reaction distribution in the catalyst layer.


2013 ◽  
Vol 2013.52 (0) ◽  
pp. 101-102
Author(s):  
Sho AKABORI ◽  
Kengo SUZUKI ◽  
Yutaka TABE ◽  
Takemi CHIKAHISA

RSC Advances ◽  
2016 ◽  
Vol 6 (2) ◽  
pp. 1333-1338 ◽  
Author(s):  
Huagen Liang ◽  
Ruoyu Xu ◽  
Kaicheng Chen ◽  
Chenyang Shen ◽  
Shibin Yin

Short-term constant voltage discharge test of the self-humidifying MEAs with different cathode structure at 60 °C and 30 psi under 20% RH.


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