Cardo-Polyetherketone Anion Exchange Membranes with Suitable Chemical/Mechanical Stability and Performance for All-Vanadium Redox Flow Battery

2014 ◽  
Vol 58 (37) ◽  
pp. 55-64 ◽  
Author(s):  
S. Yun ◽  
J. Parrondo ◽  
V. K. Ramani
Keyword(s):  
Anion Exchange ◽  
Mechanical Stability ◽  
Vanadium Redox Flow Battery ◽  
Anion Exchange Membranes ◽  
Redox Flow Battery ◽  
Flow Battery ◽  
And Performance ◽  
Vanadium Redox

Synthesis and investigation of imidazolium functionalized poly(arylene ether sulfone)s as anion exchange membranes for all-vanadium redox flow batteries

RSC Advances ◽  
2016 ◽  
Vol 6 (8) ◽  
pp. 6029-6037 ◽  
Author(s):  
Di Lu ◽  
Lele Wen ◽  
Feng Nie ◽  
Lixin Xue
Keyword(s):  
Anion Exchange ◽  
Vanadium Redox Flow Battery ◽  
Anion Exchange Membranes ◽  
Redox Flow Battery ◽  
Flow Battery ◽  
Redox Flow Batteries ◽  
Arylene Ether ◽  
Flow Batteries ◽  
Vanadium Redox

A serials of imidazolium functionalized poly(arylene ether sulfone) as anion exchange membranes (AEMs) for all-vanadium redox flow battery (VRB) application are synthesized successfully in this study.

scholarly journals Novel Anion Exchange Membrane Based on Poly(Pentafluorostyrene) Substituted with Mercaptotetrazole Pendant Groups and Its Blend with Polybenzimidazole for Vanadium Redox Flow Battery Applications

Polymers ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 915
Author(s):  
Hyeongrae Cho ◽  
Vladimir Atanasov ◽  
Henning M. Krieg ◽  
Jochen A. Kerres
Keyword(s):  
Anion Exchange ◽  
Open Circuit ◽  
Vanadium Redox Flow Battery ◽  
Anion Exchange Membranes ◽  
Redox Flow Battery ◽  
Flow Battery ◽  
Blend Membranes ◽  
Performance Results ◽  
Exchange Membrane ◽  
Vanadium Redox

In order to evaluate the performance of the anion exchange membranes in a vanadium redox flow battery, a novel anion exchange polymer was synthesized via a three step process. Firstly, 1-(2-dimethylaminoethyl)-5-mercaptotetrazole was grafted onto poly(pentafluorostyrene) by nucleophilic F/S exchange. Secondly, the tertiary amino groups were quaternized by using iodomethane to provide anion exchange sites. Finally, the synthesized polymer was blended with polybenzimidazole to be applied in vanadium redox flow battery. The blend membranes exhibited better single cell battery performance in terms of efficiencies, open circuit voltage test and charge-discharge cycling test than that of a Nafion 212 membrane. The battery performance results of synthesized blend membranes suggest that those novel anion exchange membranes are promising candidates for vanadium redox flow batteries.

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