scholarly journals Novel Mesoporous Nanotitania/Carbon Composite Electrodes for Electrochemical Energy Storage

2013 ◽  
Vol 50 (24) ◽  
pp. 37-48
Author(s):  
M. J. Sussman ◽  
N. Brodusch ◽  
R. Gauvin ◽  
G. P. Demopoulos
2022 ◽  
Vol 9 ◽  
Author(s):  
Adriana M. Navarro-Suárez ◽  
Milo S. P. Shaffer

Structural energy storage devices (SESDs), designed to simultaneously store electrical energy and withstand mechanical loads, offer great potential to reduce the overall system weight in applications such as automotive, aircraft, spacecraft, marine and sports equipment. The greatest improvements will come from systems that implement true multifunctional materials as fully as possible. The realization of electrochemical SESDs therefore requires the identification and development of suitable multifunctional structural electrodes, separators, and electrolytes. Different strategies are available depending on the class of electrochemical energy storage device and the specific chemistries selected. Here, we review existing attempts to build SESDs around carbon fiber (CF) composite electrodes, including the use of both organic and inorganic compounds to increase electrochemical performance. We consider some of the key challenges and discuss the implications for the selection of device chemistries.


2019 ◽  
Vol 7 (15) ◽  
pp. 9305-9315 ◽  
Author(s):  
Nan Zheng ◽  
Guangyu Jiang ◽  
Xiao Chen ◽  
Jiayi Mao ◽  
Yajun Zhou ◽  
...  

Potassium ion batteries (KIBs) are the emerging and promising energy storage system for large-scale electrochemical energy storage.


2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Xiang Gao ◽  
Xuan Du ◽  
Tyler S. Mathis ◽  
Mengmeng Zhang ◽  
Xuehang Wang ◽  
...  

AbstractImproving the accessibility of ions in the electrodes of electrochemical energy storage devices is vital for charge storage and rate performance. In particular, the kinetics of ion transport in organic electrolytes is slow, especially at low operating temperatures. Herein, we report a new type of MXene-carbon nanotube (CNT) composite electrode that maximizes ion accessibility resulting in exceptional rate performance at low temperatures. The improved ion transport at low temperatures is made possible by breaking the conventional horizontal alignment of the two-dimensional layers of the MXene Ti3C2 by using specially designed knotted CNTs. The large, knot-like structures in the knotted CNTs prevent the usual restacking of the Ti3C2 flakes and create fast ion transport pathways. The MXene-knotted CNT composite electrodes achieve high capacitance (up to 130 F g−1 (276 F cm−3)) in organic electrolytes with high capacitance retention over a wide scan rate range of 10 mV s−1 to 10 V s−1. This study is also the first report utilizing MXene-based supercapacitors at low temperatures (down to −60 °C).


MRS Advances ◽  
2016 ◽  
Vol 1 (45) ◽  
pp. 3049-3055
Author(s):  
S. Gupta ◽  
B. Aberg ◽  
S. B. Carrizosa

ABSTRACTGraphene-based nanomaterials (graphene nanosheets/graphene nanoribbons) decorated with vanadium pentoxide (V2O5) nanobelts (i.e. GVNBs) were synthesized via one-step low-temperature facile hydrothermal/solvothermal method as high-performance electrochemical composite electrodes. VNBs were formed in the presence of graphene oxide (GO), a mild oxidant, which transforms into reduced GO (rGOHT) assisted in enhancing the electronic conductivity with mechanical strength for GVNBs. From surface sensitive electron microscopy and spectroscopy structural characterization techniques and analyses, rGOHT nanosheets/ nanoribbons appear to be inserted into and coated with the layered crystal structure of VNBs, which further confirmed the enhanced electrical conductivity of VNBs. The electrochemical energy storage capacity of GVNBs is investigated using electrochemistry and the specific capacitance Cs are determined from both the cyclic voltammetry (CV) with scan rate and galvanostatic charge/discharge V-t profiles with varying current density. The GVNBs having rGO-rich composite V1G3 (V2O5/GO = 1:3) showed superior performance followed by V2O5-rich V3G1 (V2O5/GO = 3:1) as compared with V1G1 (V2O5/GO = 1:1) composites besides pure component (rGOHT and V2O5) materials. Moreover, V1G3 and V3G1 composites showed excellent cyclic stability and the capacitance retention of > 80% after 200 cycles. Furthermore, by performing extensive simulations and modeling of electrochemical impedance spectroscopy data, we determined various circuit parameters (charge transfer and solution resistance, double layer and low frequency capacitance). These findings highlight the comparative performance of nanocomposite hybrid electrode materials.


Author(s):  
Dhanasekar Kesavan ◽  
Vimal Kumar Mariappan ◽  
Karthikeyan Krishnamoorthy ◽  
Sang-Jae Kim

In this study, we report a facile carbothermal method for the preparation of boron-oxy-carbide (BOC) nanostructures and explore their properties towards electrochemical energy storage devices.


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